4.5 Article

Characteristics and performance of high-density polyethylene, calcium carbonate particles and polyethylene maleic anhydride nanocomposites

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POLYMER BULLETIN
卷 -, 期 -, 页码 -

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SPRINGER
DOI: 10.1007/s00289-023-04802-9

关键词

High-density polyethylene; Nano-calcium carbonate; Polyethylene maleic anhydride; Nanocomposites; Compatibilizer; PE-g-MA; HDPE; NCC

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In this study, high-density polyethylene (HDPE), nano-calcium carbonate (NCC), and polyethylene-g-maleic anhydride (PE-g-MA) nanocomposites were prepared using the infusion shaping method. Different loadings of NCC and PE-g-MA were blended with HDPE, and the properties of the resulting nanocomposites were examined. The addition of NCC particles acted as a heat barrier and improved the dispersion of nanoparticles, while the incorporation of PE-g-MA enhanced the interfacial adhesion between the particles and HDPE.
High-density polyethylene (HDPE), nano-calcium carbonate (NCC) and polyethylene-g-maleic anhydride (PE-g-MA) nanocomposites were blended utilizing the infusion shaping strategy. Three frameworks of different NCC and PE-g-MA loadings were planned and fused into the lattice of HDPE. The qualities of each planned framework with various rates of NCC and PE-g-MA were checked. The hardening impact of these various loadings on the grid of HDPE was assessed. Mechanical, warm and physical examinations were performed on such nanocomposites tests to explore and think about their properties. The pliable highlights were estimated utilizing the automated mechanical general testing machine recording an expansion of 22% in the endure break contrasted with the flawless HDPE with keeping up the elastic worth demonstrating the hardening impact event. PE-g-MA affected the de-holding impact and raised the strength at yield point. TGA warm examination decided the warm decay of unadulterated HDPE and its nanocomposites. The NCC particles contributed in limiting the warmth saturation into the HDPE lattice by going about as a warmth hindrance during the warm deterioration measure and helping the development of carbide which forestalled the volatilization of the disintegrated materials. The joining of PE-g-MA improved the scattering of the NCC particles, the probabilities of agglomeration expanding the interfacial attachment between the nanoparticles and the HDPE grid. Dissolve stream list is a significant boundary which can anticipate the processability of polymeric materials. The expansion of PE-g-MA as a compatibilizer to the HDPE/NCC grid caused an expansion in the consistency which prompts a lessening in the dissolve stream list. This lessening is a mechanical preferred position that sparing the creation energy and may be ascribed to the physical snares that created among added substance and compatibilizer in the HDPE network.

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