Luminescence Enhancement of CsMnBr3 Nanocrystals through Heterometallic Doping

The absorption and photoluminescence (PL) of CsMnBr3 with Mn(II) in octahedral crystal fields are extremely weak due to a d-d forbidden transition. Herein, we introduce a facile and general synthetic procedure that can prepare undoped and heterometallic doped CsMnBr3 NCs at room temperature. Importantly, both PL and absorption of CsMnBr3 NCs were significantly improved after doping a small amount of Pb2+ (4.9%). The absolute photoluminescence quantum yield (PL QY) of Pb-doped CsMnBr3 NCs is up to 41.5%, 11-fold higher than undoped CsMnBr3 NCs (3.7%). The PL enhancement is attributed to the synergistic effects between [MnBr6](4-) units and [PbBr6](4-) units. Furthermore, we verified the similar synergistic effects between [MnBr6](4-) units and [SbBr6](4- )units in Sb-doped CsMnBr3 NCs. Our results highlight the potential of tailoring luminescence properties of manganese halides through heterometallic doping.

Automated summary

A facile and general synthetic procedure was introduced to prepare undoped and heterometallic doped CsMnBr3 NCs at room temperature. By doping a small amount of Pb2+ (4.9%), both photoluminescence (PL) and absorption of CsMnBr3 NCs were significantly improved. The absolute PL quantum yield of Pb-doped CsMnBr3 NCs is up to 41.5%, 11-fold higher than undoped CsMnBr3 NCs (3.7%). The PL enhancement is attributed to the synergistic effects between [MnBr6](4-) units and [PbBr6](4-) units.