Synthesis of the MnO2-Fe3O4 catalyst support on amorphous silica: a new Fenton's reagent in the degradation of the reactive blue-19 in aqueous solution

In this study, a new Fenton's reagent was synthesized via two steps: (1) the dispersed Fe3O4 nanoparticles were immobilized on the surface of the SiO2 carrier via the precipitation process, and (2) the MnO2 nano-sheets were coated on the surface of Fe3O4/SiO2 via hydrothermal method. The SiO2 carrier has been synthetically utilized from Vietnamese rice husk. The successful formation of the MnO2-Fe3O4/SiO2 composite has been analytically characterized by the XRD (X-ray diffraction), SEM (scanning electron microscope), EDS (energy dispersive spectrometry)-mapping, FTIR (Fourier transform infrared), S-BET (Brunauer-Emmett-Teller specific surface area), and adsorption/desorption isotherms. This Fenton system was employed to catalyze degradation process of the reactive-blue 19 (RB19) with approximately 100% of removal efficiency after 25 min at the optimal condition of 0.15 g/100 mL of catalyst dosage, pH = 3, and the H2O2 concentration of 3 mL/100 mL. Moreover, the catalyst could be reused at least six times with high catalytic activity that was more than 90%. In conclusion, this study showed that the mesoporous MnO2-Fe3O4/SiO2 composite has a great potential for the removal application of dyes from wastewater, and the application of Vietnam rice husk in environmental treatment was developed.

Automated summary

In this study, a new Fenton's reagent was synthesized by immobilizing Fe3O4 nanoparticles on SiO2 carrier and coating MnO2 nano-sheets on Fe3O4/SiO2. The successful formation of the MnO2-Fe3O4/SiO2 composite was confirmed by various analytical methods. The Fenton system showed high efficiency in degrading reactive-blue 19 (RB19) and the catalyst could be reused multiple times. This study demonstrated the potential of the mesoporous MnO2-Fe3O4/SiO2 composite in dye removal and the utilization of Vietnam rice husk in environmental treatment.