期刊
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
卷 571, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jmmm.2023.170562
关键词
Dual-alloy sintering; Sintered NdFeB magnets; Grain boundary diffusion; Coercivity enhancement
The magnetic properties and thermal stability of high-performance NdFeB magnets are improved by dual-alloy sintering with Pr85Al15 and grain boundary diffusion with Tb55Pr20Cu25. The addition of Pr and Al strengthens the magnetic decoupling effect at the grain boundaries and a thin layer of (Nd, Pr)2Fe14B with higher magnetocrystalline anisotropy field is formed at the grain surface. The coercivity is further enhanced and thermal stability is improved after grain boundary diffusion with Tb55Pr20Cu25 alloy. Different magnetic levels of high-performance NdFeB magnets can be easily achieved by modifying the amount of PrAl for sintered magnets and/or grain boundary diffusion with TbPrCu alloys.
Magnetic-property modification and thermal stability improvement for high-performance NdFeB magnets by dual-alloy (DA) sintering with Pr85Al15 (PrAl) together with grain boundary diffusion (GBD) with Tb55Pr20Cu25 (TbPrCu) is demonstrated. The coercivity is increased from 14.9 to 16.4-18.0 kOe for the magnet DA sintering with 2-4 % PrAl. Pr and Al at grain boundary strengthens magnetic decoupling effect. In addition, a thin layer of (Nd, Pr)2Fe14B with higher magnetocrystalline anisotropy field (HA) is formed at grain surface. Both effects contribute to the coercivity enhancement for the magnets prepared by DA sintering with PrAl. Furthermore, remarkable coercivity enhancement, from 14.9 to 18.0 kOe to 22.7-27.1 kOe, with improved thermal stability is attained for the above magnets after GBD with Tb55Pr20Cu25 alloy. Besides, the increased Curie temperature of 2:14:1 phase indicates the entrance of Tb into 2:14:1 phase and helps to improve thermal stability. Most importantly, various magnetic levels of high-performance NdFeB magnets, including 48-52 M, 45H, 50SH and 40-45UH, can be easily attained by modifying the amount of PrAl for DA sintered magnets and/or GBD with TbPrCu alloys.
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