期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 88, 期 7, 页码 4254-4263出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.2c02815
关键词
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A Pd(II)-catalyzed dehydrogenative remote C4-H coupling of indoles with unfunctionalized arenes at room temperature was achieved using a weak chelating trifluoroacetyl group as a directing group. Various substituents on the arenes were compatible with the dehydrogenative cross coupling reaction.
A Pd(II)-catalyzed dehydrogenative remote C4-H coupling of indoles with unfunctionalized arenes at room temperature was reported. The weak chelating trifluoroacetyl group at the C3-position served as a directing group for the remote C4-H activation. Arenes with a wide range of substituents were employed as the coupling partner in the dehydrogenative cross coupling reaction.
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