期刊
ORGANIC LETTERS
卷 25, 期 14, 页码 2492-2497出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.3c00671
关键词
-
A catalytic defluorinative boroarylation of alkenes with polyfluoroarenes and B(2)pin(2) was achieved using a PCy3-ligated copper catalyst. This method demonstrated good functional group compatibility and proceeded under mild reaction conditions, avoiding the need for stoichiometric quantities of organometallics. Valuable boronate-containing polyfluoroarenes, including challenging all-carbon quaternary carboncenter-containing triaryl alkylboronates, were efficiently synthesized.
A catalytic defluorinative boroarylation of alkenes with polyfluoroarenes and B(2)pin(2) with the assistance of a PCy3-ligated copper catalyst was developed. Taking advantage of benchstable alkenes as latent nucleophiles and avoiding traditional reliance on stoichiometric quantities of organometallics, this method showcased good functional group compatibility and proceeded under very mild reaction conditions. A series of valuable boronate-containing polyfluoroarenes including all-carbon quaternary carboncenter-containing triaryl alkylboronates that are otherwise difficult to access were efficiently prepared.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据