4.7 Article

Torrefied paper as a packaging material and subsequently as a bioethanol substrate: Synergy of torrefaction and alkaline treatment for increased utility

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ELSEVIER
DOI: 10.1016/j.resconrec.2023.106882

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Cellulose; Tensile strength; Glucose yield; Torrefaction; Alkaline treatment

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The sequential combination of torrefaction and alkaline treatment can enhance the wet strength of torrefied cellulosic paper and promote bioethanol production. Torrefaction at different temperatures significantly improved the wet-tensile strength of cellulose filter paper. Glucose yield decreased with increased torrefaction severity, but increased after alkaline treatment.
The sequential combination of torrefaction and alkaline treatment is one possible design strategy for a circular economy in which torrefied cellulosic paper with enhanced wet strength is repeatedly used as a packaging material, then hydrolyzed downstream for bioethanol production after alkaline treatment. The wet-tensile strength of cellulose filter paper increased by 1533%, 2233%, 1567%, and 557% after torrefaction for 40 mins at 200 degrees C, 220 degrees C, 240 degrees C and 260 degrees C, respectively. Glucose yield decreased with increase in torrefaction severity but after treating torrefied filter samples with alkaline (NaOH) solution, glucose yield increased. For instance, the glucose yield of raw filter paper was 955 mg/g of substrate whereas it was 690 mg/g of substrate for the same filter paper sample torrefied at 200 degrees C. The glucose yield increased to 808 and 933 mg/g of substrate with 1% and 10% alkaline treatment, respectively.

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