Preparation of manganese-oxides-coated magnetic microcrystalline cellulose via KMnO4 modification: Improving the counts of the acid groups and adsorption efficiency for Pb(II)

Herein, the manganese-oxides-coated magnetic microcrystalline cellulose (MnOx@Fe3O4@MCC) was prepared by coprecipitation and subsequently modified with KMnO4 solution at room temperature, which was in turn applied for the removal of Pb(II) from wastewater. The adsorption properties of Pb(II) on MnOx@Fe3O4@MCC were investigated. The kinetics and isothermal data of Pb(II) were described well by the Pseudo-second-order model and the Langmuir isotherm model, respectively. At pH = 5, 318 K, the Langmuir maximum Pb(II) adsorption capacity of MnOx@Fe3O4@MCC was 446.43 mg/g, which is higher than many documented bio-based adsorbents. The results of Fourier transform infra-red and X-ray photoelectron spectroscopy indicated that the adsorption mechanisms for Pb(II) mainly involved surface complexation, ion exchange, electrostatic interaction and precipitation. Interestingly, the increased amount of carboxyl group on the surface of microcrystalline cel-lulose modified by KMnO4 was one of the important reasons for the high Pb(II) adsorption performance of MnOx@Fe3O4@MCC. Furthermore, MnOx@Fe3O4@MCC exhibited excellent activity (70.6 %) after five consecutive regeneration cycles, indicating its high stability and reusability. Endorsing to the cost-effectiveness, environmentally friendliness, and reusable nature, MnOx@Fe3O4@MCC can be counted as a great alternative contender for the remediation of Pb(II) from industrial wastewater.

Automated summary

The manganese-oxides-coated magnetic microcrystalline cellulose was prepared by coprecipitation and modified with KMnO4 solution for the removal of Pb(II) from wastewater. The adsorption mechanism mainly involved surface complexation, ion exchange, electrostatic interaction, and precipitation. The material exhibited high adsorption capacity, stability, and reusability.