Cellulose nanocrystals-based bio-composite optical materials for reversible colorimetric responsive films and coatings

Photonic materials with a tunable chiral nematic structure that can selectively reflect light dynamically are valuable for applications in smart responsive materials. Here, we prepared potential photonic composites with a chiral nematic structure by forming cellulose nanocrystals (CNCs) and waterborne polyurethane (WPU) com-posites with different compositions on different substrates by evaporation-induced self-assembly. With increasing WPU content, the reflected wavelength increased from 400 to 680 nm, which was mainly caused by the increase of the chiral nematic pitch. In addition, the mechanical properties were better for higher WPU content. WPU was sensitive to small amounts of moisture in ethanol owing to the swollen WPU after absorbing water will increase the helical pitch. The reversible red shift induced by moisture was approximately 100 nm. When wood was used as the substrate, the CNCs still self-assembled to form chiral nematic structures and the adhesion forces of the composites to the wood substrate were strong. By using MgCl2 solution as an ink, invisible patterns can be written on the coating, which can be revealed temporarily by ethanol. In addition, the invisible pattern of photonic coating is rewritable. The easily prepared environmentally friendly photonic composite has great po-tential in sensors, anti-counterfeiting labels and smart decorative coatings.

Automated summary

We prepared photonic composites with a tunable chiral nematic structure by self-assembly of cellulose nanocrystals and waterborne polyurethane. The reflected wavelength increased with increasing WPU content due to the increase of the chiral nematic pitch. Higher WPU content also led to better mechanical properties. The composites formed strong adhesion forces with wood substrates and invisible patterns could be written and revealed temporarily using MgCl2 solution as an ink.