相关参考文献
注意：仅列出部分参考文献，下载原文获取全部文献信息。
Review
Chemistry, Physical
Mochen Jia et al.
Summary: Luminescent nanothermometry has attracted significant scientific attention for its ability to accurately measure the internal temperature of nanoscale objects. Lanthanide-based ratiometric luminescent thermometers, due to their high photochemical stability and superior thermometric performance, have found widespread applications in various fields. However, debates still exist regarding the temperature-sensing mechanisms, quantitative characterization of performance, and reliability of temperature readouts.
Review
Chemistry, Physical
Mochen Jia et al.
Summary: Luminescent nanothermometry is a promising technique for accurately measuring the internal temperature of nanoscale objects. Lanthanide-based ratiometric luminescent thermometers, with their high photochemical stability, low toxicity, and superior thermometric performance, have found widespread applications in various fields. However, there are still debates regarding the underlying temperature-sensing mechanisms, the quantitative characterization of performance, and the reliability of temperature readouts. This review provides insights into the origin of thermal response luminescence, rationalizes the ratiometric scheme or thermometric mechanisms, discusses the problems in the characterization of thermometric performance, and showcases the cutting-edge design and emerging applications of lanthanide-based ratiometric thermometers. The challenges and opportunities for further advances in this field are also discussed.
Article
Chemistry, Physical
Gaochao Liu et al.
Summary: In this study, broadband NIR phosphors were designed and optimized through chemical substitution to enhance thermal stability and quantum efficiency. The as-fabricated phosphor-in-glass-based NIR LED light source showed potential in alcohol concentration detection. This research provides a design principle for exploring NIR phosphors with improved thermal stability and will stimulate further material discovery and quantitative analysis research in NIR spectroscopy.
CHEMISTRY OF MATERIALS
(2022)
Article
Optics
Yuanbo Yang et al.
Summary: A new single-band ratiometric (SBR) thermometry is proposed by combining the temperature-induced red shift of charge transfer state (CTS) of W-O and Eu-O with the ground state absorption (GSA) and excited state absorption (ESA) of Eu3+. The SBR thermometry of Eu3+ doped calcium tungstate shows the highest relative sensitivity of 1.25% K-1 at 573K, surpassing conventional luminescent ratiometric thermometry methods.
Article
Optics
Hao Suo et al.
Summary: This study reports a novel double-perovskite phosphor La2MgHfO6:Cr3+/Yb3+ that exhibits ultra-broadband NIR emissions and remarkable luminescence properties. By controlling energy transfer process, the quantum efficiency and thermal stability of emissions are substantially improved. The phosphors are further integrated into a miniaturized NIR LED package, demonstrating superior performance.
LASER & PHOTONICS REVIEWS
(2022)
Article
Multidisciplinary Sciences
Enhai Song et al.
Summary: Photothermal sensing is crucial for smart wearable devices. Researchers have developed a dual-wavelength emitting material Li2ZnSiO4:Mn2+ and a wearable optical fibre temperature sensor, which demonstrates stable ratiometric temperature sensing in both contact and noncontact modes. The sensor integrated into a wearable mask shows great potential for detecting physiological thermal changes, making it suitable for wearable health monitoring.
NATURE COMMUNICATIONS
(2022)
Article
Multidisciplinary Sciences
Jinsheng Liao et al.
Summary: This study reports a unique two-dimensional negative-thermal-expansion phosphor and discovers enhanced green upconversion and near-infrared downshifting luminescence with increasing temperature. The investigation of the luminescence mechanism, temperature dependence of the luminescence lifetime, and the application of temperature sensing provide important insights into the design of negative-thermal-expansion phosphors.
NATURE COMMUNICATIONS
(2022)
Article
Optics
Xiuxia Yang et al.
Summary: In this paper, a novel strategy based on a lanthanide structural probe is demonstrated to realize ratiometric mechanoluminescence (ML) for stress sensing, aiming at improving the reliability of stress sensing by establishing the relationship between the ML asymmetry ratio of the structural probe and the applied stress through stress-induced change in local site symmetry.
LASER & PHOTONICS REVIEWS
(2022)
Article
Optics
Erving Ximendes et al.
Summary: This study improves the thermal resolution of luminescent thermometers by using dimensionality reduction techniques on calibration datasets, enabling precise monitoring of temperature changes smaller than 0.1 degrees C.
LIGHT-SCIENCE & APPLICATIONS
(2022)
Editorial Material
Optics
Hongjie Zhang et al.
LIGHT-SCIENCE & APPLICATIONS
(2022)
Article
Optics
Wei Xu et al.
Summary: This paper proposes a strategy to implement effective luminescence nanothermometry by utilizing the different thermal responses between Yb3+ -> Nd3+ and Nd3+ -> Yb3+ energy transfer processes. Unlike the traditional ratiometric sensing method, this technique uses intensity ratios between Yb3+ and Nd3+ near-IR emissions as the detecting and reference signals for temperature measurement, showing excellent immunity to interference and high thermal sensitivity.
PHOTONICS RESEARCH
(2022)
Article
Engineering, Environmental
Luyao Pu et al.
Summary: A facile hydrothermal method was developed to construct monodispersed candy-like NaY(MoO4)2:Yb3+/Nd3+ micro-thermometers, which exhibited efficient near-infrared anti-stokes luminescence. By leveraging active lattice phonon and phonon-assisted Yb3+ -> Nd3+ energy transfer, the luminescence intensity was greatly enhanced with high sensitivity and resolution for multi-mode thermometry.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Inorganic & Nuclear
Lei Zhong et al.
Summary: A novel ratiometric luminescence thermometry strategy was proposed in this study, combining the thermally induced redshift of the charge transfer band with the dramatic quenching of the intervalent charge transition in Dy3+ and Pr3+ doped MNO phosphors. The emission color of the sample changes significantly with temperature, allowing for visual temperature sensing. The Dy3+ and Pr3+ activated MNO phosphors show excellent sensitivity, signal resolution, reversibility, and temperature resolution, making them promising for luminescence thermometry and safety markers.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Review
Materials Science, Multidisciplinary
Joanna Stefanska et al.
Summary: Luminescence thermometry has gained increasing interest from the fundamental research community, and it is further stimulated by the needs and challenges of other fields of science and technology. Although many temperature-responsive luminescent phosphors have been proposed, their optimization has not radically improved their sensitivity and accuracy, nor simplified temperature measurements for growing demands or specific applications. However, occasionally, new materials and dedicated readout techniques are proposed that contribute significantly to the development of new approaches.
JOURNAL OF MATERIALS CHEMISTRY C
(2022)
Article
Nanoscience & Nanotechnology
Joanna Drabik et al.
Summary: The luminescence thermometry method utilizes the strong thermal dependence of thermally induced excited state absorption to improve temperature readout parameters, and can be applied for 2D thermal imaging of microelectronic printed circuit boards using the strong color changes exhibited by phosphors.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Review
Chemistry, Inorganic & Nuclear
Naike Shi et al.
Summary: Negative thermal expansion (NTE) is a counterintuitive phenomenon where unit cell volume of materials contracts upon heating. Framework structure materials, with flexible bridging units and large voids, facilitate transverse atomic vibrations leading to NTE. The magnitude of NTE is influenced by framework size and metal atom size, and can be controlled through chemical substitution, local structure distortion, and guest molecular or ion intercalation.
COORDINATION CHEMISTRY REVIEWS
(2021)
Review
Optics
Hao Suo et al.
Summary: Noninvasive lanthanide-doped optical thermometers based on fluorescent intensity ratio technique and near-infrared light-responsive nanothermometers show great potential for biomedical applications. These technologies offer new possibilities for temperature measurement in inaccessible areas and deep tissues.
LASER & PHOTONICS REVIEWS
(2021)
Article
Chemistry, Inorganic & Nuclear
Jingyu Feng et al.
Summary: This study explores the site occupation preference of Eu3+ ions in K3LuSi2O7 and its spectral properties, revealing the formation of two types of Eu3+-O2- CTBs and the thermal enhancement of CTB at high temperatures. The findings suggest a new approach for designing luminescent phosphors and introduce a noninvasive optical thermometer based on the opposite variation in excitation spectra.
INORGANIC CHEMISTRY
(2021)
Article
Optics
Lixin Peng et al.
Summary: This study focused on high-performance fluorescence intensity ratio (FIR) thermometry utilizing the temperature-induced redshift of the charge transfer band (CTB), with a theoretical highest relative sensitivity of 1.86% K-1 and lowest uncertainty of 0.1 K at 783 K. Optimum excitation wavelengths for positive and negative monochrome sensitivity were determined, contributing to the development of an effective temperature sensing strategy.
Article
Optics
Peipei Dang et al.
Summary: The development of a highly efficient red-emitting phosphor, CEGO, with high color purity and excellent thermal stability shows great potential as a red component for pc-WLEDs, providing a new perspective for developing new phosphor materials.
LIGHT-SCIENCE & APPLICATIONS
(2021)
Review
Physics, Applied
A. Bednarkiewicz et al.
Summary: The article discusses the importance of using luminescent probes to obtain thermal images of living organisms, and the current focus on the development and optimization of luminescent reporters. It also points out the lack of attention to the methods and technologies required to image temperature distribution at both in vitro or in vivo levels.
APPLIED PHYSICS REVIEWS
(2021)
Article
Optics
Dechao Yu et al.
Summary: Ratiometric luminescence thermometry using trivalent lanthanide ions and their 4f(n) energy levels allows for high precision temperature measurements. However, conventional Boltzmann thermometry relies on thermal coupling between two energy levels, limiting its accuracy to a narrow temperature range.
LIGHT-SCIENCE & APPLICATIONS
(2021)
Article
Materials Science, Ceramics
Liangjun Zhou et al.
Summary: The study demonstrates that thermal quenching in rare earth doped phosphors used in LEDs can be suppressed by the negative thermal expansion effect in Zr(WO4)(2), leading to enhanced luminescence intensity. This anti-thermal quenching effect is mainly attributed to the enhanced structural rigidity of the host lattice and an increase in electrons on the excited energy levels due to electron traps in the host.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Multidisciplinary
Jinmeng Xiang et al.
Summary: Controlling plant growth environment with pc-LEDs is crucial for regulating growth rhythm and increasing yield. The developed phosphor NBSP:Eu2+ exhibits high quantum yield and excellent thermal stability in the blue-violet region, showing promising potential for application in plant growth LEDs.
MATERIALS CHEMISTRY FRONTIERS
(2021)
Article
Optics
Yi Wei et al.
Summary: Ba2ZnGe2O7:Bi3+ phosphor exhibits anti-thermal-quenching property with increased emission intensity at high temperatures. Artificially creating zinc and oxygen vacancy defects can enhance emission intensity. The anti-TQ phenomenon is mainly attributed to high structure rigidity and strong ability to compensate emission loss.
LASER & PHOTONICS REVIEWS
(2021)
Article
Chemistry, Physical
Hua Zou et al.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2020)
Article
Optics
Qianyang Chang et al.
Article
Chemistry, Multidisciplinary
Anna M. Kaczmarek et al.
ADVANCED FUNCTIONAL MATERIALS
(2020)
Article
Chemistry, Inorganic & Nuclear
Mochen Jia et al.
INORGANIC CHEMISTRY FRONTIERS
(2020)
Article
Chemistry, Multidisciplinary
Ping Huang et al.
Article
Chemistry, Physical
Sergii Yakunin et al.
Article
Chemistry, Multidisciplinary
Hua Zou et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2019)
Review
Materials Science, Multidisciplinary
Carlos D. S. Brites et al.
ADVANCED OPTICAL MATERIALS
(2019)
Article
Chemistry, Inorganic & Nuclear
Shaoshuai Zhou et al.
DALTON TRANSACTIONS
(2018)
Article
Chemistry, Multidisciplinary
Hao Suo et al.
Article
Multidisciplinary Sciences
Ming Xu et al.
NATURE COMMUNICATIONS
(2018)
Article
Optics
Shaoshuai Zhou et al.
Article
Chemistry, Physical
Yoon Hwa Kim et al.
Article
Optics
Shaoshuai Zhou et al.
Review
Chemistry, Inorganic & Nuclear
Koen Binnemans
COORDINATION CHEMISTRY REVIEWS
(2015)
Article
Chemistry, Physical
Yue Tian et al.
JOURNAL OF PHYSICAL CHEMISTRY C
(2009)
Article
Materials Science, Multidisciplinary
Meera Keskar et al.
MATERIALS RESEARCH BULLETIN
(2009)
