期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 88, 期 9, 页码 6176-6181出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.3c00201
关键词
-
This study investigates the photoinduced C-X borylation reaction of aryl halides via the formation of a halogen-bonding (XB) complex using 2-naphthol as an XB acceptor. The method is chemoselective and tolerant to a broad range of functional groups, providing a concise route to corresponding boronate esters. Mechanistic studies reveal that the formation of the XB complex between aryl halide and naphthol acts as an electron donor-acceptor complex, generating aryl radicals through photoinduced electron transfer.
This study investigates the photoinduced C-X borylation reaction of aryl halides by forming a halogen-bonding (XB) complex using 2-naphthol as an XB acceptor. The method is chemoselective and broadly functional group tolerant and provides concise access to corresponding boronate esters. Mechanistic studies reveal that forming the XB complex between aryl halide and naphthol acts as an electron donor-acceptor complex to furnish aryl radicals through photoinduced electron transfer.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据