Bismaleimide resins modified by a novel vanillin-derived allyl compounds: Synthesis, curing behavior, and thermal properties

In this study, a novel biobased allyl compound with Schiff-based structure (MPAM) was developed to improve the toughness and thermal properties of 4,4 '-bismaleimidodiphenylmethane (BDM). The chemical structure of MPAM was characterized by Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (H-1 NMR). A series of BDM/DBA-MPAM blend resins (BD-MPAM resins) were prepared by adjusting the mass ratio of BDM + DBA (BD) to MPAM. The effects of MPAM content on the curing behavior, thermal and mechanical properties of BD-MPAM resins were discussed in details. Compared with BD resin, the thermal stability of modified resins was improved by increasing the content of MPAM. Meanwhile, an increase of 37.1% in flexural strength, and 228 MPa in flexural modulus were obtained for the cured BD-MPAM resin having 10 wt% MPAM loading compared to the BD resin. The impact strength of BD-10 wt% MPAM is of the maximum value (6.6 kJ/m(2)). Finally, the fracture surface morphology of the BD-MPAM resins was studied by the scanning electron microscope (SEM).

Automated summary

A novel biobased allyl compound with Schiff-based structure (MPAM) was developed to improve the toughness and thermal properties of 4,4'-bismaleimidodiphenylmethane (BDM). BDM/DBA-MPAM blend resins (BD-MPAM resins) were prepared and the effects of MPAM content on the curing behavior, thermal and mechanical properties were discussed. The modified resins showed improved thermal stability and enhanced flexural strength and modulus compared to BD resin. The impact strength of BD-10 wt% MPAM was the highest.