4.8 Article

3D Scaffolded Nickel-Tin Li-Ion Anodes with Enhanced Cyclability

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ADVANCED MATERIALS
卷 28, 期 4, 页码 742-747

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WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201504780

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  1. U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering through the Frederick Seitz Materials Research Laboratory at the University of Illinois at Urbana-Champaign [DE-FG02-07ER46471]
  2. Nanjing University Creation Talent Program [021314310023]

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A 3D mechanically stable scaffold is shown to accommodate the volume change of a high-specific-capacity nickeltin nanocomposite during operation as a Li-ion battery anode. The nickel-tin anode is supported by an electrochemically inactive conductive scaffold with an engineered free volume and controlled characteristic dimensions, which engender the electrode with significantly improved cyclability.

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