NO2 Sensing Capability of Pt-Au-SnO2 Composite Nanoceramics at Room Temperature

Composite ceramics of metal oxides and noble metals have received much attention for sensing reducing gases at room temperature. Presently, composite ceramics of SnO2 and noble metals have been prepared and investigated for sensing oxidizing NO2 at room temperature. While dramatic increases in resistance were observed for both 1 wt% Pt-SnO2 and 5 wt% Au-SnO2 composite nanoceramics after being exposed to NO2 at room temperature, the largest increase in resistance was observed for 1 wt% Pt-5 wt% -Au-SnO2 composite nanoceramics among the three composites. The response to 0.5 ppm NO2--20% O-2-N-2 was as high as 875 at room temperature, with a response time of 2566 s and a recovery time of 450 s in the air of 50% relative humidity (RH). Further investigation revealed that water molecules in the air are essential for recovering the resistance of Pt-Au-SnO2 composite nanoceramics. A room temperature NO2-sensing mechanism has been established, in which NO2 molecules are catalyzed by Pt-Au to be chemisorbed on SnO2 at room temperature, and desorbed from SnO2 by the attraction of water molecules in the air. These results suggest that composite ceramics of metal oxides and noble metals should be promising for room temperature sensing, not only reducing gases, but also oxidizing gases.

Automated summary

Composite ceramics of metal oxides and noble metals have been widely studied for sensing reducing gases at room temperature. In this study, composite ceramics of SnO2 and noble metals were prepared and found to be effective in sensing oxidizing NO2 at room temperature. The Pt-Au-SnO2 composite nanoceramics showed the largest increase in resistance when exposed to NO2, with a high response and fast recovery time. The presence of water molecules in the air was found to be crucial for the recovery of resistance in the composite ceramics. Overall, this study establishes a room temperature NO2-sensing mechanism and highlights the potential of composite ceramics for sensing both reducing and oxidizing gases at room temperature.