期刊
INORGANIC CHEMISTRY
卷 62, 期 7, 页码 3141-3152出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.2c04022
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In this study, Eu3+ single-doped LaAl1-yGayO3 solid solutions and Eu3+,Mn4+ codoped LaAl0.7Ga0.3O3 phosphors were designed and synthesized to achieve broadband ultraviolet excitation and red/far-red emission for enhancing photosynthesis in plants. The LAG:Eu3+ phosphor exhibited strong CTB excitation and characteristic red emission, similar to Eu3+-organic ligand compound. The LAG:Eu,Mn phosphor showed dual-band excitation and emission, and when coated on luminous laminated glasses, it significantly increased the radiant intensity in the red/far-red region under sunlight, indicating its potential for solar spectral conversion in plant cultivation.
Broadband ultraviolet (UV) excitation and red/far-red emission phosphors can effectively convert solar spectrum to enhance photosynthesis and promote morphogenesis in plants. Based on the above application requirements, Eu3+ single-doped LaAl1-yGayO3 solid solutions and Eu3+,Mn4+ codoped LaAl0.7Ga0.3O3 phosphors were designed and synthesized in this work. The LaAl0.7Ga0.3O3:0.05Eu3+ (LAG:Eu3+) phosphor exhibits a strong charge transfer band (CTB) excitation and characteristic 5D0-*7F2 transition red emission (619 nm), which is very similar to the luminescence properties of Eu3+-organic ligand compound (EuL3). Rietveld refinement studies further revealed that the cation substitution disturbs the site symmetry. The optimal Eu3+, Mn4+ co-doped LaAl0.7Ga0.3O3 (LAG:Eu,Mn) phosphor possesses a dual -band excitation spectrum in broadband ultraviolet (UVA, UVB) area and a dual-band emission spectrum within red/far-red area. Under the sunlight radiation, the real-time spectrum of luminous laminated glasses fabricated by coating the LAG:Eu,Mn phosphor shows the percentage of radiant intensity in the red/far-red region significantly increases, suggesting that the phosphor can be a promising candidate for solar spectral conversion in plant cultivation. We believe this work provides a new idea for developing novel broadband ultraviolet excitation and red/far-red emission phosphors.
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