期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 937, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2022.168455
关键词
Energy storage; BaTiO3-based; Relaxor characteristic
New environmental protection energy storage devices have been widely studied, and BaTiO3-based ceramics are considered excellent materials for achieving high energy storage. In this study, a series of (1-x)BaTiO3-x(Bi0.5Li0.5)(Ti0.5Sn0.5)O3 ceramics were successfully synthesized, with 0.2BLST ceramics exhibiting high energy storage density and efficiency under certain conditions. These ceramics also displayed outstanding stability and excellent charge-discharge performance, making them a promising lead-free energy material.
New environmental protection energy storage devices have been widely studied in recent years. BaTiO3- based ceramics are considered excellent materials for achieving high energy storage due to their exceptional dielectric and ferroelectric properties. In this study, a series of(1-x)BaTiO3-x(Bi0.5Li0.5)(Ti0.5Sn0.5)O3 (xBLST, x = 0.1, 0.15, 0.2, and 0.25) ceramics were successfully synthesized by the conventional solid-phase method. The 0.2BLST ceramics exhibited a high recoverable energy storage density (Wrec) of 3.83 J/cm3 and high energy storage efficiency (eta) of 88 % under the breakdown strength (Eb) of 525 kV/cm. Moreover, the Wrec of 0.2BLST ceramics had outstanding stability over 1-120 Hz and between 20 and 180 degrees C. Finally, the 0.2BLST ceramics displayed excellent charge-discharge performance with a discharge power of up to 86 MW/cm3, a high discharge density of 0.68 J/cm3, and an extremely fast discharge time (t0.9 similar to 71 ns). These properties establish that 0.2BLST ceramic is a promising lead-free energy material.(c) 2022 Elsevier B.V. All rights reserved.
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