期刊
ADVANCED MATERIALS
卷 27, 期 40, 页码 6195-6201出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201502442
关键词
crystallization-induced phosphorescence; intermolecular interactions; mechanochromism; persistent phosphorescence; pure organic luminogens
类别
资金
- National Natural Science Foundation of China [51473092, 21104044]
- Shanghai Rising-Star Program [15QA1402500]
Persistent room temperature phosphorescence (RTP) from pure organic luminogens can be rationally realized based on the crystallization-induced phosphorescence phenomenon and severe crystallization. A perfect crystal with dense molecular packing and effective intermolecular interactions isolates the triplet excitons from quenching sites and significantly blocks the high-energy vibrational dissipation, thus yielding long-lasting RTP.
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