4.4 Article

Sustainable production of acrolein over highly stable and selective WO3 over SiO2-TiO2 catalysts

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Catalytic Deactivation of HY Zeolites in the Dehydration of Glycerol to Acrolein

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Summary: The study found that increasing the SiO2/Al2O3 molar ratio of HY zeolites decreases the total amount of acid sites per unit area, leading to a reduced initial glycerol conversion; however, the initial acrolein selectivity increases with the higher Brønsted/Lewis acid sites ratio. The catalyst lifetime depends on pore structure, with larger surface areas improving deactivation rate constants.

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