4.6 Article

Preparation of PO43--Intercalated Calcium-Aluminum Hydrotalcites via Coprecipitation Method and Its Flame-Retardant Effect on Bamboo Scrimber

期刊

MOLECULES
卷 28, 期 10, 页码 -

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MDPI
DOI: 10.3390/molecules28104093

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bamboo scrimber; coprecipitation method; calcium-aluminum hydrotalcite; flame retardants; phosphate ion

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Flame-retardant CaAl-PO4-LDHs were synthesized via the coprecipitation method using PO43- as the anion of an intercalated calcium-aluminum hydrotalcite to improve the flame retardancy of bamboo scrimber. The CaAl-PO4-LDHs were characterized and used as flame retardants for bamboo scrimber, and their effects on flame retardancy were evaluated. The results showed that the CaAl-PO4-LDHs significantly decreased the peak heat release rate, delayed the time to exothermic peak, increased the Time to Ignition, and reduced the production of CO and CO2 in the bamboo scrimber.
To improve the flame retardancy of bamboo scrimber, flame-retardant CaAl-PO4-LDHs were synthesized via the coprecipitation method using PO43- as the anion of an intercalated calcium-aluminum hydrotalcite in this work. The fine CaAl-PO4-LDHs were characterized via X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), cold field scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) and thermogravimetry (TG). Different concentrations (1% and 2%) of CaAl-PO4-LDHs were used as flame retardants for the bamboo scrimber, and the flame retardancy of the bamboo scrimber was characterized via cone calorimetry. The results showed that CaAl-PO4-LDHs with excellent structures were successfully synthesized via the coprecipitation method in 6 h and at 120 degrees C. Compared with the bamboo scrimber without the flame retardant treatment, the peak heat release rate (HRR) of the bamboo scrimber treated with 1% and 2% concentrations of flame-retardant CaAl-PO4-LDHs decreased by 16.62% and 34.46%, the time taken to reach the exothermic peak was delayed by 103 s and 204 s and the Time to Ignition (TTI) was increased by 30% and 40%, respectively. Furthermore, the residual carbon of the bamboo scrimber did not change significantly, increasing by 0.8% and 2.08%, respectively. CO production decreased by 18.87% and 26.42%, respectively, and CO2 production decreased by 11.11% and 14.46%, respectively. The combined results show that the CaAl-PO4-LDHs synthesized in this work significantly improved the flame retardancy of bamboo scrimber. This work exhibited the great potential of the CaAl-PO4-LDHs, which were successfully synthesized via the coprecipitation method and applied as a flame retardant to improve the fire safety of bamboo scrimber.

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