A novel thermosensitive persulfate controlled-release hydrogel based on agarose/silica composite for sustained nitrobenzene degradation from groundwater

The increasing risk of organic contamination of groundwater poses a serious threat to the environment and human health, causing an urgent need to develop long-lasting and adaptable remediation materials. Controlled release materials (CRMs) are capable of encapsulating oxidants to achieve long-lasting release properties in aquifers and considered to be effective strategies in groundwater remediation. In this study, novel hydrogels (ASGs) with thermosensitive properties were prepared based on agarose and silica to achieve controlled per sulfate (PS) release. By adjusting the composition ratio, the gelation time and internal pore structure of the hydrogels were regulated for groundwater application, which in turn affected the PS encapsulated amount and release properties. The hydrogels exhibited significant temperature responsiveness, with 6.8 times faster gelation rates and 2.8 times longer controlled release ability at 10 degrees C than at 30 degrees C. The ASGs were further combined with zero-valent iron to achieve long-lasting degradation of the typical nitrobenzene compound 2,4-dinitrotoluene (2,4-DNT), and the degradation performance was maintained at 50 % within 14 PV, which was significantly improved compared with that of the PS/ZVI system. This study provided new concepts for the design of controlled-release materials and theoretical support for the remediation of organic contamination.

Automated summary

Novel hydrogels (ASGs) with thermosensitive properties were prepared based on agarose and silica for controlled per sulfate (PS) release. The composition ratio of the hydrogels was adjusted to regulate the gelation time and internal pore structure, which influenced the encapsulated amount and release properties of PS. The ASGs exhibited significant temperature responsiveness and when combined with zero-valent iron, achieved long-lasting degradation of 2,4-dinitrotoluene (2,4-DNT) with improved performance compared to the PS/ZVI system.