期刊
MATERIALS CHEMISTRY AND PHYSICS
卷 297, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2023.127369
关键词
Polyaniline; CMK-3; Hydroquinone; Supercapacitor
This study developed a hybrid electrode using ordered mesoporous carbon (CMK-3) as the electrical double-layer capacitor material and conductive polymer polyaniline (PANI) as the faradaic capacitance material. The PANi/CMK-3/HQ composite system exhibited high specific capacitance and excellent cyclic stability. This novel electrode provides a new route for the design and development of future supercapacitors.
Hybrid supercapacitors are important in energy storage modules owing to their high power density. High-power electrical double-layer capacitor (EDLC) materials are frequently used to host faradaic capacitance materials to maintain a high power density with improved energy density. Herein, a hybrid electrode was developed using ordered mesoporous carbon (CMK-3) as EDLC material and conductive polymer polyaniline (PANi) as faradaic capacitance material. The processing parameters and the synergistic effect of CMK-3 and PANi were determined. Hydroquinone (HQ) was added through charge-discharge in the electrolyte, and its concentration was opti-mized. The specific capacitance of the PANi/CMK-3/HQ composite system was 684 F/g, whereas those of the PANi/CMK-3 composite, pristine PANi, and CMK3 were 480, 135, and 101 F/g, respectively. The PANi/CMK-3/ HQ composite system exhibited excellent cyclic stability, maintaining capacitance retention of 95.45% after 1000 charge-discharge cycles. Finally, the practical applicability of our proposed PANi/CMK-3/HQ composite system was proved with series connected symmetric supercapacitor by powering up the light emitting diodes (LEDs) bulbs for 10 min. The proposed PANi/CMK-3/HQ electrode provides a new route for future super-capacitor design and development.
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