期刊
IONICS
卷 -, 期 -, 页码 -出版社
SPRINGER HEIDELBERG
DOI: 10.1007/s11581-023-04978-0
关键词
Zwitterionic liquids; Poly(ionic liquids); Polymer electrolytes; Lithium-ion batteries
Zwitterionic poly(ionic liquid)-based polymer electrolytes with a network structure were prepared by ultraviolet-irradiation radical polymerization, showing high thermal stability and excellent dimensional stability. The PEGMEA provided sufficient transport sites for Li+ and a high ionic conductivity of 0.20 x 10(-3) S cm(-1). The electrolyte exhibited a high lithium-ion transference number of 0.78, and the lithium symmetric battery showed good performance with a voltage polarization of 150 mV over 600 h. The Li/LiFePO4 battery demonstrated a discharge capacity of 122 mAh g(-1), a capacity retention of 90.0% after 100 cycles, and an average Coulombic efficiency exceeding 99% at 0.1 C, indicating its potential in lithium-ion batteries.
In this study, zwitterionic poly(ionic liquid)-based polymer electrolytes with a network structure are prepared by ultraviolet-irradiation radical polymerization of poly(ethylene glycol) methyl ether acrylate (PEGMEA) and zwitterionic liquids, and poly(ethylene glycol) diacrylate is used as cross-linker. The cross-linked structure endows the electrolytes with high thermal stability and excellent dimensional stability. The abundant ether-oxygen group of PEGMEA provides sufficient sites for the transport of Li+ and a high ionic conductivity of 0.20 x 10(-3) S cm(-1). The electrolyte shows a high lithium-ion transference number of 0.78, owing to the excellent dissociation ability of zwitterionic liquids towards lithium salts. The lithium symmetric battery can maintain a voltage polarization of 150 mV at 0.1 mA cm(-2) over 600 h. The Li/LiFePO4 battery shows a discharge capacity of 122 mAh g(-1), a capacity retention of 90.0% after 100 cycles, and an average Coulombic efficiency exceeding 99% at 0.1 C, demonstrating strong application potential in lithium-ion batteries.
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