期刊
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE
卷 -, 期 -, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/pssa.202300161
关键词
annealing; hole injection layer; organic light-emitting diodes; spontaneous polarization
In this study, the hole injection in organic light-emitting diodes (OLEDs) is improved by utilizing a P(VDF/TrFE) polymer layer as a hole injection layer on the indium tin oxide (ITO) electrode surface. The device's driving voltage is lowered due to the enhanced hole injection. Additionally, the structural change in the ultrathin P(VDF/TrFE) layer significantly enhances the hole injection in OLEDs.
An efficient carrier injection at the electrode/organic semiconductor interface of organic light-emitting diodes (OLEDs) is challenging. It is well-known that an electric dipole at the electrode/semiconductor interface improves the carrier injection from the electrode because of a vacuum-level shift. In this study, poly (vinylidene fluoride-trifluoroethylene) [P(VDF/TrFE)] is used as a polar polymer with spontaneous polarization. P(VDF/TrFE) is spin-coated on an indium tin oxide (ITO) electrode surface as a hole injection layer for OLEDs. The P(VDF/TrFE) layer enhances the hole injection from the ITO electrode by causing a vacuum-level shift. As a result, the device driving voltage can be lowered. In addition, annealing temperature dependence is observed. To investigate the origin of the hole injection effect, the P(VDF/TrFE)-layered ITO surface and the thin film structure of the P(VDF/TrFE) layer are measured. The P(VDF/TrFE) layers at different annealing temperatures show no difference in surface properties but show significant differences in the thin film structure. The hole injection of OLEDs is significantly enhanced because of the structural change in ultrathin P(VDF/TrFE) layer.
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