4.6 Article

Kinetics of Metastable Argon Optical Excitation and Gain in Ar/He Microplasmas

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JOURNAL OF PHYSICAL CHEMISTRY A
卷 127, 期 11, 页码 2489-2502

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AMER CHEMICAL SOC
DOI: 10.1021/acs.jpca.3c00048

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The optically pumped rare-gas metastable laser uses photoexcitation and collisional energy transfer to achieve high-intensity laser output. It can be used for a broad range of near-infrared transitions.
The optically pumped rare-gas metastable laser is capable of high-intensity lasing on a broad range of near-infrared transitions for excited-state rare gas atoms (Ar*, Kr*, Ne*, Xe*) diluted in flowing He. The lasing action is generated by photoexcitation of the metastable atom to an upper state, followed by collisional energy transfer with He to a neighboring state and lasing back to the metastable state. The metastables are generated in a high-efficiency electric discharge at pressures of similar to 0.4 to 1 atm. The diode-pumped rare-gas laser (DPRGL) is a chemically inert analogue to diode-pumped alkali laser (DPAL) systems, with similar optical and power scaling characteristics for high-energy laser applications. We used a continuous-wave linear microplasma array in Ar/He mixtures to produce Ar(1s5) (Paschen notation) metastables at number densities exceeding 1013 cm-3. The gain medium was optically pumped by both a narrow-line 1 W titanium-sapphire laser and a 30 W diode laser. Tunable diode laser absorption and gain spectroscopy determined Ar(1s5) number densities and small-signal gains up to similar to 2.5 cm-1. Continuous-wave lasing was observed using the diode pump laser. The results were analyzed with a steady-state kinetics model relating the gain and the Ar(1s5) number density.

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