期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 145, 期 19, 页码 10480-10485出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.3c02497
关键词
-
We have developed a convenient method for degrading polyacrylate homopolymers. Carboxylic acids are introduced into the polymer backbone through hydrolysis of the ester side chains, and then converted into alkenes and oxidatively cleaved in a one-pot sequential procedure. This method allows the robustness and properties of polyacrylates to be maintained during their usable lifetime. The degree of degradation can be tuned by varying the carboxylic acid content of the polymers. This method is compatible with a wide range of polymers prepared from vinyl monomers through copolymerization with different monomers including acrylates, acrylamides, and styrenics.
We establish a synthetically convenient method to degrade polyacrylate homopolymers. Carboxylic acids are installed along the polymer backbone by partial hydrolysis of the ester side chains, and then, in a one-pot sequential procedure, the carboxylic acids are converted into alkenes and oxidatively cleaved. This process enables the robustness and properties of polyacrylates to be maintained during their usable lifetime. The ability to tune the degree of degradation was demonstrated by varying the carboxylic acid content of the polymers. This method is compatible with a wide range of polymers prepared from vinyl monomers through copolymerization of acrylic acid with different monomers including acrylates, acrylamides, and styrenics.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据