期刊
LOW TEMPERATURE PHYSICS
卷 49, 期 3, 页码 338-344出版社
AIP Publishing
DOI: 10.1063/10.0017237
关键词
intermetallics; crystal structure; X-ray diffraction; magnetic properties
Polycrystalline samples of the ternary compounds R2Au2Pb were studied using powder X-ray diffraction and magnetic measurements. The crystal structure was found to be tetragonal, and the Y-, La-, and Lu-based phases were diamagnetic, while Yb2Au2Pb exhibited an intermediate valence system. The other R2Au2Pb ternaries showed antiferromagnetic ordering at low temperatures due to localized magnetic moments carried by trivalent R3+ ions.
Polycrystalline samples of the ternary compounds R2Au2Pb (R = Y, La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) were studied by means of powder X-ray diffraction and magnetic measurements. All these materials were found to crystallize with a tetragonal crystal structure of the Er2Au2Sn type (space group P4(2)/mnm, Pearson code tP20). The Y-, La-, and Lu-based phases were established to be diamagnetic, while Yb2Au2Pb was characterized as an intermediate valence system due to an unstable 4f shell. All the other R2Au2Pb ternaries were found to order antiferromagnetically at low temperatures (T-N in the range 2-30 K) due to the localized magnetic moments carried on trivalent R3+ ions.
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