4.7 Article

Electrostatics advancing green catalysis events

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Review Chemistry, Analytical

Mass spectrometry in materials synthesis

Jyotirmoy Ghosh et al.

Summary: Mass spectrometry (MS), a century-old analytical technique, is now being used as a preparative method. Electrospray deposition (ESD) of charged droplets generated by electrospray ionization (ESI) is an efficient way to form nanomaterials, including catalysts. By using mass-analyzed ions and performing ion soft landing (SL), higher chemical specificity in surface modification can be achieved, although this vacuum-based method is slow due to low ion currents. MS-based synthesis by ESD or SL provides advantages over traditional approaches, allowing control over material properties and surface patterning without the need for additives or reducing agents.

TRAC-TRENDS IN ANALYTICAL CHEMISTRY (2023)

Article Multidisciplinary Sciences

Boosting the performance of single-atom catalysts via external electric field polarization

Yanghang Pan et al.

Summary: Single-atom catalysts offer high atomic utilization and tunable reaction pathways. By using oriented external electric fields, the performance of model single-atom catalysts anchored on two-dimensional atomic crystals can be significantly improved. Theoretical investigations suggest that field-induced on-site polarization can simulate catalytic processes and dynamically regulate the catalytic performance.

NATURE COMMUNICATIONS (2022)

Article Chemistry, Physical

Remarkably enhanced photocatalytic performance of Au/AgNbO3 heterostructures by coupling piezotronic with plasmonic effects

Shun Li et al.

Summary: In this study, a novel heterostructured piezo-photocatalyst was developed by decorating plasmonic Au nanoparticles on piezoelectric AgNbO3 nanocubes. The significantly enhanced photocatalytic performance of the optimized nanocomposites can be attributed to the synergetic coupling of localized surface plasmon resonance (SPR) effect and piezotronic effect, which facilitate the extraction of energetic hot electrons from AuNPs to the AgNbO3 driven by the mechanical vibration induced piezo-potential near the heterojunction.

NANO ENERGY (2022)

Article Chemistry, Multidisciplinary

β-Lactamases Evolve against Antibiotics by Acquiring Large Active- Site Electric Fields

Zhe Ji et al.

Summary: Enzyme active sites can regulate the hydrolysis of covalent bonds through electric fields, affecting the development and overcoming of resistance. Over billions of years of evolution, the change in electric fields has increased the hydrolysis rate of covalent bonds by 5 orders of magnitude, a trend that continues in current antibiotic drug development. The electric field can be used as a unified physical metric to understand protein evolution and guide drug design.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Article Nanoscience & Nanotechnology

Piezotronic Effect Induced Schottky Barrier Decrease to Boost the Plasmonic Charge Separation of BaTiO3-Au Heterojunction for the Photocatalytic Selective Oxidation of Aminobenzyl Alcohol

Hong Liu et al.

Summary: This study demonstrates that the nanohybrid structure of BaTiO3-Au (BTO-Au) can enhance the charge carrier transfer efficiency and catalytic activity in photocatalytic organic conversion by coupling the piezotronic effect with surface plasmonic resonance (SPR).

ACS APPLIED MATERIALS & INTERFACES (2022)

Review Chemistry, Multidisciplinary

Electrostatics and Electrochemistry: Mechanism and Scope of Charge-Transfer Reactions on the Surface of Tribocharged Insulators

Jinyang Zhang et al.

Summary: The article discusses recent research advancements in the phenomenon of contact electrification and its mechanisms, as well as the emerging field of electrochemistry on insulators. Studies have shown how to exploit static charges to drive redox reactions, while also clarifying the mechanism of triboelectrification.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Review Chemistry, Multidisciplinary

Confinement in a Zeolite and Zeolite Catalysis

Yuchao Chai et al.

Summary: Zeolites, with their ordered channels on the molecular scale, are intrinsic confined systems that play crucial roles in various fields. The structural confinement in zeolites can lead to unique chemical behaviors, affecting molecular diffusion and shape-selective catalysis. Understanding the nature of zeolite confinement from spatial and electronic perspectives is essential for their effective utilization in adsorption and catalysis.

ACCOUNTS OF CHEMICAL RESEARCH (2021)

Article Chemistry, Multidisciplinary

Oriented Electrostatic Effects on O2 and CO2 Reduction by a Polycationic Iron Porphyrin

Daniel J. Martin et al.

Summary: The study demonstrates that a metalloporphyrin catalyst with four cationic groups can stabilize charged intermediates and catalyze ORR and CO2RR reactions with fast rates and low overpotentials. Each of the four atropisomers of the metalloporphyrin show differences in maximum turnover frequencies and overpotentials for the two reactions, highlighting the complexity of charge positioning in affecting the thermodynamics and kinetics of multistep molecular electrochemical transformations.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Physical

Electric Fields in Catalysis: From Enzymes to Molecular Catalysts

Nadia G. Leonard et al.

Summary: Electric fields play a crucial role in modifying the free energy landscape and impacting reactivity, yet they are rarely considered in synthetic design. This Perspective discusses the commonalities of electric field effects across different platforms and identifies practical challenges in applying them to mediate reactivity in synthetic molecular systems.

ACS CATALYSIS (2021)

Article Chemistry, Multidisciplinary

Oriented External Electric Fields and Ionic Additives Elicit Catalysis and Mechanistic Crossover in Oxidative Addition Reactions

Jyothish Joy et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Review Chemistry, Multidisciplinary

Molecular reactions at aqueous interfaces

Manuel F. Ruiz-Lopez et al.

NATURE REVIEWS CHEMISTRY (2020)

Article Nanoscience & Nanotechnology

Recent Advances of Ferro-, Piezo-, and Pyroelectric Nanomaterials for Catalytic Applications

Shun Li et al.

ACS APPLIED NANO MATERIALS (2020)

Article Multidisciplinary Sciences

Electric-Field-Induced Connectivity Switching in Single-Molecule Junctions

Chun Tang et al.

ISCIENCE (2020)

Article Chemistry, Multidisciplinary

Potential-Induced High-Conductance Transport Pathways through Single-Molecule Junctions

Parisa Yasini et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Multidisciplinary Sciences

Electric field-induced selective catalysis of single-molecule reaction

Xiaoyan Huang et al.

SCIENCE ADVANCES (2019)

Review Chemistry, Multidisciplinary

Structure and reactivity/selectivity control by oriented-external electric fields

Sason Shaik et al.

CHEMICAL SOCIETY REVIEWS (2018)

Article Chemistry, Multidisciplinary

Electrochemical and Electrostatic Cleavage of Alkoxyamines

Long Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Physical

Elucidating the Roles of Electric Fields in Catalysis: A Perspective

Fanglin Che et al.

ACS CATALYSIS (2018)

Article Chemistry, Multidisciplinary

CO2 Reduction Catalysts on Gold Electrode Surfaces Influenced by Large Electric Fields

Melissa L. Clark et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Physical

Computational optimization of electric fields for better catalysis design

Valerie Vaissier Welborn et al.

NATURE CATALYSIS (2018)

Article Multidisciplinary Sciences

Reproducible flaws unveil electrostatic aspects of semiconductor electrochemistry

Yan B. Vogel et al.

NATURE COMMUNICATIONS (2017)

Article Multidisciplinary Sciences

Electrostatic catalysis of a Diels-Alder reaction

Albert C. Aragones et al.

NATURE (2016)

Article Chemistry, Multidisciplinary

Oriented electric fields as future smart reagents in chemistry

Sason Shaik et al.

NATURE CHEMISTRY (2016)

Article Chemistry, Multidisciplinary

Experimental demonstration of pH-dependent electrostatic catalysis of radical reactions

Marta Klinska et al.

CHEMICAL SCIENCE (2015)

Article Multidisciplinary Sciences

Extreme electric fields power catalysis in the active site of ketosteroid isomerase

Stephen D. Fried et al.

SCIENCE (2014)

Article Chemistry, Multidisciplinary

Interfacial Electric Field Effects on a Carbene Reaction Catalyzed by Rh Porphyrins

Craig F. Gorin et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Chemistry, Multidisciplinary

Origin and Scope of Long-Range Stabilizing Interactions and Associated SOMO-HOMO Conversion in Distonic Radical Anions

Ganna Gryn'ova et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Chemistry, Multidisciplinary

Switching radical stability by pH-induced orbital conversion

Ganna Gryn'ova et al.

NATURE CHEMISTRY (2013)

Article Chemistry, Multidisciplinary

An Electric Field-Induced Change in the Selectivity of a Metal Oxide-Catalyzed Epoxide Rearrangement

Craig F. Gorin et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Article Chemistry, Physical

Electrostatic electrochemistry at insulators

Chongyang Liu et al.

NATURE MATERIALS (2008)

Article Chemistry, Multidisciplinary

External electric field will control the selectivity of enzymatic-like bond activations

S Shaik et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2004)