Papers Magnetic critical behavior and room temperature magnetocaloric effect in Ba1.9Pr0.1FeMoO6 double perovskite compound

In this paper, we report the critical behavior related to the magnetocaloric effect of Ba1.9Pr0.1FeMoO6 double perovskite. A maximum magnetic entropy change, |Delta S-M(max)| similar to 0.68 Jkg(-1)K(-1) and relative cooling power, RCP -62 Jkg(- 1) were observed under applied field of H = 2.5 T. The critical exponents were evaluated by using modified Arrott plots, Kouvel-Fisher, critical isotherm analysis and Widom scaling relation methods. A second order phase transition (paramagnetic to ferromagnetic) was observed at Curie temperature, T-C = 319.73 K with critical exponents beta = 0.45, gamma = 0.84, and delta = 2.91. The value of these critical exponents shows that this sample obeys mean field model and Widom scaling relation. Also, we observed that the different isothermal magneti-zation data are able to collapse into the two branches below and above TC based on the single scaling equa-tion M(H, epsilon) = epsilon(beta)f +/-(H /epsilon(beta+gamma)) that affirms the authenticity of the critical exponents.

Automated summary

In this paper, the critical behavior of Ba1.9Pr0.1FeMoO6 double perovskite related to magnetocaloric effect is reported. A maximum magnetic entropy change of |Delta S-M(max)| similar to 0.68 Jkg(-1)K(-1) and a relative cooling power of RCP -62 Jkg(- 1) were observed under an applied field of H = 2.5 T. The critical exponents for the second order phase transition from paramagnetic to ferromagnetic state were determined as beta = 0.45, gamma = 0.84, and delta = 2.91. These values indicate that the sample obeys mean field model and Widom scaling relation. The collapse of different isothermal magnetization data into two branches below and above TC further confirms the authenticity of the critical exponents.