期刊
MOLECULES
卷 28, 期 8, 页码 -出版社
MDPI
DOI: 10.3390/molecules28083535
关键词
[3+2] cycloaddition; nitrones; nitroalkenes; nicotinoids; molecular electron density theory
In this study, the [3+2] cycloaddition reactions involving Z-C-(3-pyridyl)-N-methylnitrone and series of E-2-R-nitroethenes were investigated both experimentally and theoretically using Molecular Electron Density Theory. The results demonstrate that these reactions proceed under mild conditions and exhibit complete regio- and stereocontrol. Additionally, the ELF analysis reveals a two-stage, one-step mechanism for the studied reaction.
[3 + 2] Cycloaddition reactions with the participation of Z-C-(3-pyridyl)-N-methylnitrone and series of E-2-R-nitroethenes were both experimentally and theoretically explored in the framework of Molecular Electron Density Theory. It was found that all considered processes are realized under mild conditions and in full regio- and stereocontrol. The ELF analysis additionally showed that the studied reaction proceeds by a two-stage, one-step mechanism.
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