☆ 4.8 Review

Single-Atom Catalysts for Hydrogen Activation

SMALL (2023)

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Article Engineering, Environmental

Single Co atoms anchored on nitrogen-doped hierarchically ordered porous carbon for selective hydrogenation of quinolines and efficient oxygen reduction

Yingchun Guo et al.

Summary: By elaborately designing, constructing ordered macro-mesoporous carbon with nonprecious metal single-atom sites can significantly improve catalytic performance, as demonstrated by the exceptional yield and selectivity for quinolines hydrogenation reaction and outstanding performance for the oxygen reduction reaction achieved in this study.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Chemistry, Multidisciplinary

Pd/Fe2O3 with Electronic Coupling Single-Site Pd-Fe Pair Sites for Low-Temperature Semihydrogenation of Alkynes

Ruijie Gao et al.

Summary: The study successfully constructed a highly active and stable single palladium-iron catalyst, achieving high activity and selectivity for alkyne hydrogenation and exhibiting excellent performance for purifying acetylene from ethylene streams.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

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Article Multidisciplinary Sciences

A metal-supported single-atom catalytic site enables carbon dioxide hydrogenation

Sung-Fu Hung et al.

Summary: A metal supported single-atom catalyst shows high efficiency in electrocatalytic reduction of CO2 to methane, while nitrogen-doped graphene-supported catalyst only produces CO.

NATURE COMMUNICATIONS (2022)

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Article Chemistry, Physical

Fe Single-Atom Catalysts on MOF-5 Derived Carbon for Efficient Oxygen Reduction Reaction in Proton Exchange Membrane Fuel Cells

Xiaoying Xie et al.

Summary: The development of Fe single-atom catalysts using MOF-5 as a precursor has led to the creation of highly-porous carbon with an ultrahigh specific surface area, resulting in improved performance in proton exchange membrane fuel cells for the oxygen reduction reaction. The Fe SAC-MOF-5 catalyst demonstrated excellent half-wave potential and peak power density due to the high density of single Fe atoms and increased exposure of active sites on the external surface area of the carbon support.

ADVANCED ENERGY MATERIALS (2022)

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Article Chemistry, Physical

Silica-supported Fe/Fe-O nanoparticles for the catalytic hydrogenation of nitriles to amines in the presence of aluminium additives

Vishwas G. Chandrashekhar et al.

Summary: Development of an iron-based catalyst for hydrogenation of nitriles, capable of promoting the conversion of various nitriles into primary amines under scalable and industrially viable conditions.

NATURE CATALYSIS (2022)

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Article Chemistry, Physical

Tuning the coordination environment of single-atom catalyst M-N-C towards selective hydrogenation of functionalized nitroarenes

Dan Zhou et al.

Summary: Fine-tuning the coordination environment of single-atom catalysts (SACs) using glutamic acid as the N/C source and pyrolysis atmosphere as a regulator has been shown to effectively optimize catalytic performances. This approach delicately tunes the M-N coordination number and electronic structure, leading to enhanced catalytic activity. Particularly, the Co-N-C SAC synthesized through this method exhibited significantly higher turnover frequency and selectivity in hydrogenation reactions compared to state-of-the-art noble-metal-free M-N-C catalysts.

NANO RESEARCH (2022)

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Article Chemistry, Physical

Engineering the atomic interface of porous ceria nanorod with single palladium atoms for hydrodehalogenation reaction

Zhijun Li et al.

Summary: The study describes a simple and efficient approach to create atomically dispersed palladium catalysts, which exhibit excellent catalytic activity and recyclability. Density functional theory calculations reveal that the high activity stems from the spatial isolation of palladium atoms and the modified electronic structure in defect-containing ceria nanorods.

NANO RESEARCH (2022)

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Article Chemistry, Physical

Breaking the activity limitation of iridium single-atom catalyst in hydrogenation of quinoline with synergistic nanoparticles catalysis

Qikai Shen et al.

Summary: Single-atom catalysts (SACs) with the advantages of homogeneous and heterogeneous catalysts have become a hot-spot in catalysis field. However, the lack of metal-metal bond in SACs limits their hydrogenation activity. This study proposes a catalyst, Ir1+NPs/CMK, which combines single iridium atoms and nanoparticles to boost the catalytic activity of quinoline hydrogenation, and achieves significant improvement in reactivity.

NANO RESEARCH (2022)

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Article Multidisciplinary Sciences

Highly-efficient RuNi single-atom alloy catalysts toward chemoselective hydrogenation of nitroarenes

Wei Liu et al.

Summary: The design and exploitation of high-performance catalysts for selective hydrogenation reactions is a significant challenge. In this study, the authors report a RuNi single atom alloy catalyst that exhibits exceptional activity and selectivity in the hydrogenation of 4-nitrostyrene.

NATURE COMMUNICATIONS (2022)

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Article Chemistry, Physical

Effective Ensemble of Pt Single Atoms and Clusters over the (Ni,Co)(OH)2 Substrate Catalyzes Highly Selective, Efficient, and Stable Hydrogenation Reactions

Lihua Zhu et al.

Summary: A Pt-Ni-Co catalyst with Pt single atoms and atomic clusters dispersed on (Ni,Co)(OH)(2) nanoparticles on a carbon matrix was synthesized, demonstrating high catalytic activity and selectivity in the hydrogenation of nitroaromatics. The synergistic coordination effect between Pt single atoms and Pt clusters was found to significantly enhance the reaction rate, challenging the conventional notion that Pt single atoms can only adsorb -NO2 groups. This study not only reveals the coordinated ensemble catalysis mechanism of SAACs but also provides a strategy for developing highly efficient and selective catalysts.

ACS CATALYSIS (2022)

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Review Chemistry, Physical

Atomic-Level Metal Electrodeposition: Synthetic Strategies, Applications, and Catalytic Mechanism in Electrochemical Energy Conversion

Yi Shi et al.

Summary: Electrochemical energy conversion is a promising approach to address the global energy crisis and environmental issues. This review summarizes the recent progress in electrodepositing atomic-level metal catalysts using various strategies. The application of surface-limited electrochemical techniques, such as underpotential deposition (UPD), in the synthesis of atomic-level metal catalysts is highlighted. The mechanistic investigations, comprehensive understanding of structure-activity relationships at the atomic level, and the application of these atomic-level catalysts in electrochemical energy conversion are discussed in detail.

SMALL STRUCTURES (2022)

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Article Chemistry, Physical

Single-atom Pd catalyst anchored on Zr-based metal-organic polyhedra for Suzuki-Miyaura cross coupling reactions in aqueous media

Seongsoo Kim et al.

Summary: This study successfully achieved efficient Suzuki-Miyaura cross coupling reactions in aqueous media by designing discrete cages of metal-organic polyhedra anchoring single Pd atoms. The structure showed high stability and recyclability, making it a promising candidate for single-atom catalysis applications in water.

NANO RESEARCH (2021)

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Article Chemistry, Physical

Chiral metal-organic frameworks with tunable catalytic selectivity in asymmetric transfer hydrogenation reactions

Xu Chen et al.

Summary: Metal-organic frameworks (MOFs) have shown great potential in heterogeneous catalysis, and the enantioselectivities of chiral MOF (CMOF) catalysts can be significantly enhanced by designing metals and ligands, resulting in improved chiral catalytic reactions.

NANO RESEARCH (2021)

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Article Chemistry, Physical

Metallo-aerogels derived from chitosan with encapsulated metal nanoparticles as robust, efficient and selective nanocatalysts towards reduction of nitroarenes

Yajing Shen et al.

Summary: Metallo-aerogels fabricated by pyrolysis of xerogels derived from chitosan-metal hydrogels exhibit excellent catalytic performance in hydrogenation reactions of nitroarenes. The superior catalytic properties are attributed to the graphitic shells formed during the pyrolysis process, which prevent aggregation of metal nanoparticles, leaching of metal, and increase their stability.

NANO RESEARCH (2021)

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Article Nanoscience & Nanotechnology

Highly Active and Stable Palladium Single-Atom Catalyst Achieved by a Thermal Atomization Strategy on an SBA-15 Molecular Sieve for Semi-Hydrogenation Reactions

Zhijun Li et al.

Summary: A thermal atomization strategy was used to create single-atom dispersed palladium catalysts with exceptional efficiency and stability in selective hydrogenation reactions. This catalyst has the potential for large-scale production.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Physical

Atomically dispersed Co-N4 sites anchored on N-doped carbon for aqueous phase transfer hydrogenation between nitroarenes and saturated N-heterocycles

Dan Xu et al.

Summary: Atomically dispersed Co catalysts with Co-N-4 active sites were successfully prepared in this study, facilitating transfer hydrogenation between nitroarenes and saturated N-heterocycles in aqueous solution. These catalysts exhibit higher TOF values compared to nanoparticle catalysts, demonstrating excellent catalytic performance.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

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Article Chemistry, Physical

One-step synthesis of single palladium atoms in WO2.72 with high efficiency in chemoselective hydrodeoxygenation of vanillin

Zhijun Li et al.

Summary: This study presents a one-step synthetic approach to fabricate a catalyst with atomically dispersed palladium atoms bonded covalently to nearby oxygen atoms, which shows outstanding catalytic performance and stability in the hydrodeoxygenation of vanillin. This high activity is attributed to the unique electronic structure of isolated palladium atoms confined in defective WO2.72, paving the way for the advancement of single atom catalysis through a coordination-engineered strategy.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

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Review Chemistry, Multidisciplinary

Single-Atom (Iron-Based) Catalysts: Synthesis and Applications

Baljeet Singh et al.

Summary: Supported single-metal atom catalysts consist of isolated active metal centers heterogenized on inert supports, offering control over their thermal stability, electronic properties, and catalytic activities through interactions with neighboring heteroatoms. The atomic dispersion of the catalytic centers reduces the required amount of metal and enables control over selectivity and catalyst turnover frequency.

CHEMICAL REVIEWS (2021)

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Article Chemistry, Multidisciplinary

Non-Bonding Interaction of Neighboring Fe and Ni Single-Atom Pairs on MOF-Derived N-Doped Carbon for Enhanced CO2 Electroreduction

Long Jiao et al.

Summary: Through the direct pyrolysis of MOFs assembled with Fe and Ni-doped ZnO nanoparticles, a novel Fe-1-Ni-1-N-C catalyst with neighboring Fe and Ni single-atom pairs on nitrogen-doped carbon support has been precisely constructed. The synergism of neighboring Fe and Ni single-atom pairs significantly boosts the electrocatalytic reduction of CO2, surpassing catalysts with separate Fe or Ni single atoms. The study reveals the importance of the communicative effect between adjacent single atoms for improved catalysis in single-atom catalysts containing multiple metal species.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

Zeolite-Encaged Isolated Platinum Ions Enable Heterolytic Dihydrogen Activation and Selective Hydrogenations

Xin Deng et al.

Summary: The study demonstrates a facile strategy to encapsulate Ptd(+) species within Y zeolite and reveals the unique configuration of Pt@Y model catalyst for selective hydrogenation. The atomically dispersed Pt delta+ stabilized by the surrounding oxygen atoms enables exclusive heterolytic activation of dihydrogen, leading to remarkable performance in selective hydrogenation reactions.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

Atomically Dispersed Cu Catalyst for Efficient Chemoselective Hydrogenation Reaction

Hu Liu et al.

Summary: The researchers have developed a new strategy to incorporate single atom Cu sites into melem ring, resulting in Cu-1/CN catalyst with high selectivity, activity, and stability for selective hydrogenation of 4-nitrostyrene. The presence of hydroxymethyl from trimethylolmelamine is found to be beneficial for atomically dispersing Cu atoms in CN, contributing to the optimal chemical environment for efficient hydrogenation reaction. X-ray absorption fine structure tests indicate that the Cu atom of Cu-1/CN is dominated by quaternary coordination way in the melem ring of CN.

NANO LETTERS (2021)

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Article Chemistry, Physical

Synergistic Effects for Enhanced Catalysis in a Dual Single-Atom Catalyst

Junhong Fu et al.

Summary: A dual single-atom catalyst (DSAC) Ir1Mo1/TiO2 showed much greater catalytic chemoselectivity than comparable single-atom catalysts for the hydrogenation of 4-nitrostyrene. Density functional theory studies revealed that Ir single atoms affect H2 activation while Mo single atoms are responsible for 4-NS adsorption, with synergistic cooperation contributing to the better catalytic performance.

ACS CATALYSIS (2021)

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Article Nanoscience & Nanotechnology

Effectively Regulating the Microenvironment of Atomically Dispersed Rh through Co and Pi to Promote the Selectivity in Olefin Hydroformylation

Baiyin Wei et al.

Summary: Effective control of the microenvironment of active sites is crucial for improving the selectivity of products in heterogeneous homogeneous processes. The development of a high-performance Rh-based atomically dispersed catalyst demonstrates that rational design of the local microenvironment of active metals is important to optimize catalytic performance.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Nanoscience & Nanotechnology

Pd Anchored on a Phytic Acid/Thiourea Polymer as a Highly Active and Stable Catalyst for the Reduction of Nitroarene

Meng Zhang et al.

Summary: The N, P, C, O-containing polymer, Pd-CNSP, prepared via microwave heating of phytic acid and thiourea in just 90 seconds, exhibits outstanding catalytic ability in the reduction of 4-nitrophenol. Due to the synergetic effect of the polymer support and Pd, Pd-CNSP achieves a high atomic efficiency of Pd species, with a turnover frequency value as high as 848 min(-1), the highest reported so far. Pd-CNSP also shows good selectivity for the reduction of halogen-substituted nitroaromatics, making it promising for mass production and use in other industrial hydrogenation reactions.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Multidisciplinary

Iron Single Atom Catalyzed Quinoline Synthesis

Zhongxin Chen et al.

Summary: The study focuses on the development of mechanically strong, hierarchically porous carbon plates for the immobilization of single-atom catalysts (SACs) to enhance catalytic activity and stability. The carbon-based SACs exhibit excellent activity and selectivity for the synthesis of a wide assortment of quinolines through a three-component oxidative cyclization. The strategy is also applicable to challenging reactions such as the deuteration of quinolines at the fourth position.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Polyoxometalate-Based Metal-Organic Framework as Molecular Sieve for Highly Selective Semi-Hydrogenation of Acetylene on Isolated Single Pd Atom Sites

Yiwei Liu et al.

Summary: By constructing isolated single Pd atom in a polyoxometalate-based metal-organic framework, the selective semi-hydrogenation of acetylene in an ethylene-rich gas stream can be achieved, resulting in a high selectivity of ethylene product.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Accelerated Anti-Markovnikov Alkene Hydrosilylation with Humic-Acid-Supported Electron-Deficient Platinum Single Atoms

Kairui Liu et al.

Summary: The study synthesized electron-deficient Pt single atoms supported on humic matter for use as a catalyst in hydrosilylation reactions, demonstrating super activity and selectivity. Density functional theory calculations revealed the high performance was due to the atomic dispersion of Pt and electron deficiency of the Pt-1 atoms, different from traditional Pt nanoscale catalysts. The catalyst maintained excellent performance during recycle experiments, indicating high stability.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Physical

Confinement of atomically dispersed Rh catalysts within porous monophosphine polymers for regioselective hydroformylation of alkenes

Kang Zhao et al.

Summary: This study demonstrates precise control of regioselectivity in hydroformylation using monophosphine ligands with single-atom Rh catalysts encapsulated in porous monophosphine polymers. The optimized catalyst shows enhanced regioselectivity and stability, with significant potential for application.

JOURNAL OF CATALYSIS (2021)

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Article Chemistry, Physical

Rational design of palladium single-atoms and clusters supported on silicoaluminophosphate-31 by a photochemical route for chemoselective hydrodeoxygenation of vanillin

Xiaowen Lu et al.

Summary: This study presents a novel palladium catalyst with exceptional activity and selectivity for the hydrodeoxygenation of vanillin to produce 2-methoxy-4-methylphenol. The catalyst features atomically dispersed palladium single atoms and clusters, along with strong metal-support interactions, leading to superior catalytic performance and potential for the design of fully exposed metal catalysts.

NANO RESEARCH (2021)

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Article Multidisciplinary Sciences

Phosphorus coordinated Rh single-atom sites on nanodiamond as highly regioselective catalyst for hydroformylation of olefins

Peng Gao et al.

Summary: Single-atom Rh catalysts show superior activity in olefins hydroformylation but limited success in regioselectivity control. By developing a Rh1 single-atom catalyst with nanodiamond as support, the catalyst achieved good to excellent regioselectivities in hydroformylation of arylethylenes, comparable to homogeneous counterparts. The coordination interaction between Rh-1 and surface phosphorus species was clarified by P-31 solid-state NMR and X-ray absorption spectroscopy.

NATURE COMMUNICATIONS (2021)

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Article Multidisciplinary Sciences

Neighboring Pd single atoms surpass isolated single atoms for selective hydrodehalogenation catalysis

Chiheng Chu et al.

Summary: Research shows that neighboring Pd single atom catalysts can maintain their high selectivity and greatly enhance the activity for hydrogenation of carbon-halogen bonds through cooperative interactions between adjacent atoms. This promising hydrogenation performance presents a new approach for manipulating the activity and selectivity of single atom catalysts.

NATURE COMMUNICATIONS (2021)

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Article Chemistry, Multidisciplinary

Theoretical insights into catalytic CO2 hydrogenation over single-atom (Fe or Ni) incorporated nitrogen-doped graphene

Preeyaporn Poldorn et al.

Summary: Effective and economic catalysts are crucial for the conversion of CO2 into clean energy. In this study, periodic DFT calculations were used to investigate the reaction mechanisms for CO2 hydrogenation on Fe-N3Gr and Ni-N3Gr surfaces, demonstrating that trans-HCOOH formation is feasible at low temperatures.

JOURNAL OF CO2 UTILIZATION (2021)

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Article Chemistry, Multidisciplinary

Ru single atoms for efficient chemoselective hydrogenation of nitrobenzene to azoxybenzene

Bo Wu et al.

Summary: The study shows that chemoselective hydrogenation of nitrobenzene to azoxybenzene can be achieved using Ru single atoms coordinated with oxygen atoms in CeO2, offering a selectivity of 88.2%. This work provides a new strategy for the development of an efficient and green catalytic route.

GREEN CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Tandem catalyzing the hydrodeoxygenation of 5-hydroxymethylfurfural over a Ni3Fe intermetallic supported Pt single-atom site catalyst

Ge Meng et al.

Summary: A single-atom site catalyst (SAC) with dual reactive sites of isolated Pt single atoms and the Ni3Fe intermetallic support (Pt-1/Ni3Fe IMC) was reported for tandem catalysis of the hydrodeoxygenation of 5-hydroxymethylfurfural (5-HMF), exhibiting high catalytic performance at a low reaction temperature. Experimental and computational studies confirmed that Pt-1/Ni3Fe IMC can facilitate the hydrodeoxygenation reaction through a tandem mechanism.

CHEMICAL SCIENCE (2021)

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Review Chemistry, Physical

Metal single-atom catalysts for selective hydrogenation of unsaturated bonds

Zhiyi Sun et al.

Summary: Selective hydrogenation is widely used in various fields, and single atom catalysts show excellent catalytic performance by reducing the particle size to the single atom level. Research progress indicates that synthesis methods, composition content, monatomic coordination, and the charge relationship between metal and carrier all affect the catalytic performance of single atom catalysts.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Nanoscience & Nanotechnology

Isolated Palladium Atoms Dispersed on Silicoaluminophosphate-31 (SAPO-31) for the Semihydrogenation of Alkynes

Jun Wang et al.

Summary: Supported single-atom catalysts are at the forefront of heterogeneous catalysis, with physicochemical properties that are highly interesting. This study demonstrates an efficient postsynthesis method for constructing singly dispersed palladium atoms on SAPO-31, showing promising application prospects in the semihydrogenation of alkynes. The catalyst exhibited outstanding performance in the semihydrogenation of phenylacetylene and 1-chloro-4-ethynylbenzene, as well as high activity in triethoxysilane oxidation, with retention of atomic dispersion and catalytic activity at high temperatures.

ACS APPLIED NANO MATERIALS (2021)

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Article Chemistry, Physical

Multivalent Sn species synergistically favours the CO2-into-HCOOH conversion

Jun Wu et al.

Summary: The research demonstrates that multivalent Sn species synergistically activate CO2, HCOO* adsorption, and electron transfer, thereby facilitating the conversion of CO2 into HCOOH by Sn-based catalysts.

NANO RESEARCH (2021)

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Review Chemistry, Multidisciplinary

Selective Hydrogenation over Supported Metal Catalysts: From Nanoparticles to Single Atoms

Leilei Zhang et al.

CHEMICAL REVIEWS (2020)

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Styrene Hydroformylation with In Situ Hydrogen: Regioselectivity Control by Coupling with the Low-Temperature Water-Gas Shift Reaction

Tianbo Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Prospects of Heterogeneous Hydroformylation with Supported Single Atom Catalysts

Jonas Amsler et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Relationship between Atomic Scale Structure and Reactivity of Pt Catalysts: Hydrodeoxygenation of m-Cresol over Isolated Pt Cations and Clusters

Joaquin Resasco et al.

ACS CATALYSIS (2020)

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Tuning Polarity of Cu-O Bond in Heterogeneous Cu Catalyst to Promote Additive-free Hydroboration of Alkynes

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Single-Atom Cobalt Catalysts for Electrocatalytic Hydrodechlorination and Oxygen Reduction Reaction for the Degradation of Chlorinated Organic Compounds

Ning Li et al.

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High-Efficiency Oxygen Reduction to Hydrogen Peroxide Catalyzed by Nickel Single-Atom Catalysts with Tetradentate N2O2 Coordination in a Three-Phase Flow Cell

Yulin Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Facile Synthesis of Kilogram-Scale Co-Alloyed Pt Single-Atom Catalysts via Ball Milling for Hydrodeoxygenation of 5-Hydroxymethylfurfural

Tao Gan et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

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Fabricating Pd isolated single atom sites on C3N4/rGO for heterogenization of homogeneous catalysis

Ninghua Fu et al.

NANO RESEARCH (2020)

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Fe Single Atoms and Fe2O3 Clusters Liberated from N-Doped Polyhedral Carbon for Chemoselective Hydrogenation under Mild Conditions

Ruirui Yun et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Highly Efficient Hydrogenation of Nitroarenes by N-Doped Carbon-Supported Cobalt Single-Atom Catalyst in Ethanol/Water Mixed Solvent

Huanjun Wang et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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High-Density and Thermally Stable Palladium Single-Atom Catalysts for Chemoselective Hydrogenations

Ying Ma et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Physical

Controlling N-doping type in carbon to boost single-atom site Cu catalyzed transfer hydrogenation of quinoline

Jian Zhang et al.

NANO RESEARCH (2020)

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Article Chemistry, Physical

Atomically Dispersed Co Catalyst for Efficient Hydrodeoxygenation of Lignin-Derived Species and Hydrogenation of Nitroaromatics

Longkang Zhang et al.

ACS CATALYSIS (2020)

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Article Nanoscience & Nanotechnology

Direct Synthesis of Atomically Dispersed Palladium Atoms Supported on Graphitic Carbon Nitride for Efficient Selective Hydrogenation Reactions

Fenglian Hu et al.

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Article Chemistry, Applied

On the mechanism of H-2 activation over single-atom catalyst: An understanding of Pt-1/WOx in the hydrogenolysis reaction

Maoxiang Zhou et al.

CHINESE JOURNAL OF CATALYSIS (2020)

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Iridium Single-Atom Catalyst Performing a Quasi-homogeneous Hydrogenation Transformation of CO2 to Formate

Xianzhao Shao et al.

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An electrodeposition approach to metal/metal oxide heterostructures for active hydrogen evolution catalysts in near-neutral electrolytes

Michael J. Kenney et al.

NANO RESEARCH (2019)

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Au-catalysed free-standing wurtzite structured InAs nanosheets grown by molecular beam epitaxy

Qiang Sun et al.

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Hao Li et al.

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Liberating N-CNTs Confined Highly Dispersed Co-Nx Sites for Selective Hydrogenation of Quinolines

Wanbing Gong et al.

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Pocketlike Active Site of Rh1/MoS2 Single-Atom Catalyst for Selective Crotonaldehyde Hydrogenation

Yang Lou et al.

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Atomic layer deposited Pt-Ru dual-metal dimers and identifying their active sites for hydrogen evolution reaction

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First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands

Lukas Alig et al.

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Article Green & Sustainable Science & Technology

Greenhouse gas CO2 hydrogenation to fuels: A thermodynamic analysis

Kaisar Ahmad et al.

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Palladium-bearing intermetallic electride as an efficient and stable catalyst for Suzuki cross-coupling reactions

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Structure of the catalytically active copper-ceria interfacial perimeter

Aling Chen et al.

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Insights into Nitrate Reduction over Indium-Decorated Palladium Nanoparticle Catalysts

Sujin Guo et al.

ACS CATALYSIS (2018)

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Article Chemistry, Physical

Highly Durable Platinum Single-Atom Alloy Catalyst for Electrochemical Reactions

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ADVANCED ENERGY MATERIALS (2018)

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Article Chemistry, Multidisciplinary

Ordered Porous Nitrogen-Doped Carbon Matrix with Atomically Dispersed Cobalt Sites as an Efficient Catalyst for Dehydrogenation and Transfer Hydrogenation of N-Heterocycles

Yunhu Han et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Article Chemistry, Physical

Vapor-Phase Hydrodeoxygenation of Guaiacol to Aromatics over Pt/HBeta: Identification of the Role of Acid Sites and Metal Sites on the Reaction Pathway

Lei Nie et al.

CHEMCATCHEM (2018)

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Article Engineering, Environmental

Degradation mechanism, kinetics, and toxicity investigation of 4-bromophenol by electrochemical reduction and oxidation with Pd-Fe/graphene catalytic cathodes

Dandan Xu et al.

CHEMICAL ENGINEERING JOURNAL (2018)

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Review Chemistry, Multidisciplinary

Bright Side of Lignin Depolymerization: Toward New Platform Chemicals

Zhuohua Sun et al.

CHEMICAL REVIEWS (2018)

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Article Chemistry, Physical

Single cobalt sites in mesoporous N-doped carbon matrix for selective catalytic hydrogenation of nitroarenes

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Defect Sites in Ultrathin Pd Nanowires Facilitate the Highly Efficient Electrochemical Hydrodechlorination of Pollutants by H*(ads)

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Identification of Active Hydrogen Species on Palladium Nanoparticles for an Enhanced Electrocatalytic Hydrodechlorination of 2,4-Dichlorophenol in Water

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Effects of dispersed MoS2 catalysts and reaction conditions on slurry phase hydrocracking of vacuum residue

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Isolated Single-Atom Pd Sites in Intermetallic Nanostructures: High Catalytic Selectivity for Semihydrogenation of Alkynes

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Performance of Cu-Alloyed Pd Single-Atom Catalyst for Semihydrogenation of Acetylene under Simulated Front-End Conditions

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CO2 hydrogenation to lower olefins on a high surface area K-promoted bulk Fe-catalyst

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Preparation of Pd-Fe/graphene catalysts by photocatalytic reduction with enhanced electrochemical oxidation-reduction properties for chlorophenols

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Single atom dispersed Rh-biphephos&PPh3@porous organic copolymers: highly efficient catalysts for continuous fixed-bed hydroformylation of propene

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Highly-active nickel phosphide hydrotreating catalysts prepared in situ using nickel hypophosphite precursors

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Atomic-level insights in optimizing reaction paths for hydroformylation reaction over Rh/CoO single-atom catalyst

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Cobalt Encapsulated in N-Doped Graphene Layers: An Efficient and Stable Catalyst for Hydrogenation of Quinoline Compounds

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Pd-Pb Alloy Nanocrystals with Tailored Composition for Semihydrogenation: Taking Advantage of Catalyst Poisoning

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Single-Atom Pd1/Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene

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Palladium Nanoparticles Encapsulated in Core-Shell Silica: A Structured Hydrogenation Catalyst with Enhanced Activity for Reduction of Oxyanion Water Pollutants

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Enhanced Fe2O3 Reducibility via Surface Modification with Pd: Characterizing the Synergy within Pd/Fe Catalysts for Hydrodeoxygenation Reactions

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Formation of a Pt12 Cluster by Single-Atom Control That Leads to Enhanced Reactivity: Hydrogenation of Unreactive Olefins

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Gas-phase hydrodeoxygenation of guaiacol over iron-based catalysts. Effect of gases composition, iron load and supports (silica and activated carbon)

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