Synthesis and Properties of a Novel Thermally Conductive Pressure-Sensitive Adhesive with UV-Responsive Peelability

Thermally conductive pressure-sensitive adhesive (PSA) has received a great amount of attention in recent years, but the traditional PSA hardly loses adhesion properties after UV irradiation or heating. Therefore, endowing thermally conductive adhesive with UV-responsive peelability becomes a design strategy. Herein, vinyl-functionalized graphene (AA-GMA-G) is prepared by modifying graphene with acrylic acid and subsequently reacting with glycidyl methacrylate. Then, the UV-curable acrylate copolymer is synthesized by grafting glycidyl methacrylate. Finally, the novel thermally conductivity PSA with UV-responsive peelability is obtained by blending the copolymer with AA-GMA-G and photoinitiator. The results show that the PSA at 2 wt% AA-GMA-G loading exhibits an excellent thermal conductivity (0.74 W m(-1) K-1) and a relatively strong peel strength, increasing by 15% compared with pristine graphene/PSA. Interestingly, the peel strength of AA-GMA-G/PSA can achieve a dramatic drop after UV treatment, and the decrease rate is 96.7%. Therefore, the novel thermally conductive PSA with UV-responsive peelability has potential applications in certain electronic devices.

Automated summary

In recent years, there has been a great amount of attention on thermally conductive pressure-sensitive adhesive (PSA), but traditional PSAs do not easily lose adhesion properties after UV irradiation or heating. As a design strategy, this study focuses on developing a thermally conductive adhesive with UV-responsive peelability by modifying graphene with acrylic acid and glycidyl methacrylate. The results showed that the novel PSA with UV-responsive peelability exhibited excellent thermal conductivity and a relatively strong peel strength. It has potential applications in certain electronic devices.