4.5 Article

Exotic liquid crystalline phases in monolayers of vertically vibrated granular particles

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LIQUID CRYSTALS
卷 -, 期 -, 页码 -

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TAYLOR & FRANCIS LTD
DOI: 10.1080/02678292.2023.2200262

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Two-dimensional liquid crystals; density functional theory; vibrated monolayers of granular particles; Topological defects

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Vibrated monolayers of granular particles confined into horizontal cavities form fluid patterns with orientational order resembling liquid-crystal phases. Different shapes of particles exhibit various liquid-crystal phases, such as nematic and smectic patterns. The theoretical work and experimental results on rectangles and triangles, as well as the findings on cylinders and geometric frustration caused by confinement, are presented.
Vibrated monolayers of granular particles confined into horizontal cavities form a variety of fluid patterns with orientational order that resemble equilibrium liquid-crystal phases. In some cases, one can identify nematic and smectic patterns that can be understood in terms of classical statistical mechanics of hard bodies. Low aspect ratio cylinders project as rectangles and form uniaxial, or 2-atic, and tetratic, or 4-atic, nematic phases. Other polygonal particles may exhibit different liquid-crystal phases, in general p-atic phases, of higher symmetries. We give a brief summary of theoretical work on rectangles and triangles, and provide some experimental results on vibrated monolayers. In the case of equilateral triangles, the theory predicts an exotic triatic phase, or 6-atic phase, with six-fold symmetry and three equivalent directors. The right-angled triangles exhibit a 4-atic phase with strong octatic (8-atic) correlations. Experiments on cylinders show 4-atic textures and, even more remarkable, geometric frustration caused by confinement excites topological defects, which seem to follow the same topological rules as standard liquid crystals. Some of our findings can be understood with the help of simulations of hard particles subject to thermal equilibrium, although standard Density-Functional Theories fail to account for the correct equilibrium phases in some cases.

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