☆ 4.7 Review

A comprehensive review of recent advances in the synthesis and application of metal-organic frameworks (MOFs) for the adsorptive sequestration of pollutants from wastewater

SEPARATION AND PURIFICATION TECHNOLOGY (2023)

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Article Biodiversity Conservation

Removal of polystyrene nanoplastics from aqueous solutions by a novel magnetic zeolite adsorbent

Hanghang Zhao et al.

Summary: In this study, a new magnetic adsorbent was successfully synthesized to remove polystyrene nanoplastics (PSNPs) from aqueous solutions. The adsorption amount of PSNPs by the magnetic adsorbent increased with the initial concentration and temperature of PSNPs. Factors such as solution pH, co-existing anions, and ionic strength significantly influenced the removal of PSNPs. The adsorption process of PSNPs by the magnetic adsorbent was well fitted by the pseudo-second-order and Sips models.

HUMAN AND ECOLOGICAL RISK ASSESSMENT (2023)

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Article Chemistry, Multidisciplinary

In Situ Synthesis of Bismuth Nanoclusters within Carbon Nano-Bundles from Metal-Organic Framework for Chloride-Driven Electrochemical Deionization

Yong Liu et al.

Summary: The authors proposed a novel strategy to synthesize ultrasmall bismuth nanoclusters and applied them in electrochemical deionization to address global freshwater scarcity. This method achieved ultrafast desalination and outstanding stability.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Article Chemistry, Applied

Mesoporous MOF composite for efficient removal of uranium, methyl orange, methylene blue, and Congo red dyes from aqueous solutions

Suresh Koppula et al.

Summary: The MOF-2@Al2O3 composite material shows excellent adsorption performance in efficiently removing uranium and azo dyes from water, demonstrating good reusability for up to five cycles. Studies on various parameters indicate its promising potential for practical applications in water treatment.

APPLIED ORGANOMETALLIC CHEMISTRY (2022)

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Article Agricultural Engineering

Carbon nanotube incorporated eucalyptus derived activated carbon-based novel adsorbent for efficient removal of methylene blue and eosin yellow dyes

Shailesh K. Yadav et al.

Summary: A novel carbon nanotube-incorporated eucalyptus-derived activated carbon-based adsorbent was synthesized for the removal of dyes from wastewater. The maximum adsorption efficiency for methylene blue and eosin yellow was found to be 49.61 and 49.15 mg/g, respectively, with the pseudo second order model best describing the reaction kinetics involved in the process. This activated carbon adsorbent shows great promise for water decontamination applications.

BIORESOURCE TECHNOLOGY (2022)

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Article Engineering, Environmental

Supramolecular recognition PVDF/PVA ultrafiltration membrane for rapid removing aromatic compounds from water

Qingchen Lu et al.

Summary: This study developed a polyvinylidene fluoride (PVDF) ultrafiltration membrane with the ability to remove aromatic compounds from water. The membrane used size matching and supramolecular recognition to remove aromatic compounds, while exhibiting hierarchical filtration characteristics when removing mixed solutions of proteins and aromatic compounds. Additionally, the membrane showed strong supramolecular recognition of phenolphthalein and had good reusability.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

Highly efficient and selective Hg(II) removal from water by thiol-functionalized MOF-808: Kinetic and mechanism study

Chenghan Ji et al.

Summary: MOF-808-SH is an effective metal-organic framework adsorbent with high Hg(II) adsorption capacity and ultrafast adsorption kinetics, showing high selectivity and excellent recyclability in batch experiments. This study indicates the potential of MOF-808-SH to remove Hg(II) from wastewater.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Environmental Sciences

Metal-organic frameworks with different oxidation states of metal nodes and aminoterephthalic acid ligand for degradation of Rhodamine B under solar light

Dhanaprabhu Pattappan et al.

Summary: Metal-organic frameworks (MOFs) have shown potential as effective visible light photocatalysts for degrading dyes. Among nickel, iron, and titanium-based MOFs, Fe-MOF exhibited the highest dye degradation efficiency and stability under solar light irradiation, attributed to its ability to suppress photoinduced charge recombination. Furthermore, the photodegradation of dye using Fe-MOF followed first-order kinetics and was mainly driven by superoxide anion radicals.

CHEMOSPHERE (2022)

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Review Environmental Sciences

Advanced catalytic ozonation for degradation of pharmaceutical pollutants-A review

Eliasu Issaka et al.

Summary: The advanced catalytic ozonation process shows significant effectiveness in removing refractory organic compounds and degrading toxic organic pollutants in wastewater. Heterogeneous catalytic ozonation can effectively overcome the disadvantages of homogeneous catalytic ozonation, providing higher catalytic stability and efficiency.

CHEMOSPHERE (2022)

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Article Environmental Sciences

Estimation of tetracycline antibiotic photodegradation from wastewater by heterogeneous metal-organic frameworks photocatalysts

Jafar Abdi et al.

Summary: This study investigated the potential of various machine learning methods to estimate tetracycline photodegradation efficiency on different metal-organic frameworks. CatBoost was found to be the most reliable model and accurately predicted tetracycline removal by MOFs.

CHEMOSPHERE (2022)

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Article Chemistry, Physical

Efficient removal of antimonate from water by yttrium-based metal-organic framework: Adsorbent stability and adsorption mechanism investigation

Qiao Li et al.

Summary: Efficient Y-based MOFs were synthesized for effective adsorption of Sb(V) from water, showing high stability, excellent recyclability, and promising potential for Sb(V) removal, making them a valuable adsorbent for wastewater treatment.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2022)

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Article Chemistry, Physical

SiO2 based nanocomposite for simultaneous magnetic removal and discrimination of small pollutants in water

Simona Bettini et al.

Summary: A nanocomposite adsorbent material was synthesized to efficiently remove aromatic analytes dissolved in water through chemical adsorption. The nanocomposite consists of a magnetic iron oxide core coated with SiO2 and can achieve a removal efficiency of up to 93% for certain pollutants. Additionally, the material was decorated with plasmonic Ag nanoparticles to enhance surface enhanced Raman scattering (SERS) signals for further pollutant discrimination.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2022)

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Article Chemistry, Multidisciplinary

Binary Solvent System Composed of Polar Protic and Polar Aprotic Solvents for Controlling the Dimensionality of MOFs in the Solvothermal Synthesis

Rajib Moi et al.

Summary: The nature of solvent, pH, temperature, reactant stoichiometry, concentration of precursors, and counterions are crucial factors that influence the synthesis of MOFs. These parameters play a role in determining the formation of crystalline product and dictate the overall network dimension or topology.

CRYSTAL GROWTH & DESIGN (2022)

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Article Chemistry, Applied

A bifunctional 3D porous Zn-MOF: Fluorescence recognition of Fe3+ and adsorption of congo red/methyl orange dyes in aqueous medium

Lingling Gao et al.

Summary: Zn-MOF is a bifunctional 3D porous metal-organic framework with high stability and excellent adsorption performance for CR and MO dyes. It also exhibits sensitive recognition of Fe3+ ions.

DYES AND PIGMENTS (2022)

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Review Thermodynamics

Recent advances on cobalt metal organic frameworks (MOFs) for photocatalytic CO2 reduction to renewable energy and fuels: A review on current progress and future directions

Wei Keen Fan et al.

Summary: The growing demand for renewable energy and fuels due to environmental issues from fossil fuel combustion has led to a high demand for the production of renewable energy and fuels. Solar energy-based phototechnology is highly sought after for renewable fuel production, but current materials exploration for this technology lacks efficiency. Cobalt-based metal organic frameworks have shown promise as photocatalysts for CO2 reduction due to their simplicity in preparation, high photoactivity, and stability.

ENERGY CONVERSION AND MANAGEMENT (2022)

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Article Environmental Sciences

Water-stable metal organic framework-199@polyaniline with high-performance removal of copper II

Quan Yuan et al.

Summary: In this study, MOF-199 coated with polyaniline (MOF-199@PANI) composite was fabricated as an efficient adsorbent for Cu2+ in water. The composite exhibited high adsorption capacity, attributed to the porous structure of MOF-199 and the complexation between Cu2+ and the imine moieties in PANI.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2022)

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Article Chemistry, Inorganic & Nuclear

Modulating Carbon Dioxide Storage by Facile Synthesis of Nanoporous Pillared-Layered Metal-Organic Framework with Different Synthetic Routes

Mozhgan Parsaei et al.

Summary: A novel Zn(II)-based metal-organic framework, MUT-4, has been successfully synthesized and its CO2 adsorption performance can be optimized by adjusting the synthetic methods.

INORGANIC CHEMISTRY (2022)

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Article Chemistry, Physical

Simple electrodeposition of a novel lanthanide-based porous tri-metallic metal-organic framework grown onto Ni-foam support as a novel binder-free electrode for supercapacitors

Mustafa Aghazadeh et al.

Summary: The novel three mixed metal-organic framework (TM-MOF) demonstrated high specific capacity, high-rate capability, and outstanding cycling stability, making it a promising candidate for supercapacitors.

IONICS (2022)

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Article Biochemical Research Methods

Synthesis of metal-organic framework @molecularly imprinted polymer adsorbents for solid phase extraction of organophosphorus pesticides from agricultural products

Yang Li et al.

Summary: In this study, a novel core-shell structural zeolitic imidazolate framework-8 @molecularly imprinted polymers were successfully synthesized and used as adsorbents for the solid-phase extraction of organophosphorus pesticides. The hybrid composites exhibited specific recognition and fast adsorption capacity for organophosphorus pesticides. This method proved to be sensitive, convenient, and efficient and could potentially be applied for the design of new adsorbents for trace contaminants.

JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES (2022)

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Article Green & Sustainable Science & Technology

Self-sustained bioelectrical reduction system assisted iron-manganese doped metal-organic framework membrane for the treatment of electroplating wastewater

Hanwen Wang et al.

Summary: Heavy metals pose a serious threat to human health, and their efficient removal from wastewater remains a technical challenge. In this study, a self-sustained bioelectrical reduction system (SBRS) was developed for the efficient purification of heavy metal wastewater. A novel metal-organic framework membrane (FM-MOFM) based on a conductive substrate was used as the catalytic cathode electrode. The SBRS demonstrated high removal efficiency for copper, zinc, chromium, and nickel ions, as well as organic substrates in simulated electroplating wastewater. The study highlights the potential of SBRS for simultaneous heavy metal removal from electroplating wastewater.

JOURNAL OF CLEANER PRODUCTION (2022)

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Article Environmental Sciences

Hydroxyapatite-based adsorbents: Applications in sequestering heavy metals and dyes

Andrew N. Amenaghawon et al.

Summary: Hydroxyapatite (HAp) is a versatile material used primarily in bone regeneration and has emerged as a promising adsorbent for sequestering contaminants from wastewater, such as heavy metals and dyes. Research on HAp-based adsorbents for treating heavy metal- and dye-contaminated wastewater has become increasingly popular due to its eco-friendliness and unique adsorption properties. Studies have shown that HAp-based adsorbents are effective in sequestering heavy metals and dyes from solution, providing a low-cost option for adsorptive wastewater treatment.

JOURNAL OF ENVIRONMENTAL MANAGEMENT (2022)

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Article Environmental Sciences

Highly efficient Hg2+ removal via a competitive strategy using a Co-based metal organic framework ZIF-67

Jiacheng Zhou et al.

Summary: In this study, a Co-based MOF (ZIF-67) was utilized to successfully separate Hg2+ ions from wastewater. The stronger coordination ability of Hg2+ with the organic ligand enabled efficient separation. ZIF-67 demonstrated excellent adsorption capacity and sustainable recyclability.

JOURNAL OF ENVIRONMENTAL SCIENCES (2022)

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Article Engineering, Environmental

Surface imprinted polymer on a metal-organic framework for rapid and highly selective adsorption of sulfamethoxazole in environmental samples

Guohao Cheng et al.

Summary: Hierarchically ordered porous vinyl-functionalized UIO-66 was utilized to prepare a surface molecular imprinted polymer (MIP-IL@UIO-66) for the rapid and highly selective adsorption of sulfamethoxazole (SMZ) in water. The resulting MIP-IL@UIO-66 showed ultrafast equilibrium rate, large adsorption capability, excellent adsorption selectivity, and good reusability. The adsorption performance of SMZ onto MIP-IL@UIO-66 was superior to that of a commercial solid phase extraction (SPE) adsorbent, with recoveries of 91-106% in water, soil, egg, and pork samples.

JOURNAL OF HAZARDOUS MATERIALS (2022)

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Article Engineering, Environmental

Preparation of multivariate zirconia metal-organic frameworks for highly efficient adsorption of endocrine disrupting compounds

Lizhen Han et al.

Summary: The preparation of multivariate Zr-MOFs via mixed-ligands strategy allows for the control of morphology, adsorption, and removal properties, with 57%TCPP@MOF-808 showing excellent stability and high adsorption capacity for endocrine disrupting compounds. The use of 57%TCPP@MOF-808 as sorbent in dispersive solid-phase extraction led to successful extraction of EDCs with high recoveries and enrichment factors, demonstrating its potential in environmental pollutant detection.

JOURNAL OF HAZARDOUS MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Fabrication of nanoscale core-shell structured lead azide/porous carbon based on a metal-organic framework with high safety performance

Zhenzhan Yan et al.

Summary: In this study, a carbon-based lead azide with a carbon shell coating (LA/C) was prepared using a lead-containing MOF as the precursor material. The LA/C exhibited reduced electrostatic sensitivity and increased flame sensitivity, thanks to the coating effect and excellent electrical and thermal conductivity of the carbon shell. High-speed photography of the initiation process showed that LA/C has a very short initiation time (less than 1 ms) and excellent detonation ability. The properties of LA/C were found to be better than those of previously reported pure LA and most modified LA materials. These findings provide a new perspective for synthesizing high-performance carbon-based primary explosives with a core-shell structure.

NEW JOURNAL OF CHEMISTRY (2022)

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Review Environmental Sciences

Micro/macrostructure and multicomponent design of catalysts by MOF-derived strategy: Opportunities for the application of nanomaterials-based advanced oxidation processes in wastewater treatment

Xiaoman Li et al.

Summary: MOF-derived catalysts are emerging as excellent precursors for optimizing performance in various AOPs by delicate design of structure/composition, with important advances in Fenton, persulfate-based AOPs, photocatalysis, electrochemical processes, and hybrid AOPs. The relationship between unique micro/macrostructure and/or multicomponent features and performance optimization in mass transfer, catalytic efficiency, stability, and recyclability has been clarified, providing insights for practical application in wastewater treatment.

SCIENCE OF THE TOTAL ENVIRONMENT (2022)

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Article Engineering, Chemical

A remarkable adsorbent for denitrogenation of liquid fuel: Ethylenediaminetetraacetic acid-grafted metal-organic framework, MOF-808

Md Mahmudul Hassan Mondol et al.

Summary: Removal of nitrogen-containing compounds (NCCs) from fuel is essential for clean energy. A new adsorbent, MOF808_EDTA, was obtained by grafting EDTA onto a metal-organic framework (MOF808), which showed remarkable performances in NCCs removal and is highly reusable.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

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Article Chemistry, Multidisciplinary

Nitrogen-Doped Carbon Networks with Consecutive Conductive Pathways from a Facile Competitive Carbonization-Etching Strategy for High-Performance Energy Storage

Siliang Liu et al.

Summary: A competitive carbonization-etching strategy was employed to prepare nitrogen-doped carbon polyhedron@carbon nanosheet hybrids, which exhibited excellent electrochemical performances as supercapacitor electrodes, including outstanding specific capacitance, high energy density, and long cycle life.

SMALL (2022)

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Article Chemistry, Inorganic & Nuclear

Green route of flexible Al-MOF synthesis with superior properties at low energy consumption assisted by ultrasound waves

Rana Al-Attri et al.

Summary: Metal-organic framework MIL-53(Al) was successfully prepared using sonication irradiation for the first time, and the sonochemical-assisted method showed superior characteristics and thermal stability compared to the conventional hydrothermal method. The short sonication time and low temperature synthesis conditions resulted in samples with higher surface area and narrower size distribution.

SOLID STATE SCIENCES (2022)

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Article Acoustics

An alternative technique for determining the number density of acoustic cavitation bubbles in sonochemical reactors

Aissa Dehane et al.

Summary: This paper introduces a novel technique that links the chemistry of a single bubble to the overall chemistry in a sonochemical reactor, in order to determine the number of active bubbles in a sonicated solution. The impact of ultrasonic frequency on the number density of bubbles is studied and compared with existing literature data, showing a high level of consistency.

ULTRASONICS SONOCHEMISTRY (2022)

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Article Engineering, Environmental

Electrochemically mediated precipitation of phosphate minerals for phosphorus removal and recovery: Progress and perspective

Yicheng Wang et al.

Summary: Phosphorus is an essential element for organisms, but the natural phosphorus cycle has been disrupted by overexploitation and discharge into water bodies. Electrochemically induced phosphate precipitation offers a potential solution for phosphorus recovery by creating a localized high pH environment. Factors such as pH, current density, electrode configuration, and water matrix affect the performance of electrochemical systems. Future research should focus on evaluating long-term performance, developing an automatic process for harvesting deposits, and assessing economic feasibility.

WATER RESEARCH (2022)

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Review Food Science & Technology

Plant-Based Proteins: The Good, Bad, and Ugly

William R. Aimutis

Summary: The growing global population will lead to an increased demand for protein, particularly plant-based protein, which is considered sustainable, healthy, ethical, and relatively inexpensive. However, utilizing plant-based proteins in novel food formulations remains challenging.

ANNUAL REVIEW OF FOOD SCIENCE AND TECHNOLOGY (2022)

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Article Multidisciplinary Sciences

Atomically unveiling the structure-activity relationship of biomacromolecule-metal-organic frameworks symbiotic crystal

Linjing Tong et al.

Summary: The authors refine the structure-function relationship of biomacromolecules-metal-organic frameworks (BMOFs) by identifying the atomic-level structure and revealing differences in structure upon different crystallization pathways. They also find that the nanoarchitecture significantly affects the bioactivity of the BMOFs.

NATURE COMMUNICATIONS (2022)

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Review Chemistry, Multidisciplinary

Recent Progress in Adsorptive Removal of Water Pollutants by Metal-Organic Frameworks

Mohammadreza Beydaghdari et al.

Summary: Difficulty in accessing clean water due to pollution is a serious challenge, and the use of metal-organic frameworks for wastewater treatment shows promise in addressing the issue.

CHEMNANOMAT (2022)

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Article Environmental Sciences

Thermally activated mango peels hydrochar for fixed-bed continuous flow decontamination of Pb(II) ions from aqueous solution

I. K. Rind et al.

Summary: Thermally activated hydrochars prepared from mango peels have shown promising potential in removing lead ions from contaminated drinking water, especially when activated at 400 degrees Celsius. Experimental results fit well with various kinetic models, indicating that ACH 400 is suitable for lead removal in water samples.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY (2022)

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Article Engineering, Environmental

COD removal of wastewater from hydrothermal carbonization of food waste: Using coagulation combined activated carbon adsorption

Ruixiong Hu et al.

Summary: The combination of coagulation and activated carbon adsorption can effectively reduce the COD in HTC wastewater and enhance its biodegradability, making it suitable for further biochemical treatment.

JOURNAL OF WATER PROCESS ENGINEERING (2022)

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Article Biotechnology & Applied Microbiology

Removal of environmental contaminants of emerging concern using metal-organic framework composite

Melvin S. Samuel et al.

Summary: This study investigates the adsorption characteristics of pharmaceutical pollutants using CuBTC@NH2 composite. The post-synthetic modification of CuBTC@NH2 greatly improves the physicochemical characteristics of the MOF, resulting in differences in the adsorption behavior of pharmaceutical pollutants such as IBF and ACE from aqueous solutions. The results demonstrate the potential of the CuMOF@NH2 composite to remove pharmaceutical pollutants from toxic wastewater.

ENVIRONMENTAL TECHNOLOGY & INNOVATION (2022)

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Article Chemistry, Physical

Adsorption property of fluoride in water by metal organic framework: Optimization of the process by response surface methodology technique

Yiqiong Yang et al.

Summary: In this study, three types of metal-organic frameworks adsorbents were used to remove fluoride from wastewater, and the adsorption conditions were optimized. Among them, aluminum metal-organic frameworks showed the best adsorption performance. The study also revealed that pH was the most important factor influencing fluoride removal by one of the metal-organic frameworks.

SURFACES AND INTERFACES (2022)

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Article Chemistry, Multidisciplinary

High-performance and selective adsorption of ZIF-8/MIL-100 hybrids towards organic pollutants

Yukun Zhong et al.

Summary: This study synthesized metal-organic framework composites and evaluated their effectiveness in removing organic pollutants. The ZIF-MIL-4 composite showed high adsorption capacity and selectivity, as well as significant regeneration ability. The main interactions between ZIF-MIL-4 and the pollutants were weak coordination, electrostatic, hydrogen bonding, and π-π stacking interactions.

NANOSCALE ADVANCES (2022)

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Article Multidisciplinary Sciences

Fine-tuning the dye adsorption capacity of UiO-66 by a mixed-ligand approach

Chompoonoot Nanthamathee et al.

Summary: The study utilizes a mixed ligand synthetic approach to fine-tune and enhance the dye adsorption capacity in UiO-66 and its mixed ligand derivatives. The impact of different ligands on adsorption performance is achieved through a synergistic interplay between electrostatic interaction and hydrogen bonding.

HELIYON (2022)

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Article Materials Science, Multidisciplinary

An efficient ultrasound assisted electrospinning synthesis of a biodegradable polymeric Ni-MOF supported by PVA- fibrous network as a novel CH4 adsorbent

Taher Shahriari et al.

Summary: In this study, Ni-MOF was synthesized using ultrasound irradiation and then immobilized in a PVA fibrous polymeric network using electrospinning. The Ni-MOF/PVA fibrous network showed potential as an adsorbent for CH4 gas adsorption.

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING (2022)

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Article Chemistry, Physical

Ultraweak chemiluminescence enhanced on the surface of lanthanide metal-organic framework nanosheets synthesized by ultrasonic wave

Chunxia Huang et al.

Summary: Lanthanide metal-organic frameworks (Ln-MOFs) were synthesized using the ultrasonic method and applied to enhance chemiluminescence emission. The catalytic properties of Ln-MOFs improved CL performance by increasing the generation of ROS, resulting in enhanced CL emission. This approach provides insights for developing novel CL systems based on advanced materials.

APPLIED SURFACE SCIENCE (2022)

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Article Chemistry, Physical

Two-Dimensional Layered Heterostructures of Nanoporous Carbons Using Reduced Graphene Oxide and Metal-Organic Frameworks

Nitish Kumar et al.

Summary: Two-dimensional layered carbon heterostructures with controlled porosity and high graphitic degree have attracted considerable attention. This study introduces a practical approach using reduced graphene oxide and metal-organic framework synergy to achieve 2D nanoporous highly graphitic carbons. These hybrid materials have shown a significant increase in capacitance compared to bare graphene oxide precursors, and the symmetric supercapacitor device exhibits high specific energy and specific power in an ionic liquid electrolyte.

CHEMISTRY OF MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Efficient Metal-Oriented Electrodeposition of a Co-Based Metal-Organic Framework with Superior Capacitive Performance

Yan Han et al.

Summary: An efficient cathodic electrodeposition method was developed to coat Co-based metal-organic frameworks (Co-MOF) on carbon fiber cloth (CFC), commonly used in energy fields. The use of a highly active Co metal surface promoted the nucleation and growth of Co-MOF in 3D rodlike crystal bundles. The resulting Co-MOF/CFC electrode exhibited a high areal capacitance, cycling stability, and rate capability. The assembled all-solid-state supercapacitor device (Co-MOF/CFC//AC) showed excellent energy density and power density. This work provides an effective approach for the electrosynthesis of MOF films and their use in energy storage and conversion fields.

CHEMSUSCHEM (2022)

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Article Chemistry, Physical

Electrospinning NH2-MIL-101/PAN nanofiber mats: A promising catalyst with Lewis acidic and basic bifunctional sites for organic transformation reactions

Hassan M. A. S. Hassan et al.

Summary: Metal-organic frameworks (MOFs) have unique characteristics that make them excellent candidates for catalysis purposes. This study presents a direct approach for integrating MOFs into nanofibers, resulting in enhanced catalytic performance in organic transformation reactions. The method is simple, low-cost, and offers an intriguing platform for tailoring MOF materials in the future.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2022)

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Review Chemistry, Inorganic & Nuclear

Metal-organic frameworks template-directed growth of layered double hydroxides: A fantastic conversion of functional materials

Guangfu Wang et al.

Summary: Template derivatization of metal-organic frameworks (MOFs) is an effective strategy for preparing functionalized materials. Chemically treated MOF precursors can be transformed into layered double hydroxides (LDHs), which enhance the stability, conductivity, and mass transfer capability of MOFs. This review summarizes the progress of MOF-derived LDHs and discusses their applications in the energy and environment fields.

COORDINATION CHEMISTRY REVIEWS (2022)

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Article Environmental Sciences

Degradation of toxic agrochemicals and pharmaceutical pollutants: Effective and alternative approaches toward photocatalysis

A. Saravanan et al.

Summary: The concern regarding the remediation of environmental pollution has been growing in recent years, especially in the treatment of pollutants released from pharmaceutical and agricultural sectors. Photocatalysis has gained attention for its low cost, high efficiency, and eco-friendly approach in pollutant degradation.

ENVIRONMENTAL POLLUTION (2022)

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Article Environmental Sciences

Endocrine disrupting chemicals (EDCs) in environmental matrices: Occurrence, fate, health impact, physio-chemical and bioremediation technology

Aris Ismanto et al.

Summary: Endocrine disrupting chemicals (EDCs) have adverse impacts on human and environmental well-being, being associated with diseases such as cancer, cardiovascular risk, behavioral disorders, autoimmune defects, and reproductive diseases. Conventional treatment methods are insufficient to fully remove EDCs from water, necessitating the use of advanced psychochemical and biological treatments. The lack of laws regarding acute concentration limits of EDCs in various water sources contributes to the intensified concerns about these mixed contaminants. Further data is needed to address the risks associated with the presence of EDCs in the environment.

ENVIRONMENTAL POLLUTION (2022)

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Article Environmental Sciences

Metal organic framework UiO-66 incorporated ultrafiltration membranes for simultaneous natural organic matter and heavy metal ions removal

Yi Wang et al.

Summary: This work fabricated a new type of UiO-66 incorporated polysulfone ultrafiltration membranes, which exhibited enhanced antifouling properties and heavy metal ions removal efficiency. The incorporation of UiO-66 fillers improved the hydrophilicity, porosity, and HA removal ratios of the membranes. The modified membranes also showed excellent antifouling abilities and were highly-effective in removing heavy metal ions.

ENVIRONMENTAL RESEARCH (2022)

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Review Environmental Sciences

Research progress of metal organic frameworks and their derivatives for adsorption of anions in water: A review

Xuanjie Huang et al.

Summary: Anion pollution in water is a significant issue, and the adsorption method using MOFs has shown great potential for removal. This article explores the adsorption of various anions by different types of MOFs, discusses their influencing factors and regeneration performance.

ENVIRONMENTAL RESEARCH (2022)

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Article Engineering, Environmental

Metal-organic framework-derived CuCo/carbon as an efficient magnetic heterogeneous catalyst for persulfate activation and ciprofloxacin degradation

Ming-Ming Chen et al.

Summary: In this study, an efficient and easily recycled CuCo/C catalyst was successfully synthesized through one-step carbonization of the Cu@Co-MOF-71 precursor, showing a high degradation efficiency of 90% for ciprofloxacin (CIP) and good stability and reusability. Moreover, the study investigated the superiority of CuCo/C in activating PMS for degrading CIP, as well as the intermediate products and possible degradation pathways.

JOURNAL OF HAZARDOUS MATERIALS (2022)

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Article Biochemistry & Molecular Biology

Removal of arsenic by metal organic framework/chitosan/carbon nanocomposites: Modeling, optimization, and adsorption studies

Nastaran Zare Akha et al.

Summary: In this study, nanocomposites synthesized from metal organic framework, carbon nanotube/graphene oxide, and natural polysaccharide were used as adsorbents for the removal of arsenic from water. The Zn-BDC@CT/GO composite exhibited higher adsorption capacity than Zn-BDC@CT/CNT. The process parameters were optimized using response surface methodology, and the adsorption behavior was well described by the pseudo-second-order model and the Freundlich model. The adsorbent demonstrated good reusability even after multiple adsorption-desorption cycles.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2022)

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Article Chemistry, Physical

Synthesis of hollow Fe, Co, and N-doped carbon catalysts from conducting polymer-metal-organic-frameworks core-shell particles for their application in an oxygen reduction reaction

Quoc Hao Nguyen et al.

Summary: In this study, hollow Fe, Co, and nitrogen co-doped carbon catalyst with high surface area and uniformly distributed Fe and Co species was prepared, demonstrating excellent ORR performance, stability, and tolerance to methanol crossover.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

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Article Chemistry, Physical

Removal of aqueous pharmaceuticals by magnetically functionalized Zr-MOFs: Adsorption Kinetics, Isotherms, and regeneration

Fankang Zhao et al.

Summary: In this study, a magnetically functionalized Zr-MOF (Fe3O4@MOF-525) was synthesized as an adsorbent for the removal of pharmaceuticals. The adsorption performance of Fe3O4@MOF-525 was improved due to the increase of micropore volume and specific surface area caused by defects. The adsorbent showed excellent adsorption capacity and recyclability, making it a promising candidate for water treatment.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

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Review Environmental Sciences

Adsorption behaviour of pollutants: Heavy metals, radionuclides, organic pollutants, on clays and their minerals (raw, modified and treated): A review

Raman Novikau et al.

Summary: This review examines the adsorption of heavy metals, radionuclides, and organic pollutants on clays/clay minerals and their composites under diverse conditions and deals with the applications of these materials in waste management engineering. It also discusses the efficiency and mechanisms of pollutant adsorption on treated and modified clays, as well as the beneficial effects of such modification/treatment on adsorption performance, reusability, and in vivo/in vitro toxicity.

JOURNAL OF ENVIRONMENTAL MANAGEMENT (2022)

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Review Engineering, Environmental

Activated carbon versus metal-organic frameworks: A review of their PFAS adsorption performance

Paola S. Pauletto et al.

Summary: This review focuses on recent research results on the adsorption of PFAS on activated carbons and metal-organic frameworks. It highlights the potential for further modifications of activated carbons to enhance PFAS adsorption, and the unique features of metal-organic frameworks in providing acid-base complexation and specific interaction sites.

JOURNAL OF HAZARDOUS MATERIALS (2022)

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Article Engineering, Environmental

Synthesis of chitosan composite of metal-organic framework for the adsorption of dyes; kinetic and thermodynamic approach

Tooba Saeed et al.

Summary: The iron metal-organic framework composite CS/MOF-235 was synthesized and its adsorption performance for methylene blue and methyl orange was investigated. The results showed that CS/MOF-235 had much higher adsorption capacity than MOF-235 and chitosan. The adsorption mechanisms may involve hydrogen bonding, pi-pi bonding, pore-filling, electrostatic interactions, and chemisorption.

JOURNAL OF HAZARDOUS MATERIALS (2022)

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Article Polymer Science

High Performance of UiO-66 Metal-Organic Framework Modified with Melamine for Uptaking of Lead and Cadmium from Aqueous Solutions

Alaa S. Abdelmoaty et al.

Summary: In this study, UiO-66 metal-organic framework (MOF) was prepared and modified with melamine (MUiO-66) to enhance the adsorption properties in liquid-phase adsorption. The results showed that MUiO-66 had a notable adsorption capacity for Pb and Cd(II) ions, fitting well with the pseudo-second-order kinetic and Langmuir models. Moreover, MUiO-66 exhibited good desorption and reusability characteristics. Therefore, these materials have great importance in the adsorption of heavy metals from wastewater.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS (2022)

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Article Engineering, Chemical

Catalytic nanofiber composite membrane by combining electrospinning precursor seeding and flowing synthesis for immobilizing ZIF-8 derived Ag nanoparticles

Zenghui Mai et al.

Summary: A Ag@PAN catalytic nanofiber composite membrane was successfully fabricated, characterized by various techniques, and demonstrated high catalytic performance in p-NP conversion reaction. The membrane showed excellent repeatability and maintained high catalytic activity even after multiple cycles of catalysis experiments.

JOURNAL OF MEMBRANE SCIENCE (2022)

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Article Chemistry, Physical

Facile preparation of a remarkable MOF adsorbent for Au(III) selective separation from wastewater: Adsorption, regeneration and mechanism

Yingbi Chen et al.

Summary: In this study, a novel Zr-based MOF (DONA-MOF) was synthesized and its adsorption performance was systematically evaluated. Results showed that DONA-MOF had excellent removal effect on Au(III) through monolayer chemisorption. Additionally, DONA-MOF exhibited remarkable adsorption capacity and selectivity, and maintained good removal effect after multiple cycles.

JOURNAL OF MOLECULAR LIQUIDS (2022)

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Article Chemistry, Physical

In situ anodic electrodeposition of two-dimensional conductive metal-organic framework@nickel foam for high-performance flexible supercapacitor

Hongxing Jia et al.

Summary: Metal-organic frameworks (MOFs) are promising materials for energy storage due to their large specific surface area and defined porosity. However, their utilization in supercapacitors has been hindered by poor conductivity. Recently, 2D conductive MOFs have emerged, and an anodic electrodeposition (AED) approach has been developed to fabricate uniformly deposited 2D conducting MOFs on nickel foam, which can be directly used as electrodes for supercapacitors without any additives. Electrochemical measurements have demonstrated the superior performance of these 2D conducting MOFs in both aqueous and organic electrolytes, highlighting the advantages of the AED approach over traditional methods.

JOURNAL OF POWER SOURCES (2022)

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Article Chemistry, Multidisciplinary

Synthesis and characterization of boehmite/metal - Organic framework of type AlO(OH)/MOF-74(Zn) for photocatalytic degradation of Congo red dye

Shabnam Sohrabnezhad et al.

Summary: In this study, a novel composite photocatalyst, AlO(OH)/MOF-74(Zn), was synthesized through a simple, fast, and low-cost method for the degradation of Congo Red dye. The nanocomposite was characterized and showed promising optical and catalytic properties. Optimization of variables yielded the best conditions for dye removal. The AlO(OH)/MOF-74(Zn) photocatalyst exhibited high catalytic performance, removing approximately 94% of the tested dye under visible light irradiation.

JOURNAL OF THE CHINESE CHEMICAL SOCIETY (2022)

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Article Chemistry, Multidisciplinary

Understanding Solvothermal Growth of Metal-Organic Framework Colloids for CO2 Capture Applications

Pei-Fang Hsieh et al.

Summary: This study demonstrated the synthesis of metal-organic framework (MOF) colloids via a solvothermal growth process using electrospray-differential mobility analysis (ES-DMA). The results showed the effects of synthetic parameters on the properties of Cu-MOF, and confirmed the correlation between mobility size increase and crystallinity. The experiment also showed the good CO2 adsorption ability of synthesized Cu-MOF.

LANGMUIR (2022)

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Article Chemistry, Analytical

Ultrasonic aided synthesis of a novel mesoporous cobalt-based metal-organic framework and its application in Cr(III) ion determination in centrum multivitamin and real water samples

Omar A. Fouad et al.

Summary: A Co-based metal organic framework (Co-MOF) was synthesized and used as an electroactive material in carbon paste electrode for the determination of Cr(III) ions. The Co-MOF exhibited nanometric, mesoporous character and hydrophobicity, making it a fascinating material for ionophore applications. The proposed carbon paste electrode showed high accuracy and precision in the determination of Cr(III) ions in various samples.

MICROCHEMICAL JOURNAL (2022)

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Article Chemistry, Applied

A simple, robust, and efficient structural model to predict thermal stability of zinc metal-organic frameworks (Zn-MOFs): The QSPR approach

Mojtaba Moharramnejad et al.

Summary: The thermal stability of MOFs is crucial for their applications. In this study, a precise model was developed to estimate the thermal stability of MOF compounds with zinc SBUs, based on several descriptors.

MICROPOROUS AND MESOPOROUS MATERIALS (2022)

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Article Biochemistry & Molecular Biology

Removal of Acidic Organic Ionic Dyes from Water by Electrospinning a Polyacrylonitrile Composite MIL101(Fe)-NH2 Nanofiber Membrane

Jiao Jia et al.

Summary: This study presents a one-step electrospinning method for preparing a nanofiber metal-organic framework filter, which consists of a polyacrylonitrile nanofiber membrane composite with an iron/2-amino-terephthalic acid-based metal-organic framework. The composite material demonstrated efficient adsorption and separation of acidic organic ionic dyes from aqueous solution, with good crystallinity and uniform distribution of the metal-organic framework crystals.

MOLECULES (2022)

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Article Chemistry, Physical

Surface modification of metal-organic frameworks under sublimated iron-atmosphere by controlled carbonization for boosted oxygen evolution reaction

Katam Srinivas et al.

Summary: This study develops a cost-effective and efficient electrocatalyst for oxygen evolution reaction (OER) through an innovative vapor phased iron-doping strategy. The electrocatalyst, Ni-M@C-400, demonstrates exceptional OER activity with low overpotential and significantly reduced thermodynamic barrier. This work provides a new approach to develop electrocatalysts for water electrolysis.

NANO RESEARCH (2022)

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Review Environmental Sciences

Recent advances in performance improvement of Metal-organic Frameworks to remove antibiotics: Mechanism and evaluation

Jingwen Zhang et al.

Summary: This review summarizes the effectiveness of Metal-Organic Frameworks (MOFs) based adsorption and photocatalysis strategies in addressing antibiotic pollution and environmental repair. Strategies to improve the properties of MOFs for removal and the removal mechanisms are discussed. Additionally, new evaluation methods for MOFs to remove antibiotics are presented.

SCIENCE OF THE TOTAL ENVIRONMENT (2022)

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Article Engineering, Chemical

Synergistic disulfide sites of tetrathiafulvalene-based metal-organic framework for highly efficient and selective mercury capture

Yuanzhe Tang et al.

Summary: This study proposed a tetrathiafulvalene-functionalized adsorbent with synergistic disulfide sites for highly efficient Hg2+ capture. The prepared adsorbent showed high Hg2+ affinity and excellent chemical stability, allowing for fast reduction of Hg2+ concentration below the drinking water standard. Additionally, the adsorbent demonstrated outstanding renewable performance in adsorption-regeneration cycles.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

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Article Acoustics

Cyclodextrin metal-organic framework by ultrasound-assisted rapid synthesis for caffeic acid loading and antibacterial application

Mofei Shen et al.

Summary: This study successfully investigated the ultrasound-assisted rapid synthesis of cyclodextrin metal-organic framework for caffeic acid loading and antibacterial application. The obtained crystal had a cubic structure with uniform size, and showed a higher loading rate of caffeic acid compared to traditional cyclodextrin. The crystal also exhibited good antibacterial activity.

ULTRASONICS SONOCHEMISTRY (2022)

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Review Engineering, Environmental

Potential of biocompatible calcium-based metal-organic frameworks for the removal of endocrine-disrupting compounds in aqueous environments

Fahren Fazzer Sukatis et al.

Summary: Rapid urbanization, industrialization, and population growth have led to an increased release of emerging contaminants, including endocrine-disrupting compounds (EDCs), into the aquatic environment. This poses a threat to human health and the environment, even at low levels. Therefore, there is an urgent need for new water treatment technologies to effectively remove EDCs. Calcium-based metal-organic frameworks (Ca-MOFs) are promising adsorbents due to their stability, biocompatibility, and low cost compared to traditional porous materials. Ca-MOFs have shown the ability to selectively extract a significant amount of contaminants, making them suitable for water purification. This review discusses the potential of Ca-MOFs in adsorbing EDCs, including their preparation methods, adsorption mechanisms, removal capacity, water stability, and recyclability. It supports future efforts in synthesizing biocompatible MOFs as an environmental treatment technology to improve water quality and human health.

WATER RESEARCH (2022)

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Article Engineering, Environmental

Tuning the primary selective nanochannels of MOF thin-film nanocomposite nanofiltration membranes for efficient removal of hydrophobic endocrine disrupting compounds

Ruobin Dai et al.

Summary: This study demonstrates that the water transport nanochannels in metal organic framework (MOF) incorporated thin-film nanocomposite (TFN) membranes can be tuned to enhance the removal of endocrine disrupting compounds (EDCs).

FRONTIERS OF ENVIRONMENTAL SCIENCE & ENGINEERING (2022)

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Article Chemistry, Multidisciplinary

Mitigated Aging in a Defective Metal-Organic Framework Pillared Polymer of an Intrinsic Porosity Hybrid Membrane for Efficient Gas Separation

Chenxu Geng et al.

Summary: This study presents an alternative approach to alleviate the physical aging of PIM-based membranes by pillaring them with defect-engineered metal-organic framework nanoparticles. These nanoparticles prevent the collapse of micropores in the membrane, while also providing fast diffusion pathways and facilitating CO2 transport. The resulting mixed matrix membranes display high CO2 permeability and CO2/N-2 selectivity, with only a slight reduction in CO2 permeability observed under long-term operating conditions.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

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Article Chemistry, Multidisciplinary

Preparation and Characterization of Multi-Doped Porous Carbon Nanofibers from Carbonization in Different Atmospheres and Their Oxygen Electrocatalytic Properties Research

Tao Wang et al.

Summary: Recently, electrospun nanofiber composites as electrocatalysts for ORR and OER have gained significant attention. Transition metal elements and heteroatomic doping are effective methods to enhance their performance. The construction of electrocatalysts based on MOF electrospun nanofibers has become a research hotspot. This work synthesized nickel-cobalt zeolitic imidazolate frameworks and obtained nitrogen, oxygen, and sulfur-doped bimetal porous carbon nanofiber catalysts through high-temperature carbonization treatment. The catalysts exhibited different performances for ORR and OER, with Ni1Co2-ZIFs/PAN-Ar showing the best ORR activity and Ni1Co1-ZIFs/PAN-Air exhibiting the best OER performance.

NANOMATERIALS (2022)

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Article Chemistry, Physical

Microwave-assisted solvothermal synthesis of defective zirconium-organic framework as a recyclable nano-adsorbent with superior adsorption capacity for efficient removal of toxic organic dyes

Linh Ho Thuy Nguyen et al.

Summary: In this study, a Zr-based metal-organic framework nanomaterial was successfully synthesized using a microwave method. The material exhibited a highly defective structure and showed excellent adsorption performance for organic dyes. The high adsorption activity can be attributed to the defect sites in the framework and its physisorption character.

COLLOID AND INTERFACE SCIENCE COMMUNICATIONS (2022)

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Article Engineering, Environmental

A rapid and efficient adsorptive removal of lead from water using graphene oxide prepared from waste dry cell battery

Md Golam Azam et al.

Summary: This research focused on the adsorption of lead (Pb) from water using graphene oxide (GO) synthesized from waste dry cell battery graphite. The study showed that GO successfully removed 98.87% of Pb (10 ppm) in just 20 minutes under optimal conditions. The oxygenated groups on the surface of GO played a crucial role in the adsorption process.

JOURNAL OF WATER PROCESS ENGINEERING (2022)

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Article Nanoscience & Nanotechnology

Trifluoromethyl-Modified Hierarchical Nanoporous Metal-Organic Framework Nanoparticles for Adsorption of Fluorine-Containing Pesticides

Chang Yang et al.

Summary: An -CF3-modified hierarchical nanoporous metal-organic framework (HP-MOF) was developed for the efficient adsorption of fluorine-containing pesticides. The HP-MOF showed satisfactory adsorption capacity through hydrophobic and pi-pi interactions. This study suggests that HP-Fe-CF3 has the potential to be an ideal candidate for emerging solid nanoparticle adsorbents.

ACS APPLIED NANO MATERIALS (2022)

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Article Chemistry, Inorganic & Nuclear

Gadolinium metal-organic frameworks realizing ultra-high adsorption capacity toward anionic dyes in aqueous solution

Yunyun Lei et al.

Summary: With the development of various industries, the impact of organic dye wastewater discharge on the environment cannot be ignored. In this study, gadolinium metal organic frameworks were synthesized and exhibited excellent adsorption performance for anionic dyes in water, particularly Congo red.

JOURNAL OF SOLID STATE CHEMISTRY (2022)

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Article Engineering, Chemical

Two novel Zn (II)-based metal-organic frameworks for rapidly selective adsorption and efficient photocatalytic degradation of hazardous aromatic dyes in aqueous phase

Ruixue Wu et al.

Summary: Two novel Zn-MOFs, namely Zn-MOF 1 and Zn-MOF 2, constructed from 5-hydroxy-2-nitroisophthalic acid and 5-(4-carboxy-2nitrophenoxy)-2-nitroisophthalic acid, have been synthesized and characterized. Both materials exhibit exceptional dye adsorption capacities and photocatalytic degradation capabilities.

ADVANCED POWDER TECHNOLOGY (2022)

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Article Engineering, Chemical

Recent advances in hydrochar application for the adsorptive removal of wastewater pollutants

Joshua O. Ighalo et al.

Summary: Hydrochars, special biochars obtained from hydrothermal processes, have been explored as effective adsorbents for the removal of various pollutants from wastewater. They possess unique properties such as high adsorption efficiency, regeneration ability, and environmental friendliness.

CHEMICAL ENGINEERING RESEARCH & DESIGN (2022)

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Article Environmental Sciences

Association between exposure to organophosphorus pesticides and the risk of diabetes among US Adults: Cross-sectional findings from the National Health and Nutrition Examination Survey

Xianwei Guo et al.

Summary: This study investigated the effect of organophosphorus pesticides (OPPs) exposure on the prevalence of diabetes in American adults. The results showed a positive correlation between urinary OPPs metabolites concentrations and diabetes. Combined exposure to OPPs metabolites was significantly associated with diabetes, with diethylphosphate being the major contributor. These findings add credibility to the argument that OPP exposure might trigger diabetes.

CHEMOSPHERE (2022)

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Article Environmental Sciences

Highly efficient metal-organic frameworks adsorbent for Pd(II) and Au(III) recovery from solutions: Experiment and mechanism

Jiali Tang et al.

Summary: With the increasing demand for precious metals such as palladium (Pd) and gold (Au) in modern industry, the discharge of Pd(II) and Au(III) wastewater has caused environmental pollution and resource shortage. In this study, a new metal-organic frameworks adsorbent (MOF-AFH) was synthesized to efficiently separate Pd(II) and Au(III) from water. The experimental results demonstrate that MOF-AFH has excellent selectivity and can be repeatedly used with a removal effect of over 90%.

ENVIRONMENTAL RESEARCH (2022)

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Article Chemistry, Inorganic & Nuclear

Self-supporting flexible metal-organic framework-based electrospun nanofibers membrane for efficient removal of tetracycline from aqueous solutions

Xiang Li et al.

Summary: A self-supporting flexible nanofibers membrane was designed and constructed using electrospinning, with zeolitic imidazolate framework-8 nanoparticles incorporated, for the removal of tetracycline hydrochloride from water. The nanofibers membrane had good flexibility and achieved high adsorption capacity. The adsorption mechanism was determined to be chemical and monolayer adsorption. The composite adsorbent showed excellent reusability.

JOURNAL OF SOLID STATE CHEMISTRY (2022)

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Article Chemistry, Applied

Base-functionalized metal-organic frameworks for highly efficient removal of organic acid pollutants from water

Panpan Liu et al.

Summary: The base-functionalized metal-organic framework DETA-UiO-66 showed remarkable adsorption capacity and rate for organic acid pollutants. The H-2-FA adsorption process on DETA-UiO-66 was found to be spontaneous and exothermic, making it a potential candidate for wastewater treatment and recovery. The material can be easily recovered and reused multiple times without significant loss in adsorption capacity or rate.

MICROPOROUS AND MESOPOROUS MATERIALS (2022)

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Article Chemistry, Inorganic & Nuclear

Rapid detection of lamotrigine by a water stable fluorescent lanthanide metal-organic framework sensor

Yunxiao Ma et al.

Summary: In this study, a new type of Tb-MOF with two emitting centers was designed and synthesized for detection of lamotrigine (LTG). The ratiometric fluorescence sensing technique was applied to improve the accuracy of LTG detection. The Tb-MOF exhibited excellent sensitivity with fast response and high recyclability. This research demonstrates the significance of using lanthanide metal-organic frameworks (Ln-MOFs) as platforms for fluorescent sensing.

POLYHEDRON (2022)

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Article Energy & Fuels

Room temperature boronized and phosphated cobalt-nickel metal-organic framework as the electrode material for supercapacitors

Qingli Sui et al.

Summary: In this study, boronation and phosphating were conducted on a cobalt-nickel metal-organic framework (MOF) at room temperature, resulting in a sample with excellent electrochemical properties for supercapacitor electrode materials. Additionally, an asymmetric supercapacitor using this sample achieved high specific energy and cycling stability. This research provides a clever approach to enhance the performance of supercapacitors.

JOURNAL OF ENERGY STORAGE (2022)

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Article Chemistry, Physical

Metal-organic framework (MOF) composites as promising materials for energy storage applications

Yi Peng et al.

Summary: Metal-organic framework (MOF) composites are considered important energy storage materials due to their high porousness, multifunction, various structures, and controllable chemical compositions, but they still face challenges and difficulties in batteries and supercapacitors.

ADVANCES IN COLLOID AND INTERFACE SCIENCE (2022)

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Article Chemistry, Physical

Efficient cobalt-based metal-organic framework derived magnetic Co@C-600 Nanoreactor for peroxymonosulfate activation and oxytetracycline degradation

Wenjia Mao et al.

Summary: In this study, a magnetic carbon material Co@C-600 was synthesized by carbonizing a metal organic frameworks (CUST-563) precursor and the composition of the material was found to change regularly with different carbonization temperatures. The Cobalt-based carbon materials obtained showed good dispersibility and high stability, and exhibited high degradation efficiency in the oxytetracycline degradation process.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2022)

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Article Environmental Sciences

Nickel and iron-based metal-organic frameworks for removal of organic and inorganic model contaminants

Ali Akbar Mohammadi et al.

Summary: Metal-organic frameworks (MOFs) are promising porous nanomaterials in the field of environmental remediation. In this study, Ni-MOF and Fe-MOF were analyzed for their structure using various characterization methods. The results showed that Fe-MOF exhibited remarkable adsorption of organic and inorganic model contaminants, indicating a favorable adsorption process.

ENVIRONMENTAL RESEARCH (2022)

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Article Chemistry, Inorganic & Nuclear

Magnetite Metal-Organic Frameworks: Applications in Environmental Remediation of Heavy Metals, Organic Contaminants, and Other Pollutants

Reza Taghavi et al.

Summary: This paper discusses the threat of environmental pollution caused by human activities and the application of magnetic solid-phase extraction (MSPE) in environmental remediation. MSPE utilizes metal-organic frameworks (MOFs) as sorbents and magnetic components to efficiently remove various types of organic and inorganic pollutants.

INORGANIC CHEMISTRY (2022)

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Article Chemistry, Physical

Mechanochemical synthesis of ferrite/MOF nanocomposite: Efficient photocatalyst for the removal of meropenem and hexavalent chromium from water

Negin Khosroshahi et al.

Summary: Photocatalysts have shown potential in addressing environmental water pollution by efficiently degrading drugs and heavy metals. In this study, novel nanocomposites of NiFe2O4/MOF-808 were prepared and their photocatalytic activity for Meropenem degradation and Cr(VI) reduction was investigated. The results demonstrated that nanocomposites with lower bandgaps exhibited better photocatalytic performance, with degradation occurring in 60 minutes under optimal conditions. The study also highlighted the successful recovery and sustained degradation rate of the catalyst even after multiple cycles.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY (2022)

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Article Chemistry, Inorganic & Nuclear

One-pot solvothermal synthesis of Zr-based MOFs with enhanced adsorption capacity for Cu2+ ions removal

Tong Ling Tan et al.

Summary: In this study, the adsorption behavior of MOF-801 prepared by solvothermal method in the removal of copper ion from water was investigated. The results showed that MOF-801 had good adsorption capacity for Cu2+ and could be reused.

JOURNAL OF SOLID STATE CHEMISTRY (2022)

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Article Materials Science, Multidisciplinary

Sonochemical synthesis of nanoparticles of Cd metal organic framework based on thiazole ligand as a new precursor for fabrication of cadmium sulfate nanoparticles

Akram Karbalaee Hosseini et al.

Summary: The current study reports the fabrication of a new Cd-MOF material, [Cd (DPTTZ) (5-AIP)] (IUST-1), which was synthesized using solvothermal and sonochemical methods. The crystal structure of IUST-1 was characterized using X-ray crystallography and various spectroscopic techniques.

MATERIALS LETTERS (2022)

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Article Chemistry, Analytical

Electrospun polyacrylonitrile /MIL-53(Al) MOF@ SBA-15/ 4, 4′-bipyridine nanofibers for headspace solid-phase microextraction of benzene homologues in environmental water samples with GC-FID detection

Fatemeh Kardani et al.

Summary: In this study, a novel adsorbent was synthesized using a hydrothermal method for the microextraction and determination of benzene homologues in water samples. The method offers the advantages of simplicity, rapidity, cost-effectiveness, sensitivity, and non-invasion.

MICROCHEMICAL JOURNAL (2022)

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Article Chemistry, Analytical

Thin-film microextraction using the metal-organic framework DUT-52 for determining endocrine disrupting chemicals in cosmetics

Adrian Gutierrez-Serpa et al.

Summary: Metal-organic frameworks (MOFs)-based mixed-matrix membranes (MMMs) were used for the determination of personal care products (PCPs) in cosmetic samples. Optimal conditions were carefully selected, and the method showed satisfactory analytical performance. Additionally, the greenness of the method was thoroughly assessed.

MICROCHEMICAL JOURNAL (2022)

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Article Engineering, Chemical

Analogize of metal-organic frameworks (MOFs) adsorbents functional sites for Hg2+ ions removal

Brij Mohan et al.

Summary: This review focuses on the development and properties of metal-organic frameworks (MOFs) as materials for removing mercury ions from water, and compares various functionalities with sulfur functionalities. It provides a useful research framework for addressing mercury pollution.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

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Article Engineering, Chemical

Zinc-based metal-organic framework nanofibers membrane ZIF-65/PAN as efficient peroxymonosulfate activator to degrade aqueous ciprofloxacin

Mengjie Pu et al.

Summary: A novel ZIF-65/PAN nanofiber membrane catalyst was fabricated and used for the degradation of ciprofloxacin in water. The catalytic performance and stability of the catalyst were studied, and the reaction mechanism was speculated. The results show that the ZIF-65/PAN nanofiber membrane exhibits efficient activation of PMS and high degradation efficiency of ciprofloxacin.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

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Article Engineering, Environmental

Effective sequestration of tetracycline and ciprofloxacin from aqueous solutions by Al-based metal organic framework and reduced graphene oxide immobilized alginate biosorbents

Nahyun Kim et al.

Summary: The study successfully enhanced the efficiency of removing TC and CIP from water environments by using Alg@MOF-rGO hydrogel beads, exploring the influencing factors of the adsorption process and kinetic models.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Chemistry, Multidisciplinary

An insight into the bridging role of Co3O4 in MOF-derived binary metal oxide modified sheet-like g-C3N4 for photo-assisted peroxymonosulfate activation

Guangfu Wang et al.

Summary: In this study, a ZCC-SCN catalyst was successfully synthesized through the metal-organic framework derivative modification method and applied in the photo-assisted PMS activation system. The ZCC-SCN catalyst showed enhanced porosity and larger surface area, facilitating substrate adsorption and reactivity. The bridging role of the ternary heterojunction and Co3O4 further improved the catalytic activity. The rapid degradation of tetracycline hydrochloride was driven by the generation of SO4- and O-2(-).

ENVIRONMENTAL SCIENCE-NANO (2022)

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Article Chemistry, Multidisciplinary

Facile synthesis of bismuth terephthalate metal-organic frameworks and their visible-light-driven photocatalytic activities toward Rhodamine B dye

Hoang Ai Le Pham et al.

Summary: The bismuth-terephthalate frameworks (Bi-BDC) were successfully prepared using a facile solvothermal approach in this study. The effects of synthesis temperature on the crystallinity and morphologies of the Bi-BDC frameworks were investigated. The low-temperature prepared Bi-BDC samples showed enhanced light absorption ability and exhibited high removal efficiency of organic pollutant through photocatalytic degradation.

GREEN CHEMISTRY LETTERS AND REVIEWS (2022)

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Article Engineering, Environmental

Removal of microplastics by coagulation treatment in waters and prospect of recycling of separated microplastics: A mini-review

Yu Gao et al.

Summary: Environmental pollution and health risks caused by microplastics in water have gained extensive attention. The coagulation sedimentation process is an effective method for removing microplastics, and this review discusses its advantages and the prospect of recycling microplastics in water.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2022)

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Article Chemistry, Multidisciplinary

Pore space partition of metal-organic frameworks for gas storage and separation

Anh N. Hong et al.

Summary: Pore space partition (PSP) concept is a synthetic design concept that can be used for next-step synthetic planning and execution. PSP provides a tool to design new materials platforms by focusing on chemistry and topology. The growing importance of small-molecule gas storage and separation has led to the development of small-pore materials using the uniquely suited PSP strategy. The partitioned-acs (pacs) platform is the best embodiment of the PSP concept and has resulted in a large family of chemically robust materials with controllable pore metrics and suitable functionalities.

ENERGYCHEM (2022)

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Article Engineering, Environmental

Simultaneous removal of tetracycline and norfloxacin from water by iron-trimesic metal-organic frameworks

Yi Zhou et al.

Summary: This study found that the metal-organic framework (MOF) Fe-BTC can effectively remove tetracycline and norfloxacin from water, and its adsorption performance is higher than most of the previous studies even in the competitive system. Fe-BTC maintained good removal performance in different conditions, demonstrating excellent selectivity and recyclability. The adsorption mechanism of tetracycline and norfloxacin on Fe-BTC is mainly attributed to coordination, pore filling, and pi-pi stacking. Therefore, Fe-BTC shows promise as a material for treating wastewater polluted with complex combinations of antibiotics.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2022)

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Article Chemistry, Multidisciplinary

Thiol-functionalized Zr metal-organic frameworks for efficient removal of Fe3+ from water

Yufei Yuan et al.

Summary: In this study, thiol-functionalized Zr-MOFs were found to have the highest adsorption capacity and fastest kinetics for Fe3+ removal. The material showed high selectivity for Fe3+ and rapidly purified water contaminated with excess Fe3+ to a drinkable level. The findings have significant implications for the purification of water contaminated with heavy metal ions.

CELL REPORTS PHYSICAL SCIENCE (2022)

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Article Chemistry, Multidisciplinary

Preparation of metal-organic frameworks by microwave-assisted ball milling for the removal of CR from wastewater

Fuhua Wei et al.

Summary: Metal-organic frameworks (Sm-MOFs) prepared by microwave-assisted ball milling with a water solution showed good performance in removing organic dye and exhibited thermal stability. The results of dynamics analysis indicated the great potential of Sm-MOF materials in wastewater treatment.

GREEN PROCESSING AND SYNTHESIS (2022)

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Article Chemistry, Physical

Novel high capacity model for copper binary ion exchange on e-waste derived adsorbent resin

Sabah Mariyam et al.

Summary: This study investigates the removal efficiencies of copper by waste printed circuit boards and presents a novel dual site adsorption/ion exchange mechanism. The results show that the activated waste printed circuit boards can effectively remove copper from wastewater solutions and be regenerated for re-use.

ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY (2022)

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Review Engineering, Environmental

A review of heavy metals' removal from aqueous matrices by Metal-Organic Frameworks (MOFs): State-of-the art and recent advances

Nasrin Abdollahi et al.

Summary: Surface water and groundwater contamination by heavy metals is a global serious concern. Adsorption, particularly using metal-organic frameworks (MOFs), has shown potential in removing heavy metals. This review evaluates the potential of various MOFs for heavy metal removal, discusses the mechanisms involved, and compares them with existing technologies.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2022)

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Article Engineering, Environmental

Magnetic metal-organic frameworks for efficient removal of cadmium(II), and lead(II) from aqueous solution

Ahmed F. Abdel-Magied et al.

Summary: The study synthesized two magnetic metal-organic frameworks and investigated their adsorption capacities for Cd(II) and Pb(II). The adsorption efficiency is strongly dependent on the pH of the solution, and the process follows a pseudo-second-order model and fits the Langmuir isotherm model.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2022)

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Article Chemistry, Multidisciplinary

Quick removal of metronidazole from aqueous solutions using metal-organic frameworks

Tina Kalhorizadeh et al.

Summary: This research focuses on evaluating the removal efficiency of metronidazole using two metal-organic frameworks. The results show that NH2-MIL-101-Fe exhibits excellent adsorption and removal efficiency, attributed to its unique metal sites and high specific surface area. This research is expected to promote the application of metal-organic frameworks for antibiotic removal from wastewater.

NEW JOURNAL OF CHEMISTRY (2022)

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Article Engineering, Environmental

Modified magnetic-metal organic framework as a green and efficient adsorbent for removal of heavy metals

Elham Ragheb et al.

Summary: A novel adsorbent was prepared for the fast and selective removal of heavy metal ions Hg(II), Cd(II), and Pb(II). The adsorbent was made by immobilizing tripeptide glutathione on the surface of a magnetic metal-organic framework (Fe3O4-ZrMOF). The adsorbent showed a high adsorption capacity and efficiency, removing 95-99% of the target ions within 20 minutes.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2022)

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Article Chemistry, Multidisciplinary

Facile synthesis of ZnNC derived from a ZIF-8 metal-organic framework by the microwave-assisted solvothermal technique as an anode material for lithium-ion batteries

M. G. Moustafa et al.

Summary: In this study, a microwave-assisted solvothermal technique was used to prepare a zeolitic imidazolate framework-8 (ZIF-8) material within a short period of time. The structural and elemental analysis of the samples before and after annealing were investigated using XRD and XAS. The results showed that the ZIF-8 material transformed into ZnNC after annealing under N-2. The ZnNC electrode exhibited high discharge and charge capacities, as well as improved coulombic efficiency, indicating good stability for subsequent cycles.

NEW JOURNAL OF CHEMISTRY (2022)

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Article Engineering, Multidisciplinary

Ultrasound and microwave assisted-synthesis of ZIF-8 from zinc oxide for the adsorption of phosphate

Loubna Bazzi et al.

Summary: The conversion of solid matters into metal-organic frameworks (MOFs) offers a new method for MOF synthesis. This study focuses on using ultrasound and microwave methods to transform zinc oxide into MOFs with higher conversion rates and excellent phosphate adsorption capacity. The results show the potential of using these methods for the development of MOFs from other inorganic solid resources.

RESULTS IN ENGINEERING (2022)

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Article Chemistry, Multidisciplinary

Facile solvothermal synthesis of a MIL-47(V) metal-organic framework for a high-performance Epoxy/MOF coating with improved anticorrosion properties

Mahmoud Y. Zorainy et al.

Summary: The vanadium-based metal-organic framework MIL-47 demonstrates unique properties and structure. Vanadium pentoxide was used to synthesize the MIL-47 framework, and it showed extended corrosion prevention for an aluminum alloy against artificial seawater.

RSC ADVANCES (2022)

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Article Engineering, Environmental

Metal organic frameworks (MOFs) as a cutting-edge tool for the selective detection and rapid removal of heavy metal ions from water: Recent progress

Mohd Arham Shamim et al.

Summary: Heavy metal poisoning in surface and groundwater is a major global concern, with efforts focused on removing metal ions. Metal organic frameworks show promise for adsorptive removal of heavy metal ions due to their unique properties such as tunable porosity and large surface area.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2022)

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Article Food Science & Technology

Global maps of cropland extent and change show accelerated cropland expansion in the twenty-first century

Peter Potapov et al.

Summary: High-resolution satellite observations are essential for monitoring global progress towards Sustainable Development Goals. The study shows that global cropland area increased by 9% in the first two decades of the twenty-first century, while per-capita cropland area decreased by 10%. This was primarily due to agricultural expansion in Africa and South America, leading to conflicts with the goal of protecting terrestrial ecosystems. Despite a decrease in per-capita cropland area, per-capita annual cropland net primary production increased by 3.5% due to intensified agricultural land use.

NATURE FOOD (2022)

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Article Engineering, Chemical

Zinc-based metal-organic framework nanofibers membrane ZIF-65/PAN as efficient peroxymonosulfate activator to degrade aqueous ciprofloxacin

Mengjie Pu et al.

Summary: A novel peroxymonosulfate (PMS) catalyst, ZIF-65/PAN nanofibers membrane, was fabricated for the efficient degradation of ciprofloxacin in water. The study investigated the physicochemical properties, catalytic performance, stability, and reusability of the catalyst. The results provide novel insights for the application of MOF-based membrane in PMS based advanced oxidation processes.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

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Review Environmental Sciences

A review on adsorptive removal of dyes from wastewater by hydroxyapatite nanocomposites

Shraddha Pai et al.

Summary: Hydroxyapatite is an efficient adsorbent for dye removal, especially when modified to enhance removal efficiency. Nanocomposites of hydroxyapatite show high adsorption capacities, with comprehensive studies on adsorption mechanisms and thermodynamics.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2021)

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Article Green & Sustainable Science & Technology

Synthesis and characterization of NH2-SiO2@Cu-MOF as a high-performance adsorbent for Pb ion removal from water environment

Nima Mohammadi et al.

Summary: This study developed an effective adsorbent NH2-SiO2@Cu-MOF for Pb(II) removal from aqueous environments, showing good adsorption capacity and reusability. The adsorbent exhibited promising performance in selectively removing Pb(II) from water samples.

ENVIRONMENT DEVELOPMENT AND SUSTAINABILITY (2021)

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Article Environmental Sciences

Progress and challenges of metal-organic frameworks-based materials for SR-AOPs applications in water treatment

Danlian Huang et al.

Summary: This paper provides an overview of the application of metal-organic frameworks (MOFs) in sulfate radical (SO4 center dot-) based advanced oxidation processes (SR-AOPs), highlighting the development and challenges in synthesizing different types of MOFs, their combination with other materials, and the construction of catalysts with special structures. It also discusses the mechanisms of MOFs and MOF-based materials as catalysts in activating PMS/PS in different systems, emphasizing the need for further improvements in this field.

CHEMOSPHERE (2021)

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Article Engineering, Environmental

Adsorptive removal of heavy metals from battery industry effluent using MOF incorporated polymeric beads: A combined experimental and modeling approach

Debashis Roy et al.

Summary: In this study, the metal organic framework ZIF-8 was explored as a potential adsorbent for heavy metal ions, with further investigation into its adsorption performance through mixed matrix beads (MMBs). The adsorption capacity of the MMBs for Pb and Cd was found to be high, and a model successfully predicted batch kinetics and interaction parameters.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Article Environmental Sciences

Use of Nanocellulose extracted from grass for adsorption abatement of Ciprofloxacin and Diclofenac removal with phyto, and fish toxicity studies

Tasrin Shahnaz et al.

Summary: The study focused on the adsorption of antibiotic Ciprofloxacin (CPXO) and anti-inflammatory agent Diclofenac (DCF) on Grass nanocellulose (GNC) extracted from Cyprus rotundas grass. Various experimental measures were optimized to study the adsorption process, and the maximum adsorption capacity of GNC for CPXO and DCF were determined. Phytotoxicity studies on plants and acute fish toxicity analysis on zebra fish were conducted to evaluate the effect of treated effluent on biological organisms.

ENVIRONMENTAL POLLUTION (2021)

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Article Chemistry, Physical

Rapid room-temperature synthesis of a porphyrinic MOF for encapsulating metal nanoparticles

Huihui He et al.

Summary: This study successfully prepared a functional and stable porphyrinic metal-organic framework (MOF), PCN-224-RT, as a host for encapsulating metal nanoparticles, thereby avoiding the agglomeration of nanoparticles and providing new possibilities for heterogeneous catalysis.

NANO RESEARCH (2021)

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Review Materials Science, Multidisciplinary

MOF materials as therapeutic agents, drug carriers, imaging agents and biosensors in cancer biomedicine: Recent advances and perspectives

Adam Bieniek et al.

Summary: Recent advances have shown the significant potential of MOFs in cancer diagnostics and treatment, with a vast amount of literature and data requiring systematization. This study aims to consolidate and reflect the latest developments in MOFs applications in medicine, particularly in anticancer therapy, while discussing the potential, challenges, and emerging opportunities in using MOFs for cancer treatment.

PROGRESS IN MATERIALS SCIENCE (2021)

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Article Nanoscience & Nanotechnology

Electrochemical Removal of Organic and Inorganic Pollutants Using Robust Laser-Induced Graphene Membranes

Chidambaram Thamaraiselvan et al.

Summary: The study demonstrated the successful fabrication of porous LIG electrodes on commercial water treatment membranes, showing efficient electrochemical removal of iohexol and chromium(VI). Multiple lasering resulted in significantly improved electrical conductivity of the electrodes, leading to efficient removal of undesirable compounds.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Nanoscience & Nanotechnology

Constructing Mesoporous Adsorption Channels and MOF-Polymer Interfaces in Electrospun Composite Fibers for Effective Removal of Emerging Organic Contaminants

Rui Zhao et al.

Summary: Researchers constructed interconnected mesopores in electrospun zeolitic imidazolate framework-8 (ZIF-8)/polyacrylonitrile (PAN) fibers with the assistance of poly(vinylpyrrolidone) to expose more adsorption sites and improve stability. The obtained fibers showed faster adsorption kinetics and larger adsorption capacity for antibiotic tetracycline removal compared to other strategies, demonstrating great potential for antibiotic drug removal.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Physical

Graphene-based materials for adsorptive removal of pollutants from water and underlying interaction mechanism

Jingyi Wang et al.

Summary: Graphene-based materials are considered ideal candidates for adsorptive removal of water pollutants due to their large surface area and active adsorption sites; the design of adsorbents is based on underlying adsorption mechanisms, and understanding the performance and interaction mechanisms is crucial for future development.

ADVANCES IN COLLOID AND INTERFACE SCIENCE (2021)

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Review Environmental Sciences

Copper bioavailability, uptake, toxicity and tolerance in plants: A comprehensive review

Vinod Kumar et al.

Summary: Copper is an essential element for humans and plants, but excessive intake may have detrimental effects on living systems. Monitoring the bioavailability and exposure levels of copper is crucial for prevention of toxicity, especially focusing on the behavior of copper in the soil-plant system.

CHEMOSPHERE (2021)

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Review Chemistry, Inorganic & Nuclear

Metal-organic frameworks as burgeoning materials for the capture and sensing of indoor VOCs and radon gases

Cui Lai et al.

Summary: This article summarizes the recent advances in the adsorption of indoor VOCs and Rn gas using metal-organic frameworks (MOFs), as well as the sensing technology for indoor VOCs based on the superior adsorption performance of MOFs. It also provides insights into possible future developments and challenges in this field.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Engineering, Environmental

Adsorptive removal of pesticides from water with metal-organic framework-based materials

Md. Mahmudul Hassan Mondol et al.

Summary: The review discusses the use of metal-organic frameworks for removing pesticides from aqueous solutions to alleviate environmental pollution. It highlights the importance of this method and suggests future research directions in the field.

CHEMICAL ENGINEERING JOURNAL (2021)

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Review Engineering, Environmental

Optimal preparation of catalytic Metal-organic framework derivatives and their efficient application in advanced oxidation processes

Danlian Huang et al.

Summary: Metal-organic frameworks (MOFs) derivatives show excellent user-configuration flexibility and improved stability, conductivity, and inherited characteristics after pyrolysis. Although the synthetic method of MOF derivatives is relatively rough, they are gradually being proven as potential alternative catalysts in advanced oxidation processes (AOPs).

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Physical

Microwave-assisted synthesis of Zr-based metal-organic framework (Zr-fum-fcu-MOF) for gas adsorption separation

Hao Liu et al.

Summary: A reliable strategy to synthesize Zr-based metal-organic framework was successfully achieved using microwave assistance, demonstrating high adsorption capacities for various gases, particularly CO2 capture.

CHEMICAL PHYSICS LETTERS (2021)

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Article Environmental Sciences

Recent advances in the application of water-stable metal-organic frameworks: Adsorption and photocatalytic reduction of heavy metal in water

Zhongwu Li et al.

Summary: Water-stable metal organic frameworks (WMOFs) have excellent adsorption properties and can also photocatalytically reduce heavy metal ions, showing great potential for efficient removal of heavy metals from water.

CHEMOSPHERE (2021)

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Review Environmental Sciences

Removal of organic pollutants from aqueous solution using metal organic frameworks (MOFs)-based adsorbents: A review

Audrey Tchinsa et al.

Summary: MOFs have unique properties that make them suitable for adsorptive removal of harmful organic pollutants from aqueous solution. While the introduction of functional groups and other external materials can enhance the performance of MOFs, it also increases manufacturing costs, posing a challenge for large-scale applications.

CHEMOSPHERE (2021)

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Review Environmental Sciences

Adsorptive removal of dyes from wastewater using a metal-organic framework: A review

Md Jamal Uddin et al.

Summary: Metal-organic frameworks (MOFs) are a promising adsorbent for efficient dye removal and degradation in industrial wastewater treatment. The performance of MOFs is influenced by factors such as their structure type, functional groups, ligands, and pH level.

CHEMOSPHERE (2021)

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Article Chemistry, Physical

Microporous metal-organic frameworks against endocrine-disruptor bisphenol A: parametric evaluation and optimization

Shahabaldin Rezania et al.

Summary: This study investigated the performance of two different synthesized metal-organic frameworks (MOFs) for the adsorption of Bisphenol A (BPA) from the aquatic system. It was found that MIL-53 had a higher adsorption efficacy compared to MOF (Ni), and three-parameter isotherm models provided a better description for BPA equilibrium data. The adsorption mechanism was supported by monolayer BPA adsorption theory, showing promising results for the adsorption of BPA using MIL-53.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2021)

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Article Chemistry, Physical

Tetracycline removal from aqueous solution using zirconium-based metal-organic frameworks (Zr-MOFs) with different pore size and topology: Adsorption isotherm, kinetic and mechanism studies

Jing Xia et al.

Summary: Three zirconium-based metal-organic frameworks, UiO-66, NU-1000, and MOF-525, demonstrated excellent adsorption performance for tetracycline removal. The adsorption kinetics were best described by the pseudo-second-order model, with equilibrium rapidly reached within 40 minutes on UiO-66 and NU-1000, and within 120 minutes on MOF-525. The Sips model provided the best fit for the adsorption isotherms, with high maximum Sips adsorption capacities reported for all three MOFs. The pi-pi interaction was found to play a crucial role in the adsorption process.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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Article Environmental Sciences

Aluminum-based metal-organic frameworks for adsorptive removal of anti-cancer (methotrexate) drug from aqueous solutions

Farhad Ahmadijokani et al.

Summary: The study found that NH2-MIL-101 has a higher adsorption capacity for MTX compared to other synthesized MOFs due to its large surface area, total pore volume, positive zeta potential, and polar amino functional groups. Adsorption of MTX onto NH2-MIL-101 follows Langmuir isotherms and pseudo-second-order kinetic equations. Thermodynamic data suggest that adsorption onto NH2-MIL-101 is spontaneous and exothermic, with electrostatic interactions, pi-pi stacking, and H-bonding playing a role in the adsorption mechanism.

JOURNAL OF ENVIRONMENTAL MANAGEMENT (2021)

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Article Environmental Sciences

Electrospun metal-organic frameworks hybrid nanofiber membrane for efficient removal of As(III) and As(V) from water

Qi Guo et al.

Summary: The study successfully imprisoned Zr-based MOF (UiO-66) in a PAN substrate and prepared a hybrid membrane by electrospinning, which can efficiently remove arsenate and arsenite from water. The adsorption kinetics fit the pseudo-second-order model and is dominated by chemisorption, with the adsorption isotherm described by Langmuir model.

ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY (2021)

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Article Polymer Science

Synthesis and Characterization of Cobalt Metal Organic Frameworks Prepared by Ultrasonic Wave-Assisted Ball Milling for Adsorptive Removal of Congo Red Dye from Aqueous Solutions

Ding Chen et al.

Summary: The cobalt metal-organic frameworks (Co-MOFs) prepared by ultrasonic-assisted ball milling showed excellent adsorption performance towards Congo Red, achieving high adsorption capacity and fast adsorption rate.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS (2021)

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Review Chemistry, Inorganic & Nuclear

A comprehensive review on synthetic approaches for metal-organic frameworks: From traditional solvothermal to greener protocols

Dhiraj Sud et al.

Summary: Metal-organic frameworks (MOFs) are porous materials constructed by inorganic metallic centers and organic ligands, widely used in gas purification and catalysis. Recent years have seen a shift towards green chemistry principles in synthesizing MOFs, driving continuous development in material fabrication.

POLYHEDRON (2021)

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Article Biochemistry & Molecular Biology

Removal of heavy metal ion cobalt (II) from wastewater via adsorption method using microcrystalline cellulose-magnesium hydroxide

Ruifeng Wang et al.

Summary: The MCC-magnesium hydroxide composite adsorbent prepared by reacting MCC, magnesium sulfate hexahydrate, and trisodium citrate in an ammonia bath can efficiently adsorb and remove Co(II) ions, with optimal process parameters including an MCC-MH dosage of 2.5 mg/mL, a contact reaction equilibrium time of 50 min, a Co(II) solution pH of 6.0-8.0, an initial Co(II) concentration of 300 mg/L, and a temperature of 303 K. The removal rate of Co(II) solution by MCC-MH was as high as 97.67%, and the maximum adsorption capacity reached 153.84 mg/g.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2021)

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Article Biochemistry & Molecular Biology

Lipase immobilization on a novel class of Zr-MOF/electrospun nanofibrous polymers: Biochemical characterization and efficient biodiesel production

Arastoo Badoei-dalfard et al.

Summary: New nanostructures of ZrMOF/PVP nanofibrous composites were successfully synthesized by electrospinning, showing significant properties such as small particle size distribution, large surface area, and high crystallinity. These nanostructures could lead to novel alternative materials for biological applications. Lipase MG10 was successfully immobilized on the nanofibrous composites, displaying high stability and potency in biodiesel production.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2021)

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Article Chemistry, Physical

Microwave-assisted rapid synthesis and activation of ultrathin trimetal-organic framework nanosheets for efficient electrocatalytic oxygen evolution

Qiling Li et al.

Summary: This study presents a facile method for the rapid synthesis of NiCoFe-based metal-organic framework nanosheets using microwave assistance, achieving rapid synthesis and activation for oxygen evolution reaction (OER) with enhanced electrocatalytic activity.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Facile Synthesis of Two-Dimensional Iron/Cobalt Metal-Organic Framework for Efficient Oxygen Evolution Electrocatalysis

Kai Ge et al.

Summary: A facile synthesis method was reported for the preparation of two-dimensional bimetallic metal-organic frameworks with excellent electrocatalytic activity for the oxygen evolution reaction. Experimental and theoretical studies revealed that the morphology and co-doping of Fe/Co played crucial roles in enhancing the electrocatalytic performance of the material. The simple and efficient synthetic approach is promising for the mass production and future commercialization of functional two-dimensional MOFs with low cost and high yield.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Physical

Effective and structure-controlled adsorption of tetracycline hydrochloride from aqueous solution by using Fe-based metal-organic frameworks

Zhe Zhang et al.

Summary: In this study, three Fe-based MOFs were used as adsorbents to remove TCH, and the adsorption capacity was found to be influenced by their porous properties and open metal sites. Among the MOFs, MIL-101(Fe) with high pore volume, BET surface area and binding energy exhibited excellent TCH adsorption performance. The results provide insights into the surface interactions between MOFs and TCH, which will help in developing efficient MOF-based adsorbents for pollutant removal.

APPLIED SURFACE SCIENCE (2021)

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Article Chemistry, Physical

Nitrogen-containing carbon nano-onions-like and graphene-like materials derived from biomass and the adsorption and visible photocatalytic performance

Lijuan Han et al.

Summary: Nitrogen-containing carbon (NC) materials with different morphologies, including nano-onions-like structure, show high nitrogen content and good adsorption performance, with the nano-onions-like structure exhibiting better visible-light photocatalytic performance. The pyridinic N in the NC materials serves as active sites, while the hollow nano-onions structure helps inhibit desorption of phenol and enhance adsorption performance. In addition, the presence of O-center dot(2-) species and graphite N contribute to the photocatalytic degradation of phenol under visible-light irradiation.

APPLIED SURFACE SCIENCE (2021)

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Article Chemistry, Inorganic & Nuclear

Visible-light-driven and ultrasonic-assisted copper metal-organic frameworks and graphene oxide nanocomposite for decolorization of dyes

Hai-Xin Tian et al.

Summary: The crystalline and nano-sized Cu-tipe and its nanocomposite with graphene oxide (Cu-tipe/GO) were synthesized and characterized. The composite showed higher catalytic efficiencies in photocatalytic and sonocatalytic decolorization of organic dyes compared to most MOF materials. Radicals trapping experiments were conducted to study the active species and degradation mechanism.

JOURNAL OF SOLID STATE CHEMISTRY (2021)

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Article Chemistry, Inorganic & Nuclear

Sono-synthesis of basic metal-organic framework for reusable catalysis of organic reactions in the eco-friendly conditions

Payam Abdolalian et al.

Summary: A functionalized Metal-Organic Framework (MOF) TMU-42 with azine group shows superior catalytic activity, with ultrafast formation of nanorods using ultrasonic irradiation. It demonstrates excellent conversion due to its active and size-selective pores, and retains catalytic activity after multiple cycles.

JOURNAL OF SOLID STATE CHEMISTRY (2021)

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Article Chemistry, Inorganic & Nuclear

Mechanochemical synthesis of three-component metal-organic frameworks for large scale production

Tong Gao et al.

Summary: Two pillared-layer metal-organic frameworks with pcu network were successfully synthesized via mechanochemical reaction, exhibiting high purity and porosity, superior adsorption selectivity, and potential for large-scale production. This method shows promise for one-step gas purification.

JOURNAL OF SOLID STATE CHEMISTRY (2021)

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Article Environmental Sciences

Ethylenediamine-functionalized Zr-based MOF for efficient removal of heavy metal ions from water

Farhad Ahmadijokani et al.

Summary: Ethylenediamine-functionalized Zr-based metal-organic framework (UiO-66-EDA) showed excellent adsorption capability for Pb(II), Cd(II), and Cu(II) metal ions, with adsorption behavior governed by pseudo-second-order kinetic and Langmuir isotherm models. The adsorption process depended on interactions between metal ions and the abundant functional groups on the UiO-66-EDA surface.

CHEMOSPHERE (2021)

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Article Environmental Sciences

A novel ternary heterogeneous TiO2/BiVO4/NaY-Zeolite nanocomposite for photocatalytic degradation of microcystin-leucine arginine (MC-LR) under visible light

Afshin Ebrahimi et al.

Summary: The novel B/T/N-Z nanocomposite effectively removed MC-LR from water, with contact time, catalyst dosage, and pH significantly impacting the removal efficiency. Increasing contact time, catalyst dosage, and acidic pH had positive effects on MC-LR removal.

ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY (2021)

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Article Materials Science, Multidisciplinary

Microwave-assisted solvothermal synthesis of bimetallic metal-organic framework for efficient photodegradation of organic dyes

Hong-Tham T. Nguyen et al.

Summary: The study investigated the synthesis of M/Fe-MOFs using a microwave-assisted solvothermal method, characterized their properties through various techniques, explored their photocatalytic degradation of organic dyes, proposed a mechanism for RhB dye degradation, and evaluated the stability and reusability of the materials. The results are expected to expand the understanding of bimetallic MOF synthesis and applications.

MATERIALS CHEMISTRY AND PHYSICS (2021)

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Article Environmental Sciences

Molecular level study of cadmium adsorption on dithiocarbamate modified chitosan

Zheng Yin et al.

Summary: This study investigated the chelating mechanism of dithiocarbamate chitosan (DTC-CTS) with Cd(II) using XAFS and FTIR spectroscopy, revealing the crucial role of S functional groups and the impact of S content on the adsorption mechanism at a molecular level. The findings suggest that Cd(II) forms outer-sphere complexes at low S content, while inner-sphere complexes are predominant at high S content. This information is essential for evaluating the application of modified chitosan for Cd(II) removal in various environmental settings.

ENVIRONMENTAL POLLUTION (2021)

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Article Biochemistry & Molecular Biology

Solvothermal Synthesis of a Novel Calcium Metal-Organic Framework: High Temperature and Electrochemical Behaviour

Russell M. Main et al.

Summary: The rapid growth in the field of metal-organic frameworks has shown high potential in various applications. Ca-based MOFs are highly desirable for biological and environmental applications due to their low cost and high biocompatibility, but rare due to the ionic character and large size of the Ca2+ ion.

MOLECULES (2021)

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Article Engineering, Chemical

Preparation and Carbonization of Metal Organic Framework Zn(bdc)(ted)0.5 for Enhancing Moisture Resistance and Methane Storage Capacity

Xin Pu et al.

Summary: Zn(bdc)(ted)(0.5) was synthesized for methane storage, with an optimized metal-organic framework reaching a methane adsorption capacity of 15.6 mmol/g. A carbonization strategy was proposed to improve hydrophobicity, showing a water contact angle of 144.2 degrees. The stability of methane storage capacity in humid environments was successfully improved by a carbonized coating on the surface of the MOFs.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2021)

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Article Chemistry, Inorganic & Nuclear

Solvent-Free and Phase-Selective Synthesis of Aluminum Trimesate Metal-Organic Frameworks

Jiahong Li et al.

Summary: Aluminum-based metal-organic frameworks (Al-MOFs) have shown promise as commercially valuable materials due to their wide range of applications, excellent thermal and chemical stabilities, and the abundance of aluminum. The solvent-free synthesis method in this study offers valuable insights for future industrial scale-up production of Al-MOFs and promotes their potential commercialization.

INORGANIC CHEMISTRY (2021)

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Article Chemistry, Physical

Highly efficient and selective removal of anionic dyes from aqueous solution by using a protonated metal-organic framework

Cai-Xia Yu et al.

Summary: The hydrothermal reaction of Zn(NO3)(2)·6H2O with a flexible bipyridyl ligand and 1,3-benzenedicarboxylic acid synthesized a novel metal-organic framework (MOF) that showed high adsorption capacities for anionic dyes in acidic conditions. The adsorbent exhibited excellent selectivity in adsorption and followed pseudo-second-order kinetics, with interactions mainly dominated by electrostatic forces and surface adsorption.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

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Article Chemistry, Physical

One-step synthesis of functional metal organic framework composite for the highly efficient adsorption of tylosin from water

Guohao Cheng et al.

Summary: A novel metal organic framework composite UiO-66-NH2-AMPS was successfully synthesized through one-step polymerization. It exhibited excellent adsorption performance towards tylosin (TYL) in water, with high maximum binding amount and good regeneration efficiency.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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Article Chemistry, Physical

Synthesis and characterization of 1D-Co/Zn MOFs having potential for efficient dye adsorption from wastewater

Kirandeep et al.

Summary: Two stable Metal-organic frameworks, Co-MOF and Zn-MOF, were successfully synthesized by solvothermal method. Characterized by Single Crystal X-ray, thermogravimetric analysis and morphological studies, Co-MOF exhibited significantly good adsorption results for RB5 and MO under optimized conditions.

JOURNAL OF MOLECULAR STRUCTURE (2021)

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Article Chemistry, Multidisciplinary

Responses of Defect-Rich Zr-Based Metal-Organic Frameworks toward NH3 Adsorption

Tatchamapan Yoskamtorn et al.

Summary: This study investigated the structural responses of metal-organic frameworks (MOFs) to external stimuli such as the inclusion of guest molecules and temperature/pressure, highlighting the paramount influence of functional linkers on NH3 affinity and the delicate control of material properties at the molecular level. Neutron and synchrotron diffractions, along with Rietveld refinement and density functional theory calculations, were used to elucidate the responsive adsorption behaviors of defect-rich Zr-based MOFs upon the progressive incorporation of ammonia and variable temperature.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Materials Science, Multidisciplinary

Industrializing metal-organic frameworks: Scalable synthetic means and their transformation into functional materials

Wei Liang Teo et al.

Summary: This review provides an up-to-date summary of the progress towards industrialization of metal-organic frameworks (MOFs), discussing the latest developments in scalable production and processing methods, as well as evaluating their industrial utilization potentials.

MATERIALS TODAY (2021)

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Article Materials Science, Multidisciplinary

Mechanochemistry: Toward green synthesis of metal-organic frameworks

Sylwia Glowniak et al.

Summary: Metal-organic frameworks (MOFs) are receiving special attention for their adjustable pore sizes and high potential in various applications, with mechanochemistry seen as an efficient and environmentally friendly synthesis method.

MATERIALS TODAY (2021)

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Article Chemistry, Applied

Sonochemical synthesis of Zr-based porphyrinic MOF-525 and MOF-545: Enhancement in catalytic and adsorption properties

Kwangsun Yu et al.

Summary: In this study, Zr-based porphyrinic MOF-525 and MOF-545 were successfully synthesized with high purity and uniform size through a sonochemical route, showing the potential of sonochemical synthesis in preparing MOFs with improved textural properties. The sonochemically synthesized MOF samples had more defect sites than conventionally prepared ones, leading to enhanced hydrolysis of dimethyl-4-nitrophenyl phosphate and faster and higher bisphenol-A adsorption.

MICROPOROUS AND MESOPOROUS MATERIALS (2021)

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Article Chemistry, Applied

Rapid ultrasound-assisted synthesis of controllable Zn/Co-based zeolitic imidazolate framework nanoparticles for heterogeneous catalysis

Bingqing Yao et al.

Summary: This study introduces a novel method to predictably synthesize MOF nanoparticles with desired sizes and morphologies through ultrasound-assisted synthesis. Cobalt-doped ZIF-8 with tunable particle sizes and improved nitrogen adsorption-desorption characteristics is achieved, showing enhanced catalytic performance compared to pure ZIF-8 and superior stability compared to monometallic ZIF-67.

MICROPOROUS AND MESOPOROUS MATERIALS (2021)

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Article Environmental Sciences

Recent advances on preparation and environmental applications of MOF-derived carbons in catalysis

Mengjie Hao et al.

Summary: This review summarizes the synthesis strategies of MOF-derived carbons and their potential applications in catalysis, especially in organo-catalysis, photocatalysis, and electrocatalysis. The focus is on the properties of derived carbons and their roles in improving catalytic efficiency.

SCIENCE OF THE TOTAL ENVIRONMENT (2021)

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Article Engineering, Chemical

Furfural separation from aqueous solution by pervaporation membrane mixed with metal organic framework MIL-53(Al) synthesized via high efficiency solvent-controlled microwave

Heng Mao et al.

Summary: Furfural is a typical biomass-derived platform chemical, and traditional production processes are inefficient. This study successfully improved furfural separation performance and achieved high flux and separation factor in aqueous solutions. MAPs/PEBA MMMs have shown great potential for industrial furfural production with long-term stability.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

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Article Chemistry, Multidisciplinary

The Chemistree of Porous Coordination Networks: Taxonomic Classification of Porous Solids to Guide Crystal Engineering Studies

Daniel J. O'Hearn et al.

Summary: New approaches for gas/vapor storage and purification are needed urgently due to issues related to energy consumption, cost and risk associated with current technologies. The emergence of new classes of porous physisorbents, such as PCNs, has led to over 100,000 entries in the CSD MOF subset, with a growing publication rate of over 5,000 per year.

SMALL (2021)

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Article Chemistry, Physical

Improved Electrochemical Performance of a Li1.2Ni0.2Mn0.6O2 Cathode by a Hydrothermal Method with a Metal-Organic Framework as a Precursor

Hao Guan et al.

Summary: Metal-organic frameworks were used as precursors and adsorbents to synthesize a Li1.2Ni0.2Mn0.6O2 cathode material via a hydrothermal method, resulting in improved electrochemical performance compared to conventional synthesis methods.

ACS APPLIED ENERGY MATERIALS (2021)

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Review Chemistry, Multidisciplinary

Metal-organic framework nanosheets and their composites for heterogeneous thermal catalysis: Recent progresses and challenges

Chengqian Cui et al.

Summary: Metal-organic framework nanosheets (MONs) are emerging materials with high surface areas and active sites, favorable for catalytic applications. The synthesis methods, composites, and catalytic performances of MON based nanocatalysts are discussed, offering insights into their potential for heterogeneous catalysis.

CHINESE CHEMICAL LETTERS (2021)

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Article Chemistry, Multidisciplinary

Insights into the Mechanochemical Synthesis of MOF-74

Jethro Beamish-Cook et al.

Summary: Mechanochemical synthesis of MOF-74 from ZnO and H(4)HDTA involves the formation of four short-lived intermediate phases before the final crystallization of highly crystalline MOF-74.

CRYSTAL GROWTH & DESIGN (2021)

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Review Environmental Sciences

A review of bismuth-based photocatalysts for antibiotic degradation: Insight into the photocatalytic degradation performance, pathways and relevant mechanisms

Kena Qin et al.

Summary: This review compares and evaluates the performance, degradation pathways, and potential mechanisms of bismuth-based catalysts and modified materials in antibiotic removal, showing that multi-component photocatalysts perform better than single-component photocatalysts.

ENVIRONMENTAL RESEARCH (2021)

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Article Biochemical Research Methods

Magnetic mesoporous carbon nanosheets derived from two-dimensional bimetallic metal-organic frameworks for magnetic solid-phase extraction of nitroimidazole antibiotics

Huixiao Duo et al.

Summary: Ni/ZnO@C nanosheets with magnetic mesoporous structure were synthesized for the determination of nitroimidazole antibiotics, showing satisfactory adsorption capacity and rapid adsorption kinetics.

JOURNAL OF CHROMATOGRAPHY A (2021)

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Article Chemistry, Analytical

Direct electrochemical synthesis of the copper based metal-organic framework on/in the heteroatoms doped graphene/pencil graphite electrode: Highly sensitive and selective electrochemical sensor for sertraline hydrochloride

Biuck Habibi et al.

Summary: In this study, a simple and innovative electrochemical method was used to synthesize Cu-MOF/SNDGr nanocomposite and develop an electrochemical sensor for detecting the antidepressant drug STLHC. The modified electrode showed excellent electrocatalytic activity and promising potential as an efficient sensor for STLHC determination.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2021)

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Article Engineering, Environmental

Antibiotic residues in the aquatic environment - current perspective and risk considerations

Ciaran Monahan et al.

Summary: Antibiotic use and release pose potential risks to the environment and human health, particularly impacting water environments and the development of resistance bacteria. Presence of antibiotic residues have been detected in Irish waters at levels predicting selection for resistance, with numerous multi-drug resistant bacteria found in water bodies in Ireland and Europe. Risk assessment methodologies play a crucial role in understanding the risks posed by antibiotic residues and assessing potential impacts on human and environmental health.

JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING (2021)

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Article Engineering, Environmental

Aluminum-based metal-organic frameworks (CAU-1) highly efficient UO22+ and TcO4 ions immobilization from aqueous solution

Xin Zhong et al.

Summary: An Al-based metal-organic framework, CAU-1, was synthesized via solvothermal approach with excellent thermostability, large surface area, and superior adsorption capacity for UO22+ and ReO4- ions. The adsorption mechanism involved electrostatic attraction, chelation effect, and nitrogen/oxygen-containing functional groups.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Article Materials Science, Multidisciplinary

Simple and efficient size-controllable engineering of zeolitic imidazolate framework (ZIF-8) and M-ZIF-8 by changing addition order

Daixiong Zhang et al.

Summary: The study introduces a novel method for size-controllable engineering of zeolitic imidazolate framework (ZIF-8) by changing the addition order of substances. Experimental results showed significant size difference and applicability to preparing encapsulating metal precursor.

MATERIALS LETTERS (2021)

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Article Chemistry, Applied

Facile microwave synthesis of zirconium metal-organic framework thin films on gold and silicon and application to sensor functionalization

Leah N. Appelhans et al.

Summary: Zirconium-based metal-organic frameworks, specifically UiO-66 and related frameworks, have been extensively researched for chemical warfare agent decontamination, but their potential for sensing applications is relatively unexplored. This study introduces a simple and rapid microwave assisted synthesis method for growing oriented UiO-66 thin films on unmodified silicon and gold substrates. Additionally, the synthesis of Zr/Ce solid solution thin films of UiO-66 on gold is described, along with the utility of the microwave method for functionalizing sensor architectures with UiO-66 thin films.

MICROPOROUS AND MESOPOROUS MATERIALS (2021)

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Article Chemistry, Inorganic & Nuclear

A New Metal-Organic Framework: Product of Solvothermal Synthesis in 3D-Printed Autoclaves

G. L. Denisov et al.

Summary: Polypropylene autoclave disruption may lead to unexpected product formation when synthesizing metal-organic frameworks, but in some cases it can result in new representatives of this class of crystalline materials.

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY (2021)

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Review Chemistry, Analytical

Recent advances in metal-organic frameworks/membranes for adsorption and removal of metal ions

Mingkun Gao et al.

Summary: Metal-organic frameworks (MOFs) have high specific surface area, tunable microporosity, low skeleton density, and good stability, making them ideal functional materials for detection and removal of metal ions. Current research focuses on balancing permeability and selectivity, developing superior MOFs composites for satisfactory adsorption and separation capacity, such as MOFs membranes.

TRAC-TRENDS IN ANALYTICAL CHEMISTRY (2021)

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Article Chemistry, Physical

Mechanochemical Synthesis of Nickel-Modified Metal-Organic Frameworks for Reduction Reactions

Paulette Gomez-Lopez et al.

Summary: In this study, nickel oxide nanoparticles were successfully incorporated into a metal-organic framework (MOF) structure using a solvent-free mechanochemical strategy. The catalytic potential of the Ni/UiO-66 materials in the hydrogenation reaction of methyl levulinate was investigated under flow conditions, with 5%Ni/UiO-66 showing the best catalytic performance. This work highlights the promising potential of MOFs in biomass upgrading processes.

CATALYSTS (2021)

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Article Environmental Sciences

CaFu MOF as an efficient adsorbent for simultaneous removal of imidacloprid pesticide and cadmium ions from wastewater

Sandeep Singh et al.

Summary: Research has shown that using metal organic frameworks for the adsorptive removal of imidacloprid pesticide and cadmium ions from contaminated water has been effective, with adsorption capacities of 467.23 and 781.2 mg g(-1) respectively. The adsorbed pollutants can be desorbed using dilute hydrochloric acid, allowing the material to be reused for multiple cycles without significant loss.

CHEMOSPHERE (2021)

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Review Environmental Sciences

A review of metal organic framework (MOFs)-based materials for antibiotics removal via adsorption and photocatalysis

Chunyan Du et al.

Summary: Antibiotic abuse has caused water pollution and health issues; adsorption and photodegradation are effective water treatment methods, with MOFs being excellent adsorbents and photocatalysts.

CHEMOSPHERE (2021)

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Article Environmental Sciences

Magnetic CoFe2O4 nanocrystals derived from MIL-101 (Fe/Co) for peroxymonosulfate activation toward degradation of chloramphenicol

Liu-Xi Yang et al.

Summary: Porous magnetic CoFe2O4 nanocrystals were synthesized using bimetal-organic framework as a precursor and used as catalysts for the removal of chloramphenicol. The CoFe2O4 NCs showed high degradation efficiency and removal of total organic carbon during the removal of CAP.

CHEMOSPHERE (2021)

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Article Chemistry, Physical

Superior adsorptive removal of azo dyes from aqueous solution by a Ni (II)-doped metal?organic framework

Xiu-Ling Li et al.

Summary: Ni(II) doping in MIL-101(Cr) resulted in morphological and structural defects, creating a new mesoporous structure that enhanced the adsorption efficiency for linear anionic azo dyes (e.g. Congo red and methyl orange) but decreased it for non-linear azo dyes (e.g. acid chrome blue K) due to steric hindrance. The adsorption performance of Ni(II)-doped MIL-101(Cr) was found to be controlled by the synergetic interplay among electrostatic interactions, steric hindrance, and the morphological and structural defects, pore volume, and mesoporous structure of the adsorbent.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2021)

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Review Chemistry, Inorganic & Nuclear

Isoreticular chemistry within metal-organic frameworks for gas storage and separation

Weidong Fan et al.

Summary: Precise control of pore size and environment in metal-organic framework (MOF) is essential for achieving high performance gas adsorption and separation. The introduction of isoreticular chemistry in MOFs provides opportunities to improve their gas adsorption and separation performance, enhancing their advantages in gas separation applications.

COORDINATION CHEMISTRY REVIEWS (2021)

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Review Biochemistry & Molecular Biology

Zeolitic Imidazolate Frameworks (ZIF-8) for Biomedical Applications: A Review

Hani Nasser Abdelhamid

Summary: ZIF-8 is not only an excellent protective material for bioentities, but also has advanced applications in biomedicine, including cancer therapy, antimicrobial, biosensing, and biocatalysis. Its bioinspired design enhances the material's performance in biomedical applications, offering high biomineralization capability and superior biological activity for efficient drug delivery and selectivity.

CURRENT MEDICINAL CHEMISTRY (2021)

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Article Green & Sustainable Science & Technology

Heterogeneous fenton-like degradation of amoxicillin using MOF-derived Feo embedded in mesoporous carbon as an effective catalyst

Wuming Xie et al.

Summary: The study demonstrated that the FMC/H2O2 system has high efficiency in degrading AMX, with the FMC catalyst derived from Metal-organic frameworks showing accelerated production of .OH and enhanced removal efficiency of amoxicillin due to its carbon structures facilitating electron transfer.

JOURNAL OF CLEANER PRODUCTION (2021)

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Article Materials Science, Multidisciplinary

Multi-functional polyethersulfone nanofibrous membranes with ultra-high adsorption capacity and ultra-fast removal rates for dyes and bacteria

Jianxu Bao et al.

Summary: The study successfully synthesized a novel nanofibrous membrane material for water remediation, which has high adsorption capacity and rate, demonstrating excellent performance in removing dyes and bacteria.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2021)

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Article Chemistry, Physical

Functionalization of an iron-porphyrinic metal-organic framework with Bovine serum albumin for effective removal of organophosphate insecticides

Zahra Namdar Sheikhi et al.

Summary: A multifunctional hybrid BSA-metal organic framework material was prepared for efficient removal of pesticide residues from water samples. The hybrid material showed high efficiency and suitable recyclability in removing methyl parathion and diazinon. In addition, the material with multiple binding sites exhibited enhanced adsorption activity compared to the metal organic framework alone.

JOURNAL OF MOLECULAR LIQUIDS (2021)

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Article Chemistry, Physical

Preparation of the extruded UiO-66-based Metal-Organic Framework for the diazinon removal from the real samples

Vahid Ashouri et al.

Summary: An efficient adsorbent was developed for the adsorption and removal of diazinon, utilizing a mixture of activated metal-organic framework and a binder. Various factors were optimized to achieve the best efficiency, resulting in a high adsorption capacity for diazinon.

JOURNAL OF MOLECULAR STRUCTURE (2021)

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Article Chemistry, Multidisciplinary

Scalable Room-Temperature Synthesis of Highly Robust Ethane-Selective Metal-Organic Frameworks for Efficient Ethylene Purification

Shubo Geng et al.

Summary: The study introduced two new C2H6-selective MOF adsorbents with high stability and selectivity, which can effectively separate ethylene from ethane even in high humidity conditions. The scalable synthesis method and potential industrial applications make them promising for practical use in industrial settings.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Applied

CdSe QDs@ Fe-based metal organic framework composites for improved photocatalytic RhB degradation under visible light

Yue Zhang et al.

Summary: The CdSe@Fe-BDC nanocomposites showed significantly improved photocatalytic performance in degrading Rhodamine B compared to single Fe-BDC, thanks to the heterostructure formed in CdSe@Fe-BDC which promoted electron transfer and separation of photogenerated electron-hole pairs. The photocatalytic mechanism revealed that hole cation (h(+)) and oxygen free radicals (center dot O-2(-)) were the predominant active species in the system.

MICROPOROUS AND MESOPOROUS MATERIALS (2021)

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Article Biochemistry & Molecular Biology

Solvothermal Preparation of a Lanthanide Metal-Organic Framework for Highly Sensitive Discrimination of Nitrofurantoin and l-Tyrosine

Tian-Tian Wang et al.

Summary: Metal-organic frameworks (MOFs) have been rapidly developed for broad applications, and in this study, a 2D lanthanide MOF was synthesized using a multi-dentate building block. The resulting MOF exhibited high sensitivity recognition for antibiotic nitrofurantoin and amino acid l-tyrosine, providing a feasible detection platform for discriminating antibiotics and amino acids.

MOLECULES (2021)

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Article Engineering, Chemical

Enhanced removal efficiency towards azole fungicides from environmental water using a metal organic framework functionalized magnetic lignosulfonate

Zhi-Heng Lu et al.

Summary: A novel magnetic composite was synthesized and applied for efficient removal of azole fungicides from water. The adsorbent exhibited high adsorption capacity and desirable magnetic property, making it a promising material for environmental remediation applications.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

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Article Food Science & Technology

Applications of metal-organic framework (MOF)-based sensors for food safety: Enhancing mechanisms and recent advances

Weiwei Cheng et al.

Summary: Metal-organic frameworks (MOFs) have exhibited outstanding sensing performance in food safety control sensors. Despite the great potential demonstrated by MOF-based materials, further research is needed before practical applications. With the development of new synthesis and modification techniques, sensors using MOFs as sensing materials are promising to improve food safety sensing efficiency.

TRENDS IN FOOD SCIENCE & TECHNOLOGY (2021)

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Review Chemistry, Multidisciplinary

MOF-on-MOF Architectures: Applications in Separation, Catalysis, and Sensing

Doo Hwan Hong et al.

Summary: Metal-organic frameworks (MOFs) are porous crystalline materials with high tunability. MOF-on-MOF architecturing, which combines two or more MOFs into a composite, shows unprecedented synergism within a single system, offering considerable potential for applications in separation, catalysis, and sensing.

BULLETIN OF THE KOREAN CHEMICAL SOCIETY (2021)

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Article Engineering, Environmental

Simultaneous adsorption of methylene blue and heavy metals from water using Zr-MOF having free carboxylic group

Madhu N. Nimbalkar et al.

Summary: This study utilizes zirconium based metal-organic framework for adsorptive removal of methylene blue and heavy metals from water, and confirms its adsorption performance and structural characteristics through various analyses, indicating its potential application prospects in water treatment.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

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Article Engineering, Environmental

Adsorption and removal of seven antibiotic compounds present in water with the use of biochar derived from the pyrolysis of organic waste feedstocks

Marinos Stylianou et al.

Summary: Biochars derived from various organic waste feedstocks were assessed for their adsorption capacity and mechanisms in the decontamination of antibiotics-contaminated environmental matrices. Results showed that the biochars efficiently removed a high percentage of antibiotics, with main mechanisms including surface complexation, H-bonding, pi-pi EDA interactions, and pore-filling effects.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

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Article Chemistry, Multidisciplinary

Modelling drug adsorption in metal-organic frameworks: the role of solvent

Abhishek T. Sose et al.

Summary: The research indicates that the solvent plays a crucial role in drug adsorption, being driven by electrostatic interactions. Larger pore size MOFs demonstrate an increase in interaction energy as the number of adsorbed molecules increases under high pressure.

RSC ADVANCES (2021)

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Article Engineering, Environmental

The sorption of single- and multi-heavy metals in aqueous solution using enhanced nano-hydroxyapatite assisted with ultrasonic

Cailing Zhou et al.

Summary: Enhanced nHAP synthesized with ultrasonic showed improved sorption capacities for Pb2+, Cu2+, and Zn2+, with a significant impact on Cd2+ uptake due to competitive sorption. The different metal properties and dominant sorption mechanisms resulted in varying effects on the performance of nHAPs for different metal ions.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

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Article Chemistry, Inorganic & Nuclear

Electrolytic synthesis of porphyrinic Zr-metal-organic frameworks with selective crystal topologies†

Keito Okada et al.

Summary: The thermodynamic and kinetic products of porphyrinic Zr-metal-organic frameworks were synthesized for the first time via an anodic dissolution approach. This is the first report of MOF polymorphs being controlled by electrolysis, with the selective formation of one polymorph requiring the presence of an amorphous component on the electrode during the initial reaction process.

DALTON TRANSACTIONS (2021)

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Review Chemistry, Physical

In situ chemical oxidation: peroxide or persulfate coupled with membrane technology for wastewater treatment

Huchuan Yan et al.

Summary: Refractory organic pollutants in wastewater pose serious threats to human and environmental health. The coupling of membrane technology with persulfate/peroxide-based in situ chemical oxidation (ISCO) overcomes the limitations of single technologies and achieves complementary advantages in pollutant filtration and degradation. Different membrane materials and types can be utilized in coupling processes, including one-pot coupling and two-stage coupling.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Multidisciplinary

Photocatalytic activity of new nanostructures of an Ag(i) metal-organic framework (Ag-MOF) for the efficient degradation of MCPA and 2,4-D herbicides under sunlight irradiation

Payam Hayati et al.

Summary: A new Ag(i) metal-organic framework, Ag-MOF, was synthesized using two different methods and showed excellent catalytic activity towards simultaneous photodegradation of MCPA and 2,4-D in an aqueous solution. The maximum photodegradation efficiencies for 2,4-D and MCPA were observed under optimal conditions, with a determined quantum yield of 3.21 x 10(-5) molecules per photon and high reusability efficiency. Ag-MOF is suggested for efficient treatment of organic pollutants in wastewater systems.

NEW JOURNAL OF CHEMISTRY (2021)

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Article Nanoscience & Nanotechnology

One-step microwave hydrothermal preparation of Cd/Zr-bimetallic metal-organic frameworks for enhanced photochemical properties

Wei Cheng et al.

Summary: A new bimetallic metal-organic framework Cd/Zr-MOF was successfully synthesized and showed good photocatalytic performance under specific conditions, mainly due to the study of photocatalytic degradation mechanism by adding different eliminating agents.

ADVANCED COMPOSITES AND HYBRID MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Hierarchical Porous Carbon Materials Prepared by Direct Carbonization of Metal-Organic Frameworks as an Electrode Material for Supercapacitors

Soonsang Hong et al.

Summary: This study presents the synthesis and characterization of hierarchical porous carbons (HPCs) prepared by direct carbonization of zinc-based metal-organic frameworks (MOFs), and evaluates their electrochemical performance as an electrode material for supercapacitors. The HPCs exhibited high porosity and specific capacitance, suggesting their potential utility in supercapacitor fabrication. The hierarchical porosity and nitrogen doping in HPCs were found to enhance their conductivity and specific capacitance.

BULLETIN OF THE KOREAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

Carbon nanotubes modified with 5,7-dinitro-8-quinolinol as potentially applicable tool for efficient removal of industrial wastewater pollutants

E. T. Abdel Salam et al.

ARABIAN JOURNAL OF CHEMISTRY (2020)

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Article Engineering, Environmental

Uniform and stable immobilization of metal-organic frameworks into chitosan matrix for enhanced tetracycline removal from water

Rui Zhao et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Chemistry, Physical

Regulating the dissociation of LiCl and transportation of Li ions within UiO-66-NH2 framework for humidity sensing applications with superb comprehensive performances

Ying Zhang et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2020)

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Article Chemistry, Applied

Synthesis of pearl necklace-like ZIF-8@chitosan/PVA nanofiber with synergistic effect for recycling aqueous dye removal

Niyaz Mohammad Mahmoodi et al.

CARBOHYDRATE POLYMERS (2020)

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Article Chemistry, Physical

Study of CoCu Alloy Nanoparticles Supported on MOF-Derived Carbon for Hydrosilylation of Ketones

David B. Christensen et al.

CATALYSIS LETTERS (2020)

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Article Materials Science, Paper & Wood

Super-magnetization of pectin from orange-peel biomass for sulfamethoxazole adsorption

Avinash A. Kadam et al.

CELLULOSE (2020)

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Article Materials Science, Ceramics

Adsorption of selected dyes on Ti3C2Tx MXene and Al-based metal-organic framework

Byung-Moon Jun et al.

CERAMICS INTERNATIONAL (2020)

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Article Engineering, Environmental

Multifunctional adsorbent based on metal-organic framework modified bacterial cellulose/chitosan composite aerogel for high efficient removal of heavy metal ion and organic pollutant

Dawei Li et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Engineering, Environmental

2D water-stable zinc-benzimidazole framework nanosheets for ultrafast and selective removal of heavy metals

Rongming Xu et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Environmental Sciences

N-doped porous carbon supported Ni catalysts derived from modified Ni-MOF-74 for highly effective and selective catalytic hydrodechlorination of 1,2-dichloroethane to ethylene

Xin Ning et al.

CHEMOSPHERE (2020)

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Article Chemistry, Multidisciplinary

Green Full Conversion of ZnO Nanopowders to Well-Dispersed Zeolitic Imidazolate Framework-8 (ZIF-8) Nanopowders via a Stoichiometric Mechanochemical Reaction for Fast Dye Adsorption

Mahdiar Taheri et al.

CRYSTAL GROWTH & DESIGN (2020)

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Article Environmental Sciences

A sensitive sensor based on MOFs derived nanoporous carbons for electrochemical detection of 4-aminophenol

Sisi Chen et al.

ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY (2020)

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Article Electrochemistry

Hybridization of MOFs and graphene: A new strategy for the synthesis of porous 3D carbon composites for high performing supercapacitors

Truc Van Ngo et al.

ELECTROCHIMICA ACTA (2020)

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Article Chemistry, Inorganic & Nuclear

Synergistic Role of Microwave and Perturbation toward Synthesis of Hierarchical Porous MOFs with Tunable Porosity

Subhajit Laha et al.

INORGANIC CHEMISTRY (2020)

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Article Chemistry, Inorganic & Nuclear

Removal of Hg2+ heavy metal ion using a highly stable mesoporous porphyrinic zirconium metal-organic framework

Zahra Seyfi Hasankola et al.

INORGANICA CHIMICA ACTA (2020)

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Review Green & Sustainable Science & Technology

A review on contamination and removal of sulfamethoxazole from aqueous solution using cleaner techniques: Present and future perspective

G. Prasannamedha et al.

JOURNAL OF CLEANER PRODUCTION (2020)

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Article Polymer Science

Amide-Functionalized Metal-Organic Framework for High Efficiency and Fast Removal of Pb(II) from Aqueous Solution

Hossein Shayegan et al.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS (2020)

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Article Chemistry, Physical

A cationic metal-organic framework for dye adsorption and separation based on column-chromatography

Liu Yang et al.

JOURNAL OF MOLECULAR LIQUIDS (2020)

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Article Chemistry, Inorganic & Nuclear

Removal of fluoroquinolone drug, levofloxacin, from aqueous phase over iron based MOFs, MIL-100(Fe)

Garima Chaturvedi et al.

JOURNAL OF SOLID STATE CHEMISTRY (2020)

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Article Chemistry, Inorganic & Nuclear

Three 2D polyhalogenated Co(II)-based MOFs: Syntheses, crystal structure and electrocatalytic hydrogen evolution reaction

Yong-Shuang Li et al.

JOURNAL OF SOLID STATE CHEMISTRY (2020)

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Article Materials Science, Multidisciplinary

One pot solvothermal synthesis of Co3O4@UiO-66 and CuO@UiO-66 for improved current density towards hydrogen evolution reaction

Muhammad Fiaza et al.

MATERIALS CHEMISTRY AND PHYSICS (2020)

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Review Chemistry, Multidisciplinary

Recent Progress in the Removal of Heavy Metal Ions from Water Using Metal-Organic Frameworks

Hossein Shayegan et al.

CHEMISTRYSELECT (2020)

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Article Engineering, Environmental

MOF [NH2-MIL-101(Fe)] as a powerful and reusable Fenton-like catalyst

Ahmed Aboueloyoun Taha et al.

JOURNAL OF WATER PROCESS ENGINEERING (2020)

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Article Environmental Sciences

Ultrafast and simultaneous removal of anionic and cationic dyes by nanodiamond/UiO-66 hybrid nanocomposite

Hossein Molavi et al.

CHEMOSPHERE (2020)

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Article Chemistry, Multidisciplinary

CoS2 Nanoparticles-Embedded N-Doped Carbon Nanobox Derived from ZIF-67 for Electrocatalytic N2-to-NH3 Fixation under Ambient Conditions

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ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

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Article Engineering, Multidisciplinary

Synthesis of magnetic porous carbon composite derived from metal-organic framework using recovered terephthalic acid from polyethylene terephthalate (PET) waste bottles as organic ligand and its potential as adsorbent for antibiotic tetracycline hydrochloride

Kyung-Won Jung et al.

COMPOSITES PART B-ENGINEERING (2020)

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Article Environmental Sciences

Preparation of UiO-66-NH2 and UiO-66-NH2/sponge for adsorption of 2,4-dichlorophenoxyacetic acid in water

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ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY (2020)

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Review Chemistry, Multidisciplinary

Electrospinning of Metal-Organic Frameworks for Energy and Environmental Applications

Yibo Dou et al.

ADVANCED SCIENCE (2020)

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Article Biochemistry & Molecular Biology

Macromolecular humic acid modified nano-hydroxyapatite for simultaneous removal of Cu(II) and methylene blue from aqueous solution: Experimental design and adsorption study

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INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2020)

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Review Environmental Sciences

Nanoadsorbents for wastewater treatment: next generation biotechnological solution

M. E. Ali et al.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY (2020)

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Article Engineering, Environmental

Controlled pyrolysis of MIL-88A to prepare iron/carbon composites for synergistic persulfate oxidation of phenol: Catalytic performance and mechanism

Xiaojuan Li et al.

JOURNAL OF HAZARDOUS MATERIALS (2020)

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Article Environmental Sciences

Characterization and sulfonamide antibiotics adsorption capacity of spent coffee grounds based biochar and hydrochar

Xinbo Zhang et al.

SCIENCE OF THE TOTAL ENVIRONMENT (2020)

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Review Environmental Sciences

Lead Toxicity: Health Hazards, Influence on Food Chain, and Sustainable Remediation Approaches

Amit Kumar et al.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH AND PUBLIC HEALTH (2020)

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Article Chemistry, Applied

Microwave-assisted synthesis of nano Hf- and Zr-based metal-organic frameworks for enhancement of curcumin adsorption

Y. Thi Dang et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2020)

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Hierarchy in Metal-Organic Frameworks

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ACS CENTRAL SCIENCE (2020)

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Article Chemistry, Multidisciplinary

New MOF/COF Hybrid as a Robust Adsorbent for Simultaneous Removal of Auramine O and Rhodamine B Dyes

Maryam Firoozi et al.

ACS OMEGA (2020)

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Article Materials Science, Ceramics

Fabrication and characterization of sugarcane bagasse-calcium carbonate composite for the efficient removal of crystal violet dye from wastewater

Rui-Feng Wang et al.

CERAMICS INTERNATIONAL (2020)

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Article Engineering, Environmental

Ultrahigh capacitive deionization performance by 3D interconnected MOF-derived nitrogen-doped carbon tubes

Xingtao Xu et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Materials Science, Composites

Corncob-supported Ag NPs@ ZIF-8 nanohybrids as multifunction biosorbents for wastewater remediation: Robust adsorption, catalysis and antibacterial activity

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COMPOSITES SCIENCE AND TECHNOLOGY (2020)

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Article Chemistry, Multidisciplinary

Highly Efficient and Facile Removal of Pb2+ from Water by Using a Negatively Charged Azoxy-Functionalized Metal-Organic Framework

Cai-Xia Yu et al.

CRYSTAL GROWTH & DESIGN (2020)

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Article Environmental Sciences

Cationic metal-organic frameworks as an efficient adsorbent for the removal of 2,4-dichlorophenoxyacetic acid from aqueous solutions

Gege Wu et al.

ENVIRONMENTAL RESEARCH (2020)

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Transformation of 2D Co-LDH into 3D hierarchical hollow Co3O4 polyhedral arrays with enhanced electrochemical performance for supercapacitors

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Article Biotechnology & Applied Microbiology

Low-cost hydrogel derived from agro-waste for veterinary antibiotic removal: Optimization, kinetics, and toxicity evaluation

Hoa Thanh Nguyen et al.

ENVIRONMENTAL TECHNOLOGY & INNOVATION (2020)

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Selective Adsorption of Cationic Dyes for Stable Metal-Organic Framework ZJU-48

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ACS OMEGA (2020)

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Article Chemistry, Multidisciplinary

Novel metal-organic framework of UTSA-16 (Zn) synthesized by a microwave method: Outstanding performance for CO2 capture with improved stability to acid gases

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Preparation of magnetic metal-organic frameworks with high binding capacity for removal of two fungicides from aqueous environments

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JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY (2020)

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Article Chemistry, Physical

In-situ growth of UiO-66-NH2 onto polyacrylamide-grafted nonwoven fabric for highly efficient Pb(II) removal

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APPLIED SURFACE SCIENCE (2020)

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Cobalt Removal from Simulated Wastewaters Using a Novel Flow-by Fixed Bed Bio-electrochemical Reactor

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CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION (2020)

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A remarkable adsorbent for removal of bisphenol S from water: Aminated metal-organic framework, MIL-101-NH2

Jong Min Park et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Review Chemistry, Inorganic & Nuclear

Green synthesis of metal-organic frameworks: A state-of-the-art review of potential environmental and medical applications

Sandeep Kumar et al.

COORDINATION CHEMISTRY REVIEWS (2020)

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Review Chemistry, Inorganic & Nuclear

The thermal stability of metal-organic frameworks

Colm Healy et al.

COORDINATION CHEMISTRY REVIEWS (2020)

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Cyclodextrin derivatives used for the separation of boron and the removal of organic pollutants

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SCIENCE OF THE TOTAL ENVIRONMENT (2020)

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Review Chemistry, Applied

Electrochemical fabrication of metal-organic frameworks membranes and films: A review

Zhiqian Jia et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2020)

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Exploration of the potential capacity of fly ash and bottom ash derived from wood pellet-based thermal power plant for heavy metal removal

Jong-Hwan Park et al.

SCIENCE OF THE TOTAL ENVIRONMENT (2020)

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Review Food Science & Technology

Synthesis of metal-organic frameworks (MOFs) and its application in food packaging: A critical review

P. S. Sharanyakanth et al.

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Functionalization effect of Fe-type MOF for methylene blue adsorption

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Article Chemistry, Inorganic & Nuclear

Introduction of Flexibility into a Metal-Organic Framework to Promote Hg(II) Capture through Adaptive Deformation

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INORGANIC CHEMISTRY (2020)

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Article Engineering, Environmental

Tuning the synthetic conditions of graphene oxide/magnetite/hydroxyapatite/cellulose acetate nanofibrous membranes for removing Cr (VI), Se(IV) and methylene blue from aqueous solutions

Reem Al-Wafi et al.

JOURNAL OF WATER PROCESS ENGINEERING (2020)

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Article Chemistry, Multidisciplinary

Charge-Enhanced Separation of Organic Pollutants in Water by Anionic Covalent Organic Frameworks

Wei Jiang et al.

ACS OMEGA (2020)

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Rapid mechanochemical synthesis of metal-organic frameworks using exogenous organic base

Zihao Wang et al.

DALTON TRANSACTIONS (2020)

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Removal of arsenic(III) from water by 2D zeolitic imidazolate framework-67 nanosheets

Pin Zhao et al.

ENVIRONMENTAL SCIENCE-NANO (2020)

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Article Chemistry, Multidisciplinary

Solvothermal synthesis and characterization of novel [Ni(ii)(Tpy)(Pydc)]•2H2O metal-organic framework as an adsorbent for the uptake of caffeine drug from aqueous solution

Margaret D. Olawale et al.

NEW JOURNAL OF CHEMISTRY (2020)

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Article Chemistry, Physical

Synergistic effect of electrostatic and coordination interactions for adsorption removal of cephalexin from water using a zirconium-based metal-organic framework

Yingjie Zhao et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2020)

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Article Engineering, Environmental

Adsorptive Performance of MOFs and MOF Containing Composites for Clean Energy and Safe Environment

Hossam E. Emam et al.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2020)

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Review Environmental Sciences

Metal-organic frameworks based adsorbents: A review from removal perspective of various environmental contaminants from wastewater

Tahir Rasheed et al.

CHEMOSPHERE (2020)

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Article Chemistry, Multidisciplinary

Hierarchical porous carbon nanofibers for compatible anode and cathode of potassium-ion hybrid capacitor

Xiang Hu et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

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Article Chemistry, Multidisciplinary

Simple, scalable mechanosynthesis of metal-organic frameworks using liquid-assisted resonant acoustic mixing (LA-RAM)

Hatem M. Titi et al.

CHEMICAL SCIENCE (2020)

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Article Chemistry, Multidisciplinary

Mechanochemical synthesis of mixed metal, mixed linker, glass-forming metal-organic frameworks

Michael F. Thorne et al.

GREEN CHEMISTRY (2020)

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Article Nanoscience & Nanotechnology

Removal of Endocrine-Disrupting Chemicals from Environment Using A Robust Platform Based on Metal-Organic Framework Nanoparticles

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ACS APPLIED NANO MATERIALS (2020)

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Review Engineering, Environmental

Metal oxides and metal organic frameworks for the photocatalytic degradation: A review

Sanjeev Gautam et al.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2020)

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Article Chemistry, Physical

Solvent-free mechanochemical route for the construction of ionic liquid and mixed-metal MOF composites for synergistic CO2 fixation

Yuxiu Sun et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Multidisciplinary

Manometric real-time studies of the mechanochemical synthesis of zeolitic imidazolate frameworks

Ivana Brekalo et al.

CHEMICAL SCIENCE (2020)

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Review Environmental Sciences

Effects of ionic strength on removal of toxic pollutants from aqueous media with multifarious adsorbents: A review

Yanhong Zhang et al.

SCIENCE OF THE TOTAL ENVIRONMENT (2019)

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Article Environmental Sciences

Removal of chloramphenicol in aqueous solutions by modified humic acid loaded with nanoscale zero-valent iron particles

Bing Yao et al.

CHEMOSPHERE (2019)

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Article Chemistry, Multidisciplinary

Anodic Electrodeposition of Several Metal Organic Framework Thin Films on Indium Tin Oxide Glass

Jesse L. Hauser et al.

CRYSTAL GROWTH & DESIGN (2019)

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Article Chemistry, Inorganic & Nuclear

Thiol-Functionalized Pores via Post-Synthesis Modification in a Metal-Organic Framework with Selective Removal of Hg(II) in Water

Gao-Peng Li et al.

INORGANIC CHEMISTRY (2019)

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Review Chemistry, Multidisciplinary

Environmental Chemistry and Ecotoxicology of Hazardous Heavy Metals: Environmental Persistence, Toxicity, and Bioaccumulation

Hazrat Ali et al.

JOURNAL OF CHEMISTRY (2019)

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Article Chemistry, Physical

Evaluation of graphene oxide-activated carbon as effective composite adsorbent toward the removal of cationic dyes: Composite preparation, characterization and adsorption parameters

A. Abd-Elhamid et al.

JOURNAL OF MOLECULAR LIQUIDS (2019)

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Article Engineering, Environmental

Equilibrium, Kinetic and Thermodynamic Studies on Methylene Blue Adsorption by Konjac Glucomannan/Activated Carbon Aerogel

Yuqi Wang et al.

JOURNAL OF POLYMERS AND THE ENVIRONMENT (2019)

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Article Chemistry, Physical

Bio-based magnetic metal-organic framework nanocomposite: Ultrasound-assisted synthesis and pollutant (heavy metal and dye) removal from aqueous media

Niyaz Mohammad Mahmoodi et al.

APPLIED SURFACE SCIENCE (2019)

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Article Chemistry, Multidisciplinary

Removal of selected endocrine-disrupting compounds using Al-based metal organic framework: Performance and mechanism of competitive adsorption

Byung-Moon Jun et al.

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY (2019)

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Review Engineering, Environmental

Removal of contaminants of emerging concern by metal-organic framework nanoadsorbents: A review

Lesley Joseph et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Article Environmental Sciences

Carbon composite membrane derived from MIL-125-NH2 MOF for the enhanced extraction of emerging pollutants

Neus Crespi Sanchez et al.

CHEMOSPHERE (2019)

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Article Environmental Sciences

Comprehensive evaluation on removal of lead by graphene oxide and metal organic framework

Byung-Moon Jun et al.

CHEMOSPHERE (2019)

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Article Chemistry, Multidisciplinary

Highly Exposed Active Sites of Defect-Enriched Derived MOFs for Enhanced Oxygen Reduction Reaction

Yu Zhu et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

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Article Environmental Sciences

Comprehensive evaluation of the removal mechanism of carbamazepine and ibuprofen by metal organic framework

Byung-Moon Jun et al.

CHEMOSPHERE (2019)

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Article Chemistry, Physical

Efficient removal of metal contaminants by EDTA modified MOF from aqueous solutions

Jin Wu et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2019)

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Article Chemistry, Physical

A water-stable triazine-based metal-organic framework as an efficient adsorbent of Pb(II) ions

Ruoqian Zhang et al.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2019)

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Article Engineering, Environmental

Cu, Zn-embedded MOF-derived bimetallic porous carbon for adsorption desulfurization

Quan Huo et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Article Environmental Sciences

Enhanced removal of bisphenol A from aqueous solution by aluminum-based MOF/sodium alginate-chitosan composite beads

Zifen Luo et al.

CHEMOSPHERE (2019)

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Article Biochemistry & Molecular Biology

Magnetic xanthate modified chitosan as an emerging adsorbent for cationic azo dyes removal: Kinetic, thermodynamic and isothermal studies

Bahareh Tanhaei et al.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2019)

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Article Environmental Sciences

The synergistic effect of Ag/AgCl@ZIF-8 modified g-C3N4 composite and peroxymonosulfate for the enhanced visible-light photocatalytic degradation of levofloxacin

Jiabin Zhou et al.

SCIENCE OF THE TOTAL ENVIRONMENT (2019)

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Article Nanoscience & Nanotechnology

Exploiting π-π Interactions to Design an Efficient Sorbent for Atrazine Removal from Water

Isil Akpinar et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Review Chemistry, Multidisciplinary

Performance of metal-organic frameworks for the adsorptive removal of potentially toxic elements in a water system: a critical review

Sammani Ramanayaka et al.

RSC ADVANCES (2019)

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Article Chemistry, Physical

Electroforming of a metal-organic framework on porous copper hollow fibers

Oztem H. Demirel et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Article Chemistry, Multidisciplinary

MOF-5 derived carbon as material for CO2 absorption

Wojciech Kukulka et al.

RSC ADVANCES (2019)

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Article Chemistry, Multidisciplinary

Removal of anthracene in water by MIL-88(Fe), NH2-MIL-88(Fe), and mixed-MIL-88(Fe) metal-organic frameworks

Zakariyya Uba Zango et al.

RSC ADVANCES (2019)

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Article Chemistry, Multidisciplinary

Fabrication of an amine-modified ZIF-8@GO membrane for high-efficiency adsorption of copper ions

Ning Wei et al.

NEW JOURNAL OF CHEMISTRY (2019)

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Article Engineering, Environmental

Zeolitic imidazolate frameworks: Experimental and molecular simulation studies for efficient capture of pesticides from wastewater

Reda M. Abdelhameed et al.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2019)

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Article Chemistry, Multidisciplinary

Cu@Co-MOFs as a novel catalyst of peroxymonosulfate for the efficient removal of methylene blue

Huanxuan Li et al.

RSC ADVANCES (2019)

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Article Environmental Sciences

Kinetic and equilibrium studies on the removal of 14C-ethion residues from wastewater by copper-based metal-organic framework

R. M. Abdelhameed et al.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY (2018)

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Article Chemistry, Multidisciplinary

The Interaction of Guest Molecules with Co-MOF-74: A Vis/NIR and Raman Approach

Ina Strauss et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Article Chemistry, Physical

Rapid and selective adsorption of cationic dyes by a unique metal-organic framework with decorated pore surface

Jie Zhang et al.

APPLIED SURFACE SCIENCE (2018)

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Article Engineering, Environmental

Morphology controlled porous poly(lactic acid)/zeolitic imidazolate framework-8 fibrous membranes with superior PM2.5 capture capacity

Xiu Dai et al.

CHEMICAL ENGINEERING JOURNAL (2018)

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Article Engineering, Environmental

Remarkably efficient adsorbent for the removal of bisphenol A from water: Bio-MOF-1-derived porous carbon

Biswa Nath Bhadra et al.

CHEMICAL ENGINEERING JOURNAL (2018)

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Review Chemistry, Inorganic & Nuclear

Gold rush in modern science: Fabrication strategies and typical advanced applications of gold nanoparticles in sensing

Lei Qin et al.

COORDINATION CHEMISTRY REVIEWS (2018)

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Article Engineering, Chemical

Novel melamine modified metal-organic frameworks for remarkably high removal of heavy metal Pb (II)

Na Yin et al.

DESALINATION (2018)

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Article Engineering, Chemical

Synthesis and Shaping Scale-up Study of Functionalized UiO-66 MOF for Ammonia Air Purification Filters

Yoldes Khabzina et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2018)

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Article Chemistry, Inorganic & Nuclear

Removal of hazardous cationic organic dyes from water using nickel-based metal-organic frameworks

H. M. Abd El Salam et al.

INORGANICA CHIMICA ACTA (2018)

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Article Green & Sustainable Science & Technology

Removal of ciprofloxacin using modified advanced oxidation processes: Kinetics, pathways and process optimization

Sourav Kumar Mondal et al.

JOURNAL OF CLEANER PRODUCTION (2018)

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Article Chemistry, Physical

A metal-organic framework with large 1-D channels and rich -OH sites for high-efficiency chloramphenicol removal from water

Xudong Zhao et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2018)

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Article Environmental Sciences

Adsorptive performance of MOF nanocomposite for methylene blue and malachite green dyes: Kinetics, isotherm and mechanism

Ayoub Abdullah Alqadami et al.

JOURNAL OF ENVIRONMENTAL MANAGEMENT (2018)

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Article Environmental Sciences

BTEX removal from aqueous solution with hydrophobic Zr metal organic frameworks

Ricardo Navarro Amador et al.

JOURNAL OF ENVIRONMENTAL MANAGEMENT (2018)

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Article Chemistry, Multidisciplinary

Attapulgite/carbon composites as a recyclable adsorbent for antibiotics removal

Jie Tang et al.

KOREAN JOURNAL OF CHEMICAL ENGINEERING (2018)

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Article Environmental Sciences

Occurrence, distribution, and sources of emerging organic contaminants in tropical coastal sediments of anthropogenically impacted Klang River estuary, Malaysia

Tuan Fauzan Tuan Omar et al.

MARINE POLLUTION BULLETIN (2018)

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Article Engineering, Environmental

Electrochemical oxidation of pesticide thiamethoxam on boron doped diamond anode: Role of operating parameters and matrix effect

Hafida Lebik-Elhadi et al.

PROCESS SAFETY AND ENVIRONMENTAL PROTECTION (2018)

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Article Chemistry, Multidisciplinary

Effective adsorption of ciprofloxacin hydrochloride from aqueous solutions using metal-organic framework

Chandrakanth R. Gadipelly et al.

SEPARATION SCIENCE AND TECHNOLOGY (2018)

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Article Environmental Sciences

Remediation of pharmaceutical contaminated water by use of magnetic functionalized metal organic framework. Physicochemical study of doxycycline adsorption

Shakiba Naeimi et al.

WATER AND ENVIRONMENT JOURNAL (2018)

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Article Chemistry, Physical

Factorial experimental design for the optimization of highly selective adsorption removal of lead and copper ions using metal organic framework MOF-2 (Cd)

Abdol Mohammad Ghaedi et al.

JOURNAL OF MOLECULAR LIQUIDS (2018)

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Article Chemistry, Physical

Synthesis and characterization of graphene oxide-doped nano-hydroxyapatite and its adsorption performance of toxic diazo dyes from aqueous solution

Subbaiah Muthu Prabhu et al.

JOURNAL OF MOLECULAR LIQUIDS (2018)

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Review Engineering, Chemical

Water stable metal-organic framework as adsorbent from aqueous solution: A mini-review

Yu-Jen Lee et al.

JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS (2018)

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Article Chemistry, Multidisciplinary

Metal-organic framework sorbents for the removal of perfluorinated compounds in an aqueous environment

Karima Sini et al.

NEW JOURNAL OF CHEMISTRY (2018)

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Article Chemistry, Multidisciplinary

Core-shell magnetic metal-organic framework molecularly imprinted nanospheres for specific adsorption of tetrabromobisphenol A from water

Minna Li et al.

ENVIRONMENTAL SCIENCE-NANO (2018)

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Article Chemistry, Multidisciplinary

Effect of the Synergetic Interplay between the Electrostatic Interactions, Size of the Dye Molecules, and Adsorption Sites of MIL-101(Cr) on the Adsorption of Organic Dyes from Aqueous Solutions

Wei Zhang et al.

CRYSTAL GROWTH & DESIGN (2018)

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Article Chemistry, Physical

A g-C3N4/MIL-101(Fe) heterostructure composite for highly efficient BPA degradation with persulfate under visible light irradiation

Yan Gong et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

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Article Engineering, Environmental

Diazinon removal from aqueous media by mesoporous MIL-101(Cr) in a continuous fixed-bed system

Seyed Mohammad Mirsoleimani-azizi et al.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2018)

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Article Chemistry, Multidisciplinary

Water-stable fluorinated metal-organic frameworks (F-MOFs) with hydrophobic properties as efficient and highly active heterogeneous catalysts in aqueous solution

Monika Joharian et al.

GREEN CHEMISTRY (2018)

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Article Chemistry, Multidisciplinary

Chemically Modulated Microwave-Assisted Synthesis of MOF-74(Ni) and Preparation of Metal-Organic Framework-Matrix Based Membranes for Removal of Metal Ions from Aqueous Media

Gustavo H. Albuquerque et al.

CRYSTAL GROWTH & DESIGN (2017)

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Article Environmental Sciences

Metal-organic framework Uio-66 for adsorption of methylene blue dye from aqueous solutions

A. A. Mohammadi et al.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY (2017)

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Article Green & Sustainable Science & Technology

Microwave-assisted pyrolysis with chemical activation, an innovative method to convert orange peel into activated carbon with improved properties as dye adsorbent

Su Shiung Lam et al.

JOURNAL OF CLEANER PRODUCTION (2017)

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Article Chemistry, Physical

In-situ ethylenediamine-assisted synthesis of a magnetic iron-based metal -organic framework MIL-53(Fe) for visible light photocatalysis

Xiangwen Feng et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2017)

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Article Chemistry, Physical

Highly dispersed Co-based Fischer-Tropsch synthesis catalysts from metal-organic frameworks

Bin Qiu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

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Review Chemistry, Physical

Photocatalytic Membrane Reactors (PMRs) in Water Treatment: Configurations and Influencing Factors

Xiang Zheng et al.

CATALYSTS (2017)

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Article Nanoscience & Nanotechnology

Adsorption Behaviors of Organic Micropollutants on Zirconium Metal-Organic Framework UiO-66: Analysis of Surface Interactions

Caiqin Chen et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

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Article Nanoscience & Nanotechnology

Tuning Gas Adsorption Properties of Zeolite-like Supramolecular Assemblies with gis Topology via Functionalization of Isoreticular Metal-Organic Squares

Shuang Wang et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

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Article Nanoscience & Nanotechnology

Multiple Coordination Exchanges for Room-Temperature Activation of Open-Metal Sites in Metal-Organic Frameworks

Jinhee Bae et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

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Article Engineering, Chemical

MOF-derived magnetic porous carbon-based sorbent: Synthesis, characterization, and adsorption behavior of organic micropollutants

Dezhi Chen et al.

ADVANCED POWDER TECHNOLOGY (2017)

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Review Engineering, Environmental

Electrocoagulation treatment of arsenic in wastewaters: A comprehensive review

Peipei Song et al.

CHEMICAL ENGINEERING JOURNAL (2017)

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Article Chemistry, Physical

Resin modified MIL-53 (Fe) MOF for improvement of photocatalytic performance

Tirusew Araya et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2017)

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Article Environmental Sciences

Core-shell Fe3O4@MIL-101(Fe) composites as heterogeneous catalysts of persulfate activation for the removal of Acid Orange 7

Xinxin Yue et al.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2016)

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Article Chemistry, Inorganic & Nuclear

New interpenetrated mixed (Co/Ni) metal-organic framework for dye removal under mild conditions

Alireza Abbasi et al.

INORGANICA CHIMICA ACTA (2016)

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Review Chemistry, Inorganic & Nuclear

A review on contemporary Metal-Organic Framework materials

Kranthi Kumar Gangu et al.

INORGANICA CHIMICA ACTA (2016)

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Article Chemistry, Physical

Exploring a thiol-functionalized MOF for elimination of lead and cadmium from aqueous solution

Jinmiao Zhang et al.

JOURNAL OF MOLECULAR LIQUIDS (2016)

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Review Chemistry, Multidisciplinary

Metal-organic frameworks: structure, properties, methods of synthesis and characterization

V. V. Butova et al.

RUSSIAN CHEMICAL REVIEWS (2016)

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Article Chemistry, Physical

On the electrochemical deposition of metal-organic frameworks

Nicolo Campagnol et al.

JOURNAL OF MATERIALS CHEMISTRY A (2016)

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Article Chemistry, Physical

A simple strategy for fabrication of Pd@MIL-100(Fe) nanocomposite as a visible-light-driven photocatalyst for the treatment of pharmaceuticals and personal care products (PPCPs)

Ruowen Liang et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2015)

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Article Chemistry, Physical

Methyl red removal from water by iron based metal-organic frameworks loaded onto iron oxide nanoparticle adsorbent

S. Dadfarnia et al.

APPLIED SURFACE SCIENCE (2015)

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Review Chemistry, Multidisciplinary

Zeolite-like metal-organic frameworks (ZMOFs): design, synthesis, and properties

Mohamed Eddaoudi et al.

CHEMICAL SOCIETY REVIEWS (2015)

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Article Engineering, Environmental

Understanding the Adsorption of PFOA on MIL-101(Cr)-Based Anionic-Exchange Metal-Organic Frameworks: Comparing DFT Calculations with Aqueous Sorption Experiments

Kai Liu et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2015)

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Article Chemistry, Physical

Engineering the surface of a new class of adsorbents: Metal-organic framework/graphite oxide composites

Camille Petit et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2015)

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Article Chemistry, Physical

Efficient degradation of high concentration azo-dye wastewater by heterogeneous Fenton process with iron-based metal-organic framework

Huanli Lv et al.

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL (2015)

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Article Chemistry, Physical

Lead(II) uptake by aluminium based magnetic framework composites (MFCs) in water

Raffaele Ricco et al.

JOURNAL OF MATERIALS CHEMISTRY A (2015)

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Article Chemistry, Applied

Metal-organic framework MIL-125(Ti) for efficient adsorptive removal of Rhodamine B from aqueous solution

Hongxu Guo et al.

APPLIED ORGANOMETALLIC CHEMISTRY (2015)

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Article Engineering, Chemical

Adsorptive removal of bisphenol A from aqueous solution using metal-organic frameworks

Feng-Xiang Qin et al.

DESALINATION AND WATER TREATMENT (2015)

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Article Chemistry, Multidisciplinary

Solid phase extraction of heavy metal ions from agricultural samples with the aid of a novel functionalized magnetic metal-organic framework

Mirzaagha Babazadeh et al.

RSC ADVANCES (2015)

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Article Chemistry, Multidisciplinary

A stable, pillar-layer metal-organic framework containing uncoordinated carboxyl groups for separation of transition metal ions

Xing Meng et al.

CHEMICAL COMMUNICATIONS (2014)

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Article Engineering, Environmental

Removing oil droplets from water using a copper-based metal organic frameworks

Kun-Yi Andrew Lin et al.

CHEMICAL ENGINEERING JOURNAL (2014)

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Article Chemistry, Physical

Adsorption of Rhodamine-B from aqueous solution using treated rice husk-based activated carbon

Lili Ding et al.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2014)

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Article Chemistry, Applied

Adsorption behavior of metal-organic frameworks for methylene blue from aqueous solution

Shuang Lin et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2014)

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Article Chemistry, Physical

Adsorption of Azo-Dye Orange II from Aqueous Solutions Using a Metal-Organic Framework Material: Iron-Benzenetricarboxylate

Elizabeth Rojas Garcia et al.

MATERIALS (2014)

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Article Chemistry, Physical

Electrochemical preparation of metal-organic framework films for fast detection of nitro explosives

Wei-Jin Li et al.

JOURNAL OF MATERIALS CHEMISTRY A (2014)

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Article Chemistry, Multidisciplinary

Capture of iodine in highly stable metal-organic frameworks: a systematic study

Clement Falaise et al.

CHEMICAL COMMUNICATIONS (2013)

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Article Chemistry, Multidisciplinary

Superhydrophobic perfluorinated metal-organic frameworks

Teng-Hao Chen et al.

CHEMICAL COMMUNICATIONS (2013)

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Article Engineering, Environmental

Adsorption of naproxen and clofibric acid over a metal-organic framework MIL-101 functionalized with acidic and basic groups

Zubair Hasan et al.

CHEMICAL ENGINEERING JOURNAL (2013)

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Article Chemistry, Multidisciplinary

Syntheses, Crystal Structures, and Physical Properties of Two Noninterpenetrated Pillar-Layered Metal-Organic Frameworks Based on N,N′-Di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide Pillar

Lei Han et al.

CRYSTAL GROWTH & DESIGN (2013)

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Article Chemistry, Multidisciplinary

Adsorptive Removal of Bisphenol-A from Water with a Metal-Organic Framework, a Porous Chromium-Benzenedicarboxylate

Eun Young Park et al.

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY (2013)

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Article Chemistry, Multidisciplinary

Effective Mercury Sorption by Thiol-Laced Metal-Organic Frameworks: in Strong Acid and the Vapor Phase

Ka-Kit Yee et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

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Article Chemistry, Applied

Metal-organic frameworks as a very suitable reaction inductor for selective solvent-free multicomponent reaction: IRMOF-3 as a heterogeneous nanocatalyst for Kabachnik-Fields three-component reaction

Sadegh Rostamnia et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2013)

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Article Chemistry, Inorganic & Nuclear

Exploring the coordination chemistry of MOF-graphite oxide composites and their applications as adsorbents

Camille Petit et al.

DALTON TRANSACTIONS (2012)

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Article Chemistry, Inorganic & Nuclear

Titration of Zr3(μ-OH) Hydroxy Groups at the Cornerstones of Bulk MOF UiO-67, [Zr6O4(OH)4(biphenyldicarboxylate)6], and Their Reaction with [AuMe(PMe3)]

Cherif Larabi et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2012)

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Article Chemistry, Physical

Electrospinning technology applied in zeolitic imidazolate framework membrane synthesis

Lili Fan et al.

JOURNAL OF MATERIALS CHEMISTRY (2012)

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Article Chemistry, Physical

Metal-organic framework MIL-100(Fe) for the adsorption of malachite green from aqueous solution

Shu-Hui Huo et al.

JOURNAL OF MATERIALS CHEMISTRY (2012)

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Article Chemistry, Multidisciplinary

Metal-organic framework nanofibers via electrospinning

Rainer Ostermann et al.

CHEMICAL COMMUNICATIONS (2011)

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Article Engineering, Environmental

Adsorptive removal of methyl orange and methylene blue from aqueous solution with a metal-organic framework material, iron terephthalate (MOF-235)

Enamul Haque et al.

JOURNAL OF HAZARDOUS MATERIALS (2011)

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Article Chemistry, Multidisciplinary

Enhanced Adsorption of Ammonia on Metal-Organic Framework/Graphite Oxide Composites: Analysis of Surface Interactions

Camille Petit et al.

ADVANCED FUNCTIONAL MATERIALS (2010)

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Article Chemistry, Multidisciplinary

Enhancing the stability of metal-organic frameworks in humid air by incorporating water repellent functional groups

Tianjiao Wu et al.

CHEMICAL COMMUNICATIONS (2010)

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Article Chemistry, Applied

Designing Heterogeneous Catalysts by Incorporating Enzyme-Like Functionalities into MOFs

Karl Petter Lillerud et al.

TOPICS IN CATALYSIS (2010)

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Article Chemistry, Multidisciplinary

Isoreticular MOFs as Efficient Photocatalysts with Tunable Band Gap: An Operando FTIR Study of the Photoinduced Oxidation of Propylene

Jorge Gascon et al.

CHEMSUSCHEM (2008)

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Article Multidisciplinary Sciences

Exceptional chemical and thermal stability of zeolitic imidazolate frameworks

Kyo Sung Park et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2006)

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Article Chemistry, Physical

Metal-organic frameworks -: prospective industrial applications

U Mueller et al.

JOURNAL OF MATERIALS CHEMISTRY (2006)

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Article Multidisciplinary Sciences

A chromium terephthalate-based solid with unusually large pore volumes and surface area

G Férey et al.

SCIENCE (2005)

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Article Chemistry, Inorganic & Nuclear

Flexible microporous coordination polymers

K Uemura et al.

JOURNAL OF SOLID STATE CHEMISTRY (2005)

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Review Chemistry, Multidisciplinary

Dynamic porous properties of coordination polymers inspired by hydrogen bonds

S Kitagawa et al.

CHEMICAL SOCIETY REVIEWS (2005)

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Review Chemistry, Inorganic & Nuclear

Chiral porous coordination networks: rational design and applications in enantioselective processes

B Kesanli et al.

COORDINATION CHEMISTRY REVIEWS (2003)

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