期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 636, 期 -, 页码 610-617出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2023.01.076
关键词
Oxygen evolution reaction; Electrochemical neutralization energy; Catalysts electrode; Hydrogen production; Hybrid acid; alkali electrolysis
In this study, the in-situ growth of MnCo2O4 nanoneedles and NiFeRu layered double hydroxide (LDH) nanosheets on nickel foam (NF) was reported, which serve as a highly efficient electrode for oxygen evolution reaction (OER) electrocatalysis. This electrode only requires an overpotential as low as 205 mV to reach a current density of 10 mA cm-2 in alkaline electrolyte and exhibits stable performance for continuous operation over 120 hours. Furthermore, a hybrid flow acid/alkali electrolyzer was constructed using Pt/C as the acidic cathode and MnCo2O4@NiFeRu-LDH/NF as the alkaline anode, achieving electrolytic current densities of 10 mA cm-2 and 100 mA cm-2 with applied voltages of 0.59 V and 0.94 V, respectively. This research contributes to the development of energy-saving electrolytic techniques for hydrogen generation.
The development of high-efficiency oxygen evolution reaction (OER) electrocatalysts is of great impor-tance for electrolytic H2 generation. In this work, we report in-situ growth of MnCo2O4 nanoneedles and NiFeRu layered double hydroxide (LDH) nanosheets on nickel foam (NF) (MnCo2O4@NiFeRu-LDH/ NF) that can function a highly efficient electrode toward electrocatalysis of OER. Such electrode demands an overpotential of as low as 205 mV to reach 10 mA cm-2 in alkaline electrolyte and can run stably over 120-hours continuous operation. A hybrid flow acid/alkali electrolyzer is set up by using the Pt/C as the acidic cathode coupling with the MnCo2O4@NiFeRu-LDH/NF as the alkaline anode, which only requires an applied voltage of 0.59 V and 0.94 V to attain an electrolytic current density of 10 mA cm-2 and 100 mA cm-2, respectively. The present work could push forward the further development of the electricity-saving electrolytic technique for H2 generation.(c) 2023 Published by Elsevier Inc.
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