Ni/Al2O3 catalysts for CO2 methanation: Effect of silica and nickel loading

Samples containing from 1 to 33 wt.% of NiO on silica and alumina doped with silica (1 and 20 wt.% silica in the support) have been prepared and characterized by BET, XRD, FT-IR, UV-vis-NIR, FE-SEM, EDXS, and TPR techniques. Catalysts have been pre-reduced in situ before catalytic experiments and data have been compared with Ni/Al2O3 reference sam-ple. Characterization results showed that SiO2 support has a low Ni dispersion ability mainly producing segregated NiO particles and a small amount of dispersed Ni2} in ex -change sites. Instead, for the Si-doped alumina a surface spinel monolayer phase is formed by increasing Ni loading and, only when the support surface is completely covered by this layer, NiO is formed. Moreover, H2-TPR results indicated that NiO particles are more easily reduced compared to Ni species. Low loading Ni/SiO2 catalysts show high selectivity and moderate activity for RWGS (reverse Water Gas Shift) reaction, likely mainly due to nickel species dispersed in silica exchange sites, as evidenced by visible spectroscopy. High loading Ni/SiO2 catalysts show both methanation and RWGS but evident short-term deactivation for methanation, attributed to large, segregated Ni metal particles, covered by a carbon veil. Ni on alumina-rich carriers, where nickel disperses forming a surface spinel phase, show high activity and selectivity for methanation, and short-term catalyst stability as well. This activity is attributed to small nickel clusters or metal particles interacting with alumina, formed upon reaction. The addition of SiO2 in Al2O3 support decreases the activity of Ni catalysts in CO2 methanation, because it reduces the ability of the support to disperse nickel in form of the surface spinel phase, thus reducing the amount of Ni clusters in the reduced catalysts.& COPY; 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

Automated summary

Samples of NiO on silica and alumina doped with silica were prepared and characterized. The SiO2 support showed low Ni dispersion ability, producing segregated NiO particles and dispersed Ni2+ in exchange sites, while the Si-doped alumina formed a surface spinel monolayer phase, leading to the formation of NiO. H2-TPR results indicated that NiO particles are more easily reduced than Ni species. Low loading Ni/SiO2 catalysts showed high selectivity and moderate activity for RWGS reaction, while high loading Ni/SiO2 catalysts showed both methanation and RWGS with short-term deactivation for methanation. Ni on alumina-rich carriers exhibited high activity and selectivity for methanation, attributed to small nickel clusters or metal particles interacting with alumina.