期刊
SMALL
卷 -, 期 -, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.202207509
关键词
2D ionic salts; hydrogen-bonding; ionic interation; radical; stokes shift; natural bond orbital (NBO) analysis
2D materials have attracted great interest, but the stability of ultra-thin nanosheets remains a challenge. A new study addresses the problem by synthesizing a free-standing 2D ionic salt, which is supported by a strong hydrogen bond. The research not only contributes to the construction of novel materials but also deepens the understanding of hydrogen bonding interactions.
2D materials have attracted great interest since the report of graphene. However, because of the fragile stability of ultra-thin nanosheets, most studies are restricted to sheets maintained by strong covalent or coordination bonds. The research on which kind of bonds can maintain the free-standing existence of 2D nanosheets is still of great significance. Recently, 2D ionic salts are successfully synthesized on substrates, but whether 2D ionic salts can free-stand is still a problem. Herein this problem is addressed by a free-standing 2D ionic salt (thickness: approximate to 2 nm) exfoliated from a 4,4 '-bipyridinium hydrochloride salt crystal. The stability of this 2D salt is supported by a strong N-H center dot center dot center dot Cl hydrogen (H)-bonding assisted ionic interaction (17.99 kcal mol(-1)), which is verified by density functional theory calculation and natural bond orbital analysis. The salt crystal has strong air-stable radicals inside and the 2D ionic salt exhibits red fluorescence in solution and in solid-state, especially in solution the stokes shifts are very large (approximate to 386 nm). This breakthrough work is not only beneficial for the construction of novel 2D materials but also for the understanding of H-bonding interactions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据