4.8 Article

A 2D Semiconductor-Self-Assembled Monolayer Photoswitchable Diode

期刊

ADVANCED MATERIALS
卷 27, 期 8, 页码 1426-+

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WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201405110

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资金

  1. Deutsche Forschungsgemeinschaft (DFG) via the Nanosystems Initiative Munich
  2. European Research Council [247299]
  3. Munich Centre for Advanced Photonics
  4. China Scholarship Council

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A switchable diode in a 2D semiconductor-molecular junction heterostructure is reported. MoS2 is exfoliated on top of a monolayer of azobenzene-substituted thiols on gold. Photoisomerization of the azobenzenes results in switching between a rectifier with rectifying ratios of 10(4) and a conductive state, as revealed by conducting atomic force microscopy.

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