期刊
ORGANIC LETTERS
卷 25, 期 9, 页码 1514-1518出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.3c00304
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Two sets of cascade processes were achieved by benzyne insertion into the Se=O bond. The differential factors in these processes are the structures of diaryl selenium oxides and reaction conditions. When diaryl selenium oxides with an ortho weak Sigma- electron-withdrawing group were used, triarylselenonium salts were obtained at room temperature, while ortho-(aryloxy)phenyl phenyl selanes could be produced from diaryl selenium oxides at 100 degrees C.
Two sets of cascade processes have been realized, both of which were initiated with a benzyne insertion into the Se=O bond. The key factors to differentiate these processes are based on the structures of diaryl selenium oxides and reaction conditions. When diaryl selenium oxides containing an ortho weak Sigma- electron-withdrawing group were used, triarylselenonium salts were obtained at room temperature, while ortho-(aryloxy)phenyl phenyl selanes could be produced from diaryl selenium oxides at 100 degrees C.
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