Efficient removal of bromate from contaminated water using electrochemical membrane filtration with metal heteroatom interface

Efficient utilization of atomic hydrogen (H*) is of great importance for achieving efficient bromate reduction using electrochemical technologies. Herein, an electrochemical membrane with metal heteroatom interface of Ru and Ni was developed to enhance the utilization efficiency of H* via the membrane filtration process. The RuNi membrane demonstrated 91.3% of bromate removal at 5 mA cm-2 under the flow-through operation (40 L m- 2 h-1). Cyclic voltammetry (CV) curves and electron spin resonance (ESR) spectra elucidated that the bromate reduction was mainly attributed to H*-mediated reduction rather than the direct electron transfer between bromate and RuNi active layer. The quenching experiments revealed a significant contribution of adsorbed H* to the bromate removal during the membrane filtration. Based on X-ray photoelectron spectrometry and X-ray diffraction analyses, we found that the resultant Ru0Ni0 structure on the electrochemical membrane could facilitate the generation of H* during the bromate reduction reaction. Besides, the higher pH might suppress the formation of H* and increase the energy barrier for breaking the Br-O bond, resulting in dramatic increase of energy consumption for removing bromate. Our work highlights the potential of utilizing H* in electrochemical membrane for removing bromate in water treatment and remediation.

Automated summary

An electrochemical membrane with a Ru and Ni metal heteroatom interface was developed to enhance the utilization efficiency of atomic hydrogen (H*) for bromate reduction. The RuNi membrane achieved 91.3% bromate removal at 5 mA cm-2 under flow-through operation. The bromate reduction was mainly attributed to H*-mediated reduction, and adsorbed H* significantly contributed to bromate removal during membrane filtration. The formation of Ru0Ni0 structure on the electrochemical membrane facilitated H* generation during bromate reduction.