Stress-induced change of ground-state energy of asemiconductor core-shell nanocrystal: Effect of mismatch strain and hydrostatic pressure

In this work, we study the effect of mismatch strain for coherent interface between the core and the shell of a Type I core/shell quantum dot (QD) on the ground-state energy of a particle in the core/shell QD under the framework of linear elasticity. Closed-form solution of the energy of the particle at ground state for the core and the shell being cubic structure is obtained, and the first order solution of the energy of the particle at ground state for the core and the shell being wurtzite structure is derived. The numerical results show that the energy change at ground state is proportional to hydrostatic stress and nonlinearly increases with the increase of the ratio of the shell thickness to the core radius. (c) 2023 Elsevier B.V. All rights reserved.

Automated summary

In this work, the effect of mismatch strain for the coherent interface between the core and shell of a Type I core/shell quantum dot (QD) on the ground-state energy of a particle in the core/shell QD is studied using the linear elasticity framework. Closed-form solutions for the energy of the particle at ground state are obtained for both the cubic and wurtzite structures of the core and shell. The numerical results demonstrate that the energy change at ground state is proportional to hydrostatic stress and increases non-linearly with the ratio of the shell thickness to the core radius.