Preparation of metal organic frameworks modified chitosan composite with high capacity for Hg(II) adsorption

In this study, a novel modified chitosan composite adsorbent (UNCS) was prepared by crosslinking between chitosan and metal organic frameworks (MOFs) material UiO-66-NH2 using epichlorohydrin as crosslinker. The influence of the prepared conditions was investigated. The structure and morphology of the composite were characterized by FT-IR, XRD, SEM, TGA, BET and zeta potential analysis. Effects of different variables for adsorption of Hg(II) on this adsorbent were explored. The kinetic studies indicated that the adsorption process followed the pseudo-second-order kinetic model and the adsorption equilibrium could be reached within 2 h. The adsorption was mainly controlled by chemical process. Adsorption isothermal studies illustrated that the adsorption fitted Langmuir isotherm model, implying the homogeneous adsorption on the surface of the adsorbent. The adsorbent exhibited high uptake and the maximum capacity from Langmuir model could reach 896.8 mg g-1 at pH 6. Thermodynamic studies showed the spontaneous nature and exothermic nature of the adsorption process. Additionally, the removal of Hg(II) on UNCS could achieve over 90 %. The adsorptiondesorption cycled experiments indicated the appropriate reusability of the adsorbent. Hence, this adsorbent would be promising for the removal of Hg(II) from wastewater.

Automated summary

In this study, a novel modified chitosan composite adsorbent (UNCS) was prepared by crosslinking chitosan and metal organic frameworks (MOFs) material UiO-66-NH2 with epichlorohydrin. The adsorbent exhibited high uptake for Hg(II) and could achieve over 90% removal. The adsorption process followed pseudo-second-order kinetics and fit the Langmuir isotherm model, indicating its potential for Hg(II) removal from wastewater. The UNCS adsorbent also showed good reusability in adsorption-desorption cycled experiments.