Synthesis and Characterization of Azido-Functionalized 1,2,3-Triazole and Fused 1,2,3-Triazole

Article Engineering, Environmental

Tricyclic nitrogen-rich cation salts based on 1,2,3-triazole: Chemically stable and insensitive candidates for novel gas generant

Hao Gu et al.

Summary: A series of new nitrogen-rich compounds were synthesized, with energetic salt 8 being a unique zwitterionic salt. These compounds exhibit good thermal stability and combustion performance, showing potential as novel gas generants.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Applied

About the Azido Derivatives of Pentaerythritol Tetranitrate

Tobias Lenz et al.

Summary: By synthesizing a series of azidonitrate derivatives, this study revealed significant differences in their properties, including chemical and energetic aspects such as melting points and mechanical sensitivities. The research results showed a decreasing trend in melting points among these compounds, with the tetraazido derivative exhibiting the highest sensitivity.

PROPELLANTS EXPLOSIVES PYROTECHNICS (2021)

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Article Engineering, Environmental

1,2,3-Triazole with linear and branched catenated nitrogen chains - The role of regiochemistry in energetic materials

Qi Lai et al.

Summary: Two energetic molecules with different linear and branched N8 structures were synthesized, showing a significant difference in decomposition temperatures despite having the same chemical formula and azo functionality. Analysis based on single crystal X-ray diffraction and theoretical investigations revealed that regional heterogeneity causing difference in charge distribution is the main factor contributing to the varying stabilities of these molecules.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Multidisciplinary

C5H2N14O6: achieving azido-based materials with zero oxygen balance and good energetic performance

Qing Lang et al.

Summary: A new azido-based compound 4, N,N'-methylenebis(N-(4-azido-1,2,5-oxadiazol-3-yl)nitramide), was synthesized and characterized, with a compact face-to-face and wavelike stacking crystal structure. The introduction of nitro groups resulted in compound 4 having a zero oxygen balance based on carbon monoxide, which is unusual for azido-based materials. The excellent crystal arrangement and oxygen balance provided compound 4 with better detonation performance (D: 9018 m s(-1); P: 34.5 GPa), indicating its potential application as a high-energy-density material.

NEW JOURNAL OF CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Comparative study on 1,2,3-triazole based azo- and triazene-bridged high-nitrogen energetic materials

Shang-biao Feng et al.

Summary: Two different 1,2,3-triazole based energetic compounds with azo and triazene bridge were investigated, the azo compound showed superior energetic properties compared to the triazene compound. This work provides insights into nitrogen-bridged energetic materials, especially the rarely studied triazene-bridge type explosives.

ENERGETIC MATERIALS FRONTIERS (2021)

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Article Chemistry, Multidisciplinary

Combination of 1,2,3-triazole and 1,2,4-triazole frameworks for new high-energy and low-sensitivity compounds

Wen-jing Yao et al.

Summary: A series of energetic compounds based on C-C linked 1,2,3-triazole and 1,2,4-triazole were synthesized and characterized in this study. These compounds exhibit high thermal stability, fast detonation velocities, and low mechanical sensitivity compared to RDX, showing potential for advancing the development of new high-energy density materials.

ENERGETIC MATERIALS FRONTIERS (2021)

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Article Chemistry, Multidisciplinary

Tricyclic nitrogen-rich explosives with a planar backbone: bis(1,2,4-triazolyl)-1,2,3-triazoles as potential stable green gas generants

Hao Gu et al.

Summary: Two tricyclic nitrogen-rich compounds were synthesized, leading to metal-free energetic salts with positive heat of formation and good thermal stability. These salts exhibit high detonation velocities comparable to RDX, along with low sensitivities to mechanical stimulations. Additionally, the evaluation of gas production capacities showed high gas production volume and pressure compared to commonly used gas generants.

NEW JOURNAL OF CHEMISTRY (2021)

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Article Engineering, Environmental

Synthesis of a bi-heterocyclic skeleton with high HOF and corresponding energetic salts with high heat of detonation

Yupeng Cao et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Chemistry, Multidisciplinary

Dinitromethyl groups enliven energetic salts

Yifei Zhou et al.

ENERGETIC MATERIALS FRONTIERS (2020)

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Article Chemistry, Multidisciplinary

Assembly of Tetrazolylfuroxan Organic Salts: Multipurpose Green Energetic Materials with High Enthalpies of Formation and Excellent Detonation Performance

Alexander A. Larin et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

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Article Chemistry, Multidisciplinary

Energetic materials with fluorinated four-membered heterocyclic ring: 3,3′-difluoroazetidine (DFAZ) salts

Jifeng Chen et al.

NEW JOURNAL OF CHEMISTRY (2019)

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Article Chemistry, Multidisciplinary

5-(4-Azidofurazan-3-yl)-1-hydroxytetrazole and its derivatives: from green primary to secondary explosives

Jichuan Zhang et al.

NEW JOURNAL OF CHEMISTRY (2019)

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Article Chemistry, Multidisciplinary

Gem-dinitromethyl-substituted Energetic Metal-Organic Framework based on 1,2,3-Triazole from in situ Controllable Synthesis

Hao Gu et al.

CHEMISTRY-AN ASIAN JOURNAL (2018)

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Article Chemistry, Multidisciplinary

Potassium Nitraminofurazan Derivatives: Potential Green Primary Explosives with High Energy and Comparable Low Friction Sensitivities

Ying Li et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

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Article Chemistry, Multidisciplinary

Azido and Tetrazolo 1,2,4,5-Tetrazine N-Oxides

David E. Chavez et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

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Article Chemistry, Multidisciplinary

Potassium 4,5-Bis(dinitromethyl)furoxanate: A Green Primary Explosive with a Positive Oxygen Balance

Chunlin He et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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Article Chemistry, Applied

A New Synthetic Route for 3,3′-Bis(fluorodinitromethyl)difurazanyl Ether (FOF-13) and Its Energetic Properties

Lianjie Zhai et al.

JOURNAL OF ENERGETIC MATERIALS (2016)

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Article Chemistry, Multidisciplinary

Energetic N-Nitramino/N-Oxyl-Functionalized Pyrazoles with Versatile π-π Stacking: Structure-Property Relationships of High-Performance Energetic Materials

Ping Yin et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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Article Chemistry, Multidisciplinary

Synthesis and Investigation of Advanced Energetic Materials Based on Bispyrazolylmethanes

Dennis Fischer et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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Article Chemistry, Multidisciplinary

Combining the Advantages of Tetrazoles and 1,2,3-Triazoles: 4,5-Bis(tetrazol-5-yl)-1,2,3-triazole, 4,5-Bis(1-hydroxytetrazol-5-yl)-1,2,3-triazole, and their Energetic Derivatives

Alexander A. Dippold et al.

CHEMISTRY-A EUROPEAN JOURNAL (2016)

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Article Chemistry, Inorganic & Nuclear

Tailoring the Energetic Properties of 5-(5-Amino-1,2,3-triazol-4-yl)tetrazole and Its Derivatives by Salt Formation: From Sensitive Primary to Insensitive Secondary Explosives

Daniel Izsak et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2016)

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Article Chemistry, Multidisciplinary

An unprecedentedly simple method of synthesis of aryl azides and 3-hydroxytriazenes

Pavel S. Gribanov et al.

GREEN CHEMISTRY (2016)

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Article Chemistry, Inorganic & Nuclear

Energetic Sila-Nitrocarbamates: Silicon Analogues of Neo-Pentane Derivatives

Quinn J. Axthammer et al.

INORGANIC CHEMISTRY (2016)

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Article Chemistry, Multidisciplinary

Energetic Salts Based on 3,5-Bis(dinitromethyl)-1,2,4-triazole Monoanion and Dianion: Controllable Preparation, Characterization, and High Performance

Jiaheng Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

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Article Chemistry, Inorganic & Nuclear

Synthesis and structural characterization of 3,5-dinitro-1,2,4-triazolates

R. Haiges et al.

DALTON TRANSACTIONS (2015)

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Article Chemistry, Multidisciplinary

A green high-initiation-power primary explosive: synthesis, 3D structure and energetic properties of dipotassium 3,4-bis(3-dinitromethylfurazan-4-oxy) furazan

Lianjie Zhai et al.

RSC ADVANCES (2015)

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Article Chemistry, Multidisciplinary

3,3′-Bi(1,2,4-oxadiazoles) Featuring the Fluorodinitromethyl and Trinitromethyl Groups

Marcos A. Kettner et al.

CHEMISTRY-A EUROPEAN JOURNAL (2014)

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Article Chemistry, Multidisciplinary

A Study of 5-(1,2,4-Triazol-C-yl)tetrazol-1-ols: Combining the Benefits of Different Heterocycles for the Design of Energetic Materials

Alexander A. Dippold et al.

CHEMISTRY-A EUROPEAN JOURNAL (2013)

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Article Chemistry, Physical

Pushing the limits of energetic materials - the synthesis and characterization of dihydroxylammonium 5,5′-bistetrazole-1,1′-diolate

Niko Fischer et al.

JOURNAL OF MATERIALS CHEMISTRY (2012)

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Article Chemistry, Multidisciplinary

1,3-Bis(nitroimido)-1,2,3-triazolate Anion, the N-Nitroimide Moiety, and the Strategy of Alternating Positive and Negative Charges in the Design of Energetic Materials

Thomas M. Klapoetke et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

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Article Chemistry, Multidisciplinary

3-Azido-N-nitro-1H-1,2,4-triazol-5-amine-Based Energetic Salts

Kai Wang et al.

CHEMISTRY-A EUROPEAN JOURNAL (2011)

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Article Chemistry, Multidisciplinary

The Taming of CN7-: The Azidotetrazolate 2-Oxide Anion

Thomas M. Klapoetke et al.

CHEMISTRY-A EUROPEAN JOURNAL (2011)

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Article Chemistry, Multidisciplinary

Trinitromethyl-Substituted 5-Nitro- or 3-Azo-1,2,4-triazoles: Synthesis, Characterization, and Energetic Properties

Venugopal Thottempudi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

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Article Chemistry, Multidisciplinary

Selective Preparation of 3,4,5-Trinitro-1H-Pyrazole: A Stable All-Carbon-Nitrated Arene

Gregoire Herve et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

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Article Chemistry, Multidisciplinary

Nitrotetrazolate-2N-oxides and the Strategy of N-Oxide Introduction

Michael Goebel et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

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Article Chemistry, Physical

Energetic mono and dibasic 5-dinitromethyltetrazolates: synthesis, properties, and particle processing

Zhuo Zeng et al.

JOURNAL OF MATERIALS CHEMISTRY (2007)

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Article Chemistry, Physical

A quantum mechanical investigation of the relation between impact sensitivity and the charge distribution in energetic molecules

BM Rice et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2002)

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Review Chemistry, Physical

Computational characterization of energetic materials

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JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM (2001)

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Synthesis and Characterization of Azido-Functionalized 1,2,3-Triazole and Fused 1,2,3-Triazole

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