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Article
Nanoscience & Nanotechnology
Xingfa Chen et al.
Summary: This study investigates hexagonal WO3/three-dimensional porous graphene (h-WO3/3DG) as an intercalation anode material for Zn-ion batteries (ZIBs), demonstrating its excellent electrochemical performance. A zinc metal-free full battery is also constructed, highlighting the potential of h-WO3 as an advanced intercalation anode material for ZIBs.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Review
Chemistry, Multidisciplinary
Yanqun Lv et al.
Summary: This review presents the recent development of beyond aqueous electrolytes for Zn-ion batteries, including various types of electrolytes and the critical issues and corresponding strategies for designing beyond aqueous electrolytes.
ADVANCED MATERIALS
(2022)
Review
Chemistry, Multidisciplinary
Jin Cao et al.
Summary: This paper reviews the strategies of regulating Zn2+ solvation shells in electrolytes based on electrolyte engineering for dendrite-free and side reaction-suppressed aqueous zinc-ion batteries. Fruitful achievements have been made by controlling Zn2+ solvation shells through high-concentration electrolytes, deep eutectic solvents, ionic liquids, functional additives, etc.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Article
Chemistry, Physical
Fuhan Cui et al.
Summary: The study presents a high-performance NH4V4O10-x @rGO cathode for aqueous zinc-ion batteries, featuring oxygen vacancies and reduced graphene oxide surface modification. This cathode shows high capacity, impressive rate ability, and stable cycle performance, providing a reasonable strategy for improving the electrochemical performance of zinc-ion batteries through deficiency and surface engineering.
ENERGY STORAGE MATERIALS
(2022)
Article
Green & Sustainable Science & Technology
Daliang Han et al.
Summary: Aqueous zinc batteries are safer than lithium-ion batteries, but their anodes are susceptible to dendrite failure and side reactions. The authors demonstrate a low-cost electrolyte that involves hydrate salt and organic solvent, proving to be non-flammable. The zinc battery cell delivers excellent performance even at low temperatures of -30 degrees Celsius.
NATURE SUSTAINABILITY
(2022)
Article
Nanoscience & Nanotechnology
Yuanyuan Ren et al.
Summary: This study proposed a simple and universal method for fabricating single-particle microelectrodes, which showed excellent electrochemical properties when applied to different materials. The single-particle microelectrode can be used to study the electrochemical oscillations of Li-ion batteries and assemble a full-cell microbattery.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Fangwang Ming et al.
Summary: This work proposes a hybrid electrolyte induced by the salting-in effect as an effective strategy to achieve a highly reversible zinc anode with good stability and compatibility. By altering the solvation structure and reducing parasitic side reactions, this electrolyte ensures a stable zinc anode with excellent cycling stability.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Evan Miu et al.
Summary: In this study, the critical influence of hydrogen intercalation on the activity of tungsten trioxide in the hydrogen evolution reaction is demonstrated using experimental and computational methods. Unlike previous heterogeneous catalysis research focusing on surface processes, this study reveals the crucial role of bulk oxide modification in the experimental hydrogen evolution activity.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Review
Materials Science, Multidisciplinary
Chaowei Li et al.
Summary: This article reviews the application of flexible solid-state aqueous batteries (FSABs) in wearable electronic devices and provides detailed information on the engineering, design, and characterization of these batteries. The article summarizes the recent progress in the electrochemical performance and mechanical flexibility of FSABs and offers insights into the major challenges and future prospects in this research area.
MATERIALS SCIENCE & ENGINEERING R-REPORTS
(2022)
Article
Materials Science, Multidisciplinary
Ya Huang et al.
Summary: Dual-band electrochromic smart windows, regarded as an attractive option to reduce energy consumption, face challenges in modulation selectivity and durability. This study constructs a unique pine-needle-like heterostructure, demonstrating superior performance and patterned EC layers on conductive glass and films.
ADVANCED OPTICAL MATERIALS
(2022)
Article
Chemistry, Physical
Bhaskar Kakoty et al.
Summary: This study focuses on the improvement of aqueous rechargeable zinc-ion batteries by introducing highly polar propylene carbonate (PC), which suppresses water-derived parasitic reactions and enhances battery performance. The addition of a small amount of PC in the zinc ion electrolyte results in a stable zinc plating/stripping process and inhibits the dissolution of the cathode, leading to exceptional capacity and coulombic efficiency.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Chemistry, Multidisciplinary
Huanyan Liu et al.
Summary: This research proposes a novel metal-organic complex interphase strategy to address the corrosion and dendrite issues in aqueous Zn metal batteries. By forming complex interphases between metal Zn and phytic acid, the deposition of Zn is made more uniform and the Coulombic efficiency is significantly improved, leading to enhanced stability and cycling lifetime of Zn metal batteries.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Review
Chemistry, Multidisciplinary
Jiangtao Hu et al.
Summary: The achievement of high concentration electrolyte (HCE) is an important breakthrough for high-energy-density lithium-ion batteries (LIBs) in the growing electric vehicle market. By altering the aggregation of cations, HCE offers technical superiority over conventional dilute electrolytes. Recently, the concept of localized HCE (LHCE) has been proposed and extensively investigated, contributing to the optimization of electrolyte structures for improved battery performance.
Article
Chemistry, Physical
Shan Guo et al.
Summary: Electrolyte additive is a key technology in energy storage, especially for aqueous zinc-ion batteries, but there is a lack of systematic research on its features and mechanisms. A comprehensive review on commonly used zinc-ion electrolyte additives is essential for further improvements in this field.
ENERGY STORAGE MATERIALS
(2021)
Article
Engineering, Environmental
Jin Cao et al.
Summary: A novel rocking-chair ZIBs with excellent cycling stability and high energy density is developed by employing tungsten oxide/carbide (WO3/WC) layered heterogeneous hybrid as the intercalated anode and MnO2/graphite cathode. The batteries deliver admirable capacity and long-term cyclability, offering excellent capacity, cyclic stability, and energy density. This research provides a novel insight for designing safe and high-efficient ZIBs.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Energy & Fuels
Qingyi Huang et al.
Summary: The study focuses on improving the performance of Zn2+-based electrochromic technology through morphology control, using WO3 as the research model. Different shapes of hexagonal WO3 films were successfully prepared, showing promising electrochromic properties.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2021)
Article
Chemistry, Physical
Yuanhao Shen et al.
Summary: Water-in-salt electrolyte has improved the performance of aqueous lithium-ion batteries, but also increased the cost, hence aqueous sodium-ion batteries and zinc-based batteries show potential as alternatives.
ENERGY STORAGE MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Saida Cora et al.
Summary: Multivalent chemistry offers benefits for developing energy storage technologies beyond lithium ion. Metallic zinc anodes are appealing for secondary ion batteries due to their high volumetric capacity at a low cost. However, the complex interfacial mass exchange at the Zn electrolyte/anode boundary and the dynamic progression of the solid electrolyte interphase (SEI) are still not fully understood. Critical differences were observed in SEI formation between nonaqueous and aqueous Zn electrolytes for reversible Zn deposition, with a disproportional loss of coulombs in the nonaqueous electrolyte suggesting in situ formation of an ionically permeable SEI layer.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Yufei Lu et al.
Summary: Flexible aqueous zinc-ion batteries demonstrate high performance and cycle life through electrolyte dynamics engineering strategy. They also show excellent flexibility to charge smart watches under deformed states, providing new opportunities for the development of wearable electronics.
Review
Chemistry, Multidisciplinary
Xiao Wang et al.
Summary: This review discusses the key challenges of rechargeable aqueous zinc-ion batteries, analyzing the structural features and electrochemical properties of different cathode materials, and proposing various electrode design strategies to guide future research activities. The focus is mainly on achieving high energy density and durable cathode materials.
Article
Chemistry, Multidisciplinary
Xuan Qiu et al.
Summary: A new organic electrolyte containing zinc trifluoromethanesulfonate salt and a mixed solvent has been proposed for zinc batteries, which shows high ionic conductivity, wide potential window, and dendrite-free zinc plating/stripping. A 2 V zinc//polytriphenylamine composite battery fabricated with the optimized electrolyte exhibits high performance and long cycle life even with high mass-loading of PTPAn in the cathode and high zinc-utilization.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Qiu Zhang et al.
Summary: The study introduces a novel electrolyte design strategy to transform Zn(H2O)(6)(2+) into ZnCl42-, which suppresses the dendritic growth and interface hydrogen evolution reaction in Zn batteries. This approach enables uniform Zn deposition and high Coulombic efficiency, leading to long lifespan metal anode batteries.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Lei Yan et al.
Summary: The study introduces a long-life and high-rate Zn-organic battery using a poly(1,5-naphthalenediamine) cathode and Zn anode in an alkaline electrolyte. The organic cathode shows excellent self-rechargeability, leading to a high energy density for the Zn-organic battery.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Multidisciplinary
Qi Wu et al.
Summary: The newly demonstrated multilayered metal-dielectric metamaterials (MMDMs) serve as a new family of inorganics-based EC materials to achieve dynamic alternation among multicolors with high contrast and high color purity. This is achieved by significantly enhancing the confinement of the incident light in specific optical frequencies.
Article
Multidisciplinary Sciences
Zirui Lin et al.
Summary: In this study, tetraamino-p-benzoquinone was used as a cathode material to achieve facile proton conduction through the Grotthuss-type mechanism, showing excellent electrochemical performance. This work proposes an effective approach towards high performance organic electrode materials, with the flexible structural design of organic materials making them promising candidates for cathode in rechargeable batteries.
NATURE COMMUNICATIONS
(2021)
Article
Materials Science, Multidisciplinary
Shen Wang et al.
Summary: This study explores the synchronous optical and electrochemical performance correspondence relationship of ESCs constructed with a 3D WO3-x nanowire networks/fluorine-doped tin oxide bifunctional electrode, revealing high areal capacity, excellent optical modulation, and stability. Moreover, it reveals the synergistic reaction mechanism between Al3+ ion intercalation behavior and surface pseudocapacitance reaction, providing a promising pathway for developing multi-functional integrated smart supercapacitors.
NPG ASIA MATERIALS
(2021)
Article
Electrochemistry
Xiulei Ji
Summary: Molten ZnCl2 hydrates are ionic liquids with intriguing physical and electrochemical properties, suitable for use as electrolytes in Zn metal batteries. Understanding the properties of molten ZnCl2 hydrates is crucial for designing high-performance electrolytes.
Review
Chemistry, Physical
Jiahui Lu et al.
Summary: The increasing demand for alternative energy sources has led to rapid development of new energy storage technologies. Multivalent ion batteries like zinc, calcium, aluminum, and magnesium-ion are promising for large-scale energy storage due to abundance of raw materials and high energy density. However, challenges such as low electrochemical reversibility and safety concerns related to side reactions need to be addressed for practical applications.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Multidisciplinary
Yinxiang Zeng et al.
Summary: A template-engaged ion exchange approach was developed for synthesizing Co-substituted Mn-rich PBA hollow spheres, which showed efficient zinc ion storage properties with high capacity, decent rate capability, and prolonged cycle life.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Korkrit Songmueang et al.
Summary: This research developed a flower-like W/WO3 hybrid as a cathode for ZIBs, showing exceptional rate performance and cycling performance. Additionally, the reversible Zn2+ insertion/extraction mechanism in W/WO3 was demonstrated for the first time, along with the impressive flexibility and capabilities of the soft-packaged batteries.
CHEMICAL COMMUNICATIONS
(2021)
Review
Chemistry, Multidisciplinary
Pragati A. Shinde et al.
Review
Materials Science, Multidisciplinary
Zhen Wang et al.
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(2020)
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Jun Ming et al.
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(2016)
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JOURNAL OF MATERIALS CHEMISTRY
(2012)
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Manickam Sasidharan et al.
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2008)
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CV Ramana et al.
JOURNAL OF PHYSICAL CHEMISTRY B
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