期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 88, 期 7, 页码 4875-4879出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.3c00197
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This article describes an Fe-catalyzed coupling reaction between oxime ester and benzothiazole, which involves C-C bond cleavage of oxime ester through a single-electron transfer process. This iron catalytic system performed in water under mild reaction conditions offers a streamlined strategy for the construction of alkyl nitrile substituted benzothiazole derivatives. The application of this strategy for the synthesis of some key important compounds, including 4-heterocyclic-3-arylbutanoic acid, is also reported.
An Fe-catalyzed coupling reaction between oxime ester and benzothiazole is described, which involves C-C bond cleavage of oxime ester via a single-electron transfer process. This iron catalytic system performed in water under mild reaction conditions offers a streamlined strategy to the construction of alkyl nitrile substituted benzothiazole derivatives. Application of this strategy for the synthesis of some key important compounds including 4-heterocyclic-3-arylbutanoic acid is also reported.
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