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A discrete antimony(v) oxide

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NATURE CHEMISTRY
卷 15, 期 5, 页码 593-594

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NATURE PORTFOLIO
DOI: 10.1038/s41557-023-01191-4

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Monomeric stibine oxide has been difficult to obtain due to the large antimony orbitals and the high electronegativity difference with oxygen. However, a free tris(2,6-diisopropylphenyl)stibine oxide has been isolated and can serve as an oxo-transfer reagent.
Monomeric stibine oxide has remained elusive due to the large antimony orbitals coupled with a high electronegativity difference with oxygen. Now, a free tris(2,6-diisopropylphenyl)stibine oxide has been isolated that can act as oxo-transfer reagent.

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