期刊
POLYHEDRON
卷 242, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2023.116504
关键词
Fluoro stannane; Z -type ligand; Palladium; Bond activation
The chemistry of Z-type ligands has attracted attention due to their distinctive chemical bonds, properties, and reactivities. A study found that Lewis acidic fluorostannane coordination enhances nucleophilicity, providing new opportunities for Pd-catalyzed cross-coupling reactions. Through phosphine chelation, fluorostannane acts as a Lewis acid and weakens the strong and polar Sn-F bond via a-donation from the Pd center, allowing easy abstraction of the F atom. This enables the catalytic arylation of fluorostannane for the first time.
The chemistry of a-acceptor (Z-type) ligands has been attracting significant interest for some time, and the geometric and electronic structures featuring Z-type ligands have provided a profound understanding of their distinctive chemical bonds, chemical properties, and reactivities. We herein report that the coordination of Lewis acidic fluorostannane as Z-type ligands enhances their nucleophilicities, opening new opportunities for the development of Pd-catalyzed cross-coupling reaction of fluorostannanes as coupling reagents. Thanks to phosphine chelation, fluorostannane serves as a Lewis acid (Z-type ligand) toward Pd atom and withdraws electron density from the Pd center via the a*(Sn-F) orbital. Thus, the strong and polar Sn-F bond is efficiently weakened via a-donation from the Pd center. Accordingly, the F atom in fluorostannane was readily abstracted by even moderate Lewis acidic boranes, leading to the conversion of Z-type stannane to X-stannyl complexes. This key conversion enabled the catalytic arylation of fluorostannane for the first time.
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