期刊
NANO RESEARCH
卷 16, 期 4, 页码 4775-4785出版社
TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-022-5259-5
关键词
high-entropy layered oxides (HELOs); CO2 reduction; layered double hydroxides (LDHs); photoelectrocatalytic
In this study, Ni-Mn-Cu-Co-Fe-Al high-entropy layered oxides (HELOs) with a layered nanosheet structure were successfully constructed by a simple pathway of topological transformation under relatively low temperature. These HELOs exhibited excellent activity and selectivity for CO2 photoelectroreduction, and also showed improved performance in a photo-assisted Zn-CO2 battery.
High-entropy oxides receive significant attention owing to their four effects . However, they still suffer from harsh construction conditions such as high temperature and high pressure and present a block-like structure. Herein, in this work, Ni-Mn-Cu-Co-Fe-Al high-entropy layered oxides (HELOs) with a layered nanosheet structure were constructed by a simple pathway of topological transformation under relatively low temperature (300 ?) with six-membered Ni-Mn-Cu-Co-Fe-Al layered double hydroxides (LDHs) precursors, which exhibited an outstanding activity and excellent selectivity for CO2 photoelectroreduction (obtaining the highest carbon monoxide yield of 909.55 mu mol center dot g(-1)center dot h(-1) under -0.8 V vs. reversible hydrogen electrode (RHE), which is almost twice that of pure electrocatalysis). In addition, the charging voltage of a photo-assisted Zn-CO2 battery with HELOs as electrode was reduced from 2.62 to 2.40 V; the discharging voltage of the battery was increased from 0.51 to 0.59 V with the assistance of illumination. The improvement of round-trip efficiency of the battery indicates that light played a positive role in both the charging and discharging processes. This study not only lays an important foundation for the development of high-entropy oxides but also expands their application in the field of photoelectrochemistry.
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