期刊
ORGANIC LETTERS
卷 25, 期 12, 页码 2113-2117出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.3c00539
关键词
-
Here, a new method for synthesizing 2-aminobenzofuran 3-enes through the C-S insertion reaction of alkyne-tethered diazo compounds is reported. Metal carbene, as an active synthetic intermediate, plays a crucial role in organic synthesis. By utilizing the carbene/alkyne metathesis strategy, a novel donor carbene is generated in situ as a key intermediate with distinct reactions from the donor receptor carbene.
Herein, we report a new method of synthesizing of 2-aminobenzofuran 3-enes via the formal C-S insertion reaction of alkyne-tethered diazo compounds. Metal carbene, as a kind of active synthetic intermediate, plays a very important role in organic synthesis. Through the carbene/alkyne metathesis strategy, a new donor carbene is produced in situ as a key intermediate, which has different reactions from the donor receptor carbene.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据