期刊
ORGANIC LETTERS
卷 25, 期 17, 页码 2958-2963出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.3c00574
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Alkyl tert-butyl peroxides are synthesized from their corresponding tert-alkyl precursors and tert-butyl hydroperoxide with the aid of a promoter. These peroxides can be used in a copper-catalyzed radical functionalization, which involves coupling with various partners and exhibits broad substrate compatibility. Mechanistic investigations suggest the involvement of alkyl radical species in the coupling reactions.
Alkyl tert-butyl peroxides are prepared from the corresponding tert-alkyl precursors and tert-butyl hydroperoxide in the presence of a promoter. These substrates can be utilized in a mild copper-catalyzed radical functionalization that utilizes several coupling partners and has a broad substrate scope. A mechanistic study suggests that alkyl radical species participate in the coupling reactions.
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