期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 88, 期 13, 页码 8802-8824出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.3c00632
关键词
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Thieno[2 ',3 ',4 ':4,5]naphtho[1,8-cd]pyridines, S,N-doped pyrene analogs, were synthesized by combination of Pd catalyzed cross-coupling reactions and acid-mediated cycloisomerization. The modular synthesis approach allowed for the preparation of various functionalized derivatives. The photophysical properties were extensively studied using steady-state and femtosecond transient absorption along with cyclic voltammetry and (TD)-DFT calculations. The introduction of a five-membered thiophene into the 2-azapyrene scaffold resulted in redshifted emission and significant effects on excited state dynamics, such as quantum yield, lifetime, decay rates, and ISC ability, which could be further controlled by the substitution pattern of the heterocyclic scaffold.
Thieno[2 ',3 ',4 ':4,5]naphtho[1,8-cd]pyridines, S,N-doped pyrene analogs, were prepared bycombinationof Pd catalyzed cross-coupling reactions and acid-mediated cycloisomerization.The modular scope of the synthesis allowed for access to a varietyof functionalized derivatives. The photophysical properties have beenstudied in detail by steady-state and femtosecond transient absorptionaccompanied by cyclic voltammetry and (TD)-DFT calculations. The introductionof a five-membered thiophene into the 2-azapyrene scaffold leads toredshifted emission and substantial effects on the excited state dynamics,e.g., quantum yield, lifetime, decay rates, and the ISC ability, whichcan be further tuned by the substitution pattern of the heterocyclicscaffold.
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